Dimethylarsinic acid (BioDeep_00000002848)

 

Secondary id: BioDeep_00001867631, BioDeep_00001892245

human metabolite Endogenous blood metabolite


代谢物信息卡片


Hydroxydimethylarsine oxide

化学式: C2H7AsO2 (137.9662)
中文名称: 二甲基砷标准溶液, 椰油酸
谱图信息: 最多检出来源 Homo sapiens(blood) 40.01%

分子结构信息

SMILES: C[As](=O)(C)O
InChI: InChI=1S/C2H7AsO2/c1-3(2,4)5/h1-2H3,(H,4,5)

描述信息

Dimethylarsinic acid, also known as cacodylic acid, is formally rated as possibly a carcinogenic (IARC 2B), potentially toxic compound. Derivatives of cacodylic acid, cacodylates, were frequently used as herbicides. For example, Agent Blue, one of the chemicals used during the Vietnam War, is a mixture of cacodylic acid and sodium cacodylate. Sodium cacodylate is frequently used as a buffering agent in the preparation and fixation of biological samples for transmission electron microscopy. Dimethylarsinic acid is highly toxic by ingestion, inhalation, or skin contact. Once thought to be a byproduct of inorganic arsenic detoxification, it is now believed to have serious health consequences of its own. It has been shown to be teratogenic in rodents, most often causing cleft palate but also fetal fatality at high doses. It has been shown to be genotoxic in human cells, causing apoptosis and also decreased DNA production and shorter DNA strands. While not itself a strong carcinogen, dimethylarsinic acid does promote tumours in the presence of carcinogens in organs such as the kidneys and liver (Wikipedia).
Cacodylic acid is the chemical compound with the formula (CH3)2AsO2H. Derivatives of cacodylic acid, cacodylates, were frequently used as herbicides. For example, "Agent Blue," one of the chemicals used during the Vietnam War, is a mixture of cacodylic acid and sodium cacodylate. Sodium cacodylate is frequently used as a buffering agent in the preparation and fixation of biological samples for transmission electron microscopy.
D010575 - Pesticides > D006540 - Herbicides
D016573 - Agrochemicals

同义名列表

15 个代谢物同义名

Hydroxydimethylarsine oxide; As,as-dimethylarsinic acid; Acid, dimethylarsinic; Dimethylarsenic acid; Dimethylarsinic acid; Dimethylarsinate; Acid, cacodylic; [As(CH3)2O(OH)]; cacodylic acid; Kakodylsaeure; Me2as(=o)OH; CACODYLate; Ansar; Cacodylate; Cacodylic acid



数据库引用编号

22 个数据库交叉引用编号

分类词条

相关代谢途径

Reactome(4)

BioCyc(0)

PlantCyc(0)

代谢反应

60 个相关的代谢反应过程信息。

Reactome(60)

BioCyc(0)

WikiPathways(0)

Plant Reactome(0)

INOH(0)

PlantCyc(0)

COVID-19 Disease Map(0)

PathBank(0)

PharmGKB(0)

4 个相关的物种来源信息

在这里通过桑基图来展示出与当前的这个代谢物在我们的BioDeep知识库中具有相关联信息的其他代谢物。在这里进行关联的信息来源主要有：

  • PubMed: 来源于PubMed文献库中的文献信息，我们通过自然语言数据挖掘得到的在同一篇文献中被同时提及的相关代谢物列表，这个列表按照代谢物同时出现的文献数量降序排序，取前10个代谢物作为相关研究中关联性很高的代谢物集合展示在桑基图中。
  • NCBI Taxonomy: 通过文献数据挖掘，得到的代谢物物种来源信息关联。这个关联信息同样按照出现的次数降序排序，取前10个代谢物作为高关联度的代谢物集合展示在桑吉图上。
  • Chemical Taxonomy: 在物质分类上处于同一个分类集合中的其他代谢物
  • Chemical Reaction: 在化学反应过程中，存在为当前代谢物相关联的生化反应过程中的反应底物或者反应产物的关联代谢物信息。

点击图上的相关代谢物的名称，可以跳转到相关代谢物的信息页面。

亚细胞结构定位 关联基因列表
Cytoplasm 12 ANXA5, CASP3, CASP8, CAT, CCND1, GSTM1, GSTO1, GSTT1, HPGDS, MAPK8, ODC1, PML
Peripheral membrane protein 2 ANXA5, PML
Endoplasmic reticulum membrane 2 HSP90B1, PML
Nucleus 10 CASP3, CASP8, CCND1, HSP90B1, MAPK8, N6AMT1, OGG1, PCNA, PDS5B, PML
cytosol 19 ANXA5, AS3MT, CASP3, CASP8, CAT, CCND1, GPT, GSR, GSTM1, GSTO1, GSTT1, HPGDS, HSP90B1, MAPK8, N6AMT1, ODC1, OGG1, PDS5B, PML
nuclear body 1 PCNA
centrosome 2 CCND1, PCNA
nucleoplasm 9 CASP3, CASP8, CCND1, HPGDS, MAPK8, OGG1, PCNA, PDS5B, PML
Cytoplasmic side 1 PML
lamellipodium 1 CASP8
Early endosome membrane 1 PML
Synapse 1 MAPK8
glutamatergic synapse 1 CASP3
neuronal cell body 1 CASP3
sarcolemma 1 ANXA5
smooth endoplasmic reticulum 1 HSP90B1
Cytoplasm, cytosol 2 AS3MT, GSTO1
Membrane 3 ANXA5, CAT, HSP90B1
axon 1 MAPK8
extracellular exosome 8 ANXA5, CAT, GPT, GSR, GSTO1, GSTT1, HSP90B1, PCNA
endoplasmic reticulum 1 HSP90B1
perinuclear region of cytoplasm 1 HSP90B1
bicellular tight junction 1 CCND1
mitochondrion 4 CASP8, CAT, GSR, OGG1
protein-containing complex 5 CASP8, CAT, HSP90B1, N6AMT1, OGG1
intracellular membrane-bounded organelle 2 CAT, HPGDS
postsynaptic density 1 CASP3
extracellular region 3 ANXA5, CAT, HSP90B1
mitochondrial outer membrane 1 CASP8
mitochondrial matrix 3 CAT, GSR, OGG1
Nucleus membrane 1 CCND1
nuclear membrane 2 CCND1, PML
external side of plasma membrane 2 ANXA5, GSR
nucleolus 1 PML
midbody 1 HSP90B1
Cell projection, lamellipodium 1 CASP8
focal adhesion 3 ANXA5, CAT, HSP90B1
Peroxisome 1 CAT
Peroxisome matrix 1 CAT
peroxisomal matrix 1 CAT
peroxisomal membrane 1 CAT
Nucleus, PML body 1 PML
PML body 1 PML
collagen-containing extracellular matrix 2 ANXA5, HSP90B1
nuclear speck 1 OGG1
Zymogen granule membrane 1 ANXA5
chromatin 2 PCNA, PDS5B
Chromosome 1 PDS5B
cytoskeleton 1 CASP8
nuclear replication fork 1 PCNA
chromosome, telomeric region 2 PCNA, PML
intercellular bridge 1 GSTM1
Nucleus, nucleoplasm 1 OGG1
Melanosome 1 HSP90B1
Nucleus speckle 1 OGG1
cell body 1 CASP8
replication fork 1 PCNA
sperm plasma membrane 1 HSP90B1
ficolin-1-rich granule lumen 1 CAT
secretory granule lumen 1 CAT
endoplasmic reticulum lumen 1 HSP90B1
nuclear matrix 2 OGG1, PML
transcription repressor complex 1 CCND1
male germ cell nucleus 1 PCNA
Nucleus matrix 1 OGG1
chromosome, centromeric region 1 PDS5B
vesicle membrane 1 ANXA5
nuclear lamina 1 PCNA
Sarcoplasmic reticulum lumen 1 HSP90B1
basal dendrite 1 MAPK8
CD95 death-inducing signaling complex 1 CASP8
death-inducing signaling complex 2 CASP3, CASP8
ripoptosome 1 CASP8
cyclin-dependent protein kinase holoenzyme complex 2 CCND1, PCNA
endocytic vesicle lumen 1 HSP90B1
catalase complex 1 CAT
endoplasmic reticulum chaperone complex 1 HSP90B1
endothelial microparticle 1 ANXA5
cyclin D1-CDK4 complex 1 CCND1
PCNA complex 1 PCNA
PCNA-p21 complex 1 PCNA
replisome 1 PCNA
cyclin D1-CDK6 complex 1 CCND1
eRF1 methyltransferase complex 1 N6AMT1


文献列表

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  • Chuan Chen, Yu Yu, Yijie Wang, Axiang Gao, Baoyun Yang, Zhu Tang, Fang-Jie Zhao. Reduction of Dimethylarsenate to Highly Toxic Dimethylarsenite in Paddy Soil and Rice Plants. Environmental science & technology. 2023 01; 57(1):822-830. doi: 10.1021/acs.est.2c07418. [PMID: 36490306]
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  • Jun Tang, Qinheng Zhu, Yang Xu, Yexinyi Zhou, Longtao Zhu, Lanfei Jin, Weiye Wang, Lan Gao, Guangdi Chen, Hao Zhao. Total arsenic, dimethylarsinic acid, lead, cadmium, total mercury, methylmercury and hypertension among Asian populations in the United States: NHANES 2011-2018. Ecotoxicology and environmental safety. 2022 Aug; 241(?):113776. doi: 10.1016/j.ecoenv.2022.113776. [PMID: 35738098]
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