NCBI Taxonomy: 1906

Streptomyces fradiae (ncbi_taxid: 1906)

found 500 associated metabolites at species taxonomy rank level.

Ancestor: Streptomyces

Child Taxonomies: Streptomyces fradiae subsp. acinicolor, Streptomyces fradiae ATCC 10745 = DSM 40063

Indoleacetic acid

2-Amino-3-(2-amino-2-carboxy-ethyl)disulfanyl-propanoic acid

C10H9NO2 (175.0633254)


Indoleacetic acid (IAA) is a breakdown product of tryptophan metabolism and is often produced by the action of bacteria in the mammalian gut. Higher levels of IAA are associated with bacteria from Clostridium species including C. stricklandii, C. lituseburense, C. subterminale, and C. putrefaciens (PMID: 12173102). IAA can be found in Agrobacterium, Azospirillum, Bacillus, Bradyrhizobium, Clostridium, Enterobacter, Pantoea, Pseudomonas, Rhizobium (PMID: 12173102, PMID: 17555270, PMID: 12147474, PMID: 19400643, PMID: 9450337, PMID: 21397014) (https://link.springer.com/chapter/10.1007/978-1-4612-3084-7_7) (https://escholarship.org/uc/item/1bf1b5m3). Some endogenous production of IAA in mammalian tissues also occurs. It may be produced by the decarboxylation of tryptamine or the oxidative deamination of tryptophan. IAA frequently occurs at low levels in urine and has been found in elevated levels in the urine of patients with phenylketonuria (PMID: 13610897). IAA has also been identified as a uremic toxin according to the European Uremic Toxin Working Group (PMID: 22626821). Using material extracted from human urine, it was discovered by Kogl in 1933 that indoleacetic acid is also an important plant hormone (PMID: 13610897). Specifically, IAA is a member of the group of phytohormones called auxins. IAA is generally considered to be the most important native auxin. Plant cells synthesize IAA from tryptophan (Wikipedia). IAA and some derivatives can be oxidized by horseradish peroxidase (HRP) into cytotoxic species. IAA is only toxic after oxidative decarboxylation; the effect of IAA/HRP is thought to be due in part to the formation of methylene-oxindole, which may conjugate with DNA bases and protein thiols. IAA/HRP could be used as the basis for targeted cancer, a potential new role for plant auxins in cancer therapy (PMID: 11163327). 1h-indol-3-ylacetic acid, also known as (indol-3-yl)acetate or heteroauxin, belongs to indole-3-acetic acid derivatives class of compounds. Those are compounds containing an acetic acid (or a derivative) linked to the C3 carbon atom of an indole. 1h-indol-3-ylacetic acid is slightly soluble (in water) and a weakly acidic compound (based on its pKa). 1h-indol-3-ylacetic acid is a mild, odorless, and sour tasting compound and can be found in a number of food items such as sweet bay, chinese bayberry, winter squash, and linden, which makes 1h-indol-3-ylacetic acid a potential biomarker for the consumption of these food products. 1h-indol-3-ylacetic acid can be found primarily in most biofluids, including blood, feces, saliva, and urine, as well as throughout most human tissues. 1h-indol-3-ylacetic acid exists in all living species, ranging from bacteria to humans. In humans, 1h-indol-3-ylacetic acid is involved in the tryptophan metabolism. Moreover, 1h-indol-3-ylacetic acid is found to be associated with appendicitis and irritable bowel syndrome. 1h-indol-3-ylacetic acid is a non-carcinogenic (not listed by IARC) potentially toxic compound. Chronic Exposure: Kidney dialysis is usually needed to relieve the symptoms of uremic syndrome until normal kidney function can be restored. CONFIDENCE standard compound; INTERNAL_ID 190; DATASET 20200303_ENTACT_RP_MIX501; DATA_PROCESSING MERGING RMBmix ver. 0.2.7; DATA_PROCESSING PRESCREENING Shinyscreen ver. 0.8.0; ORIGINAL_ACQUISITION_NO 3375; ORIGINAL_PRECURSOR_SCAN_NO 3371 CONFIDENCE standard compound; INTERNAL_ID 190; DATASET 20200303_ENTACT_RP_MIX501; DATA_PROCESSING MERGING RMBmix ver. 0.2.7; DATA_PROCESSING PRESCREENING Shinyscreen ver. 0.8.0; ORIGINAL_ACQUISITION_NO 3366; ORIGINAL_PRECURSOR_SCAN_NO 3363 CONFIDENCE standard compound; INTERNAL_ID 190; DATASET 20200303_ENTACT_RP_MIX501; DATA_PROCESSING MERGING RMBmix ver. 0.2.7; DATA_PROCESSING PRESCREENING Shinyscreen ver. 0.8.0; ORIGINAL_ACQUISITION_NO 3365; ORIGINAL_PRECURSOR_SCAN_NO 3361 CONFIDENCE standard compound; INTERNAL_ID 190; DATASET 20200303_ENTACT_RP_MIX501; DATA_PROCESSING MERGING RMBmix ver. 0.2.7; DATA_PROCESSING PRESCREENING Shinyscreen ver. 0.8.0; ORIGINAL_ACQUISITION_NO 3395; ORIGINAL_PRECURSOR_SCAN_NO 3391 DATA_PROCESSING MERGING RMBmix ver. 0.2.7; CONFIDENCE standard compound; INTERNAL_ID 190; DATASET 20200303_ENTACT_RP_MIX501; DATA_PROCESSING PRESCREENING Shinyscreen ver. 0.8.0; ORIGINAL_ACQUISITION_NO 3366; ORIGINAL_PRECURSOR_SCAN_NO 3363 CONFIDENCE standard compound; INTERNAL_ID 190; DATASET 20200303_ENTACT_RP_MIX501; DATA_PROCESSING MERGING RMBmix ver. 0.2.7; DATA_PROCESSING PRESCREENING Shinyscreen ver. 0.8.0; ORIGINAL_ACQUISITION_NO 3369; ORIGINAL_PRECURSOR_SCAN_NO 3366 CONFIDENCE standard compound; INTERNAL_ID 190; DATASET 20200303_ENTACT_RP_MIX501; DATA_PROCESSING MERGING RMBmix ver. 0.2.7; DATA_PROCESSING PRESCREENING Shinyscreen ver. 0.8.0; ORIGINAL_ACQUISITION_NO 3385; ORIGINAL_PRECURSOR_SCAN_NO 3380 D006133 - Growth Substances > D010937 - Plant Growth Regulators > D007210 - Indoleacetic Acids Acquisition and generation of the data is financially supported in part by CREST/JST. IPB_RECORD: 275; CONFIDENCE confident structure CONFIDENCE standard compound; INTERNAL_ID 2796 CONFIDENCE standard compound; INTERNAL_ID 166 COVID info from COVID-19 Disease Map Corona-virus KEIO_ID I038 Coronavirus SARS-CoV-2 COVID-19 SARS-CoV COVID19 SARS2 SARS 3-Indoleacetic acid (Indole-3-acetic acid) is the most common natural plant growth hormone of the auxin class. It can be added to cell culture medium to induce plant cell elongation and division. 3-Indoleacetic acid (Indole-3-acetic acid) is the most common natural plant growth hormone of the auxin class. It can be added to cell culture medium to induce plant cell elongation and division.

   

L-Methionine

(2S)-2-amino-4-(methylsulfanyl)butanoic acid

C5H11NO2S (149.0510466)


Methionine (Met), also known as L-methionine, is an alpha-amino acid. These are amino acids in which the amino group is attached to the carbon atom immediately adjacent to the carboxylate group (alpha carbon). Amino acids are organic compounds that contain amino (–NH2) and carboxyl (–COOH) functional groups, along with a side chain (R group) specific to each amino acid. Methionine is one of 20 proteinogenic amino acids, i.e., the amino acids used in the biosynthesis of proteins. Methionine is found in all organisms ranging from bacteria to plants to animals. It is classified as an aliphatic, non-polar amino acid. Methionine is an essential amino acid (there are 9 essential amino acids), meaning the body cannot synthesize it, and it must be obtained from the diet. It is required for normal growth and development of humans, other mammals, and avian species. In addition to being a substrate for protein synthesis, methionine is an intermediate in transmethylation reactions, serving as the major methyl group donor in vivo, including the methyl groups for DNA and RNA intermediates. Methionine is a methyl acceptor for 5-methyltetrahydrofolate-homocysteine methyltransferase (methionine synthase), the only reaction that allows for the recycling of this form of folate, and is also a methyl acceptor for the catabolism of betaine. Methionine is the metabolic precursor for cysteine. Only the sulfur atom from methionine is transferred to cysteine; the carbon skeleton of cysteine is donated by serine (PMID: 16702340 ). There is a general consensus concerning normal sulfur amino acid (SAA) requirements. WHO recommendations amount to 13 mg/kg per 24 h in healthy adults. This amount is roughly doubled in artificial nutrition regimens. In disease or after trauma, requirements may be altered for methionine, cysteine, and taurine. Although in specific cases of congenital enzyme deficiency, prematurity, or diminished liver function, hypermethioninemia or hyperhomocysteinemia may occur, SAA supplementation can be considered safe in amounts exceeding 2-3 times the minimum recommended daily intake. Apart from some very specific indications (e.g. acetaminophen poisoning) the usefulness of SAA supplementation is not yet established (PMID: 16702341 ). Methionine is known to exacerbate psychopathological symptoms in schizophrenic patients, but there is no evidence of similar effects in healthy subjects. The role of methionine as a precursor of homocysteine is the most notable cause for concern. Acute doses of methionine can lead to acute increases in plasma homocysteine, which can be used as an index of the susceptibility to cardiovascular disease. Sufficiently high doses of methionine can actually result in death. Longer-term studies in adults have indicated no adverse consequences of moderate fluctuations in dietary methionine intake, but intakes higher than 5 times the normal amount resulted in elevated homocysteine levels. These effects of methionine on homocysteine and vascular function are moderated by supplements of vitamins B-6, B-12, C, and folic acid (PMID: 16702346 ). When present in sufficiently high levels, methionine can act as an atherogen and a metabotoxin. An atherogen is a compound that when present at chronically high levels causes atherosclerosis and cardiovascular disease. A metabotoxin is an endogenously produced metabolite that causes adverse health effects at chronically high levels. Chronically high levels of methionine are associated with at least ten inborn errors of metabolism, including cystathionine beta-synthase deficiency, glycine N-methyltransferase deficiency, homocystinuria, tyrosinemia, galactosemia, homocystinuria-megaloblastic anemia due to defects in cobalamin metabolism, methionine adenosyltransferase deficiency, methylenetetrahydrofolate reductase deficiency, and S-adenosylhomocysteine (SAH) hydrolase deficiency. Chronically elevated levels of methionine in infants can lead to intellectual disability and othe... [Spectral] L-Methionine (exact mass = 149.05105) and Adenosine (exact mass = 267.09675) and S-Adenosyl-L-homocysteine (exact mass = 384.12159) were not completely separated on HPLC under the present analytical conditions as described in AC$XXX. Additionally some of the peaks in this data contains dimers and other unidentified ions. [Spectral] L-Methionine (exact mass = 149.05105) and Tyramine (exact mass = 137.08406) were not completely separated on HPLC under the present analytical conditions as described in AC$XXX. Additionally some of the peaks in this data contains dimers and other unidentified ions. l-Methionine. CAS Common Chemistry. CAS, a division of the American Chemical Society, n.d. https://commonchemistry.cas.org/detail?cas_rn=63-68-3 (retrieved 2024-07-01) (CAS RN: 63-68-3). Licensed under the Attribution-Noncommercial 4.0 International License (CC BY-NC 4.0). L-Methionine is the L-isomer of Methionine, an essential amino acid for human development. Methionine acts as a hepatoprotectant. L-Methionine is the L-isomer of Methionine, an essential amino acid for human development. Methionine acts as a hepatoprotectant.

   

Malonyl-CoA

3-[(2-{3-[(2R)-3-[({[({[(2R,3S,4R,5R)-5-(6-amino-9H-purin-9-yl)-4-hydroxy-3-(phosphonooxy)oxolan-2-yl]methoxy}(hydroxy)phosphoryl)oxy](hydroxy)phosphoryl}oxy)methyl]-2-hydroxy-3-methylbutanamido]propanamido}ethyl)sulfanyl]-3-oxopropanoic acid

C24H38N7O19P3S (853.1155988)


Malonyl-CoA belongs to the class of organic compounds known as acyl-CoAs. These are organic compounds containing a coenzyme A substructure linked to an acyl chain. Thus, malonyl-CoA is considered to be a fatty ester lipid molecule. Malonyl-CoA is a very hydrophobic molecule, practically insoluble (in water), and relatively neutral. Within humans, malonyl-CoA participates in a number of enzymatic reactions. In particular, malonyl-CoA can be biosynthesized from acetyl-CoA; which is mediated by the enzyme acetyl-CoA carboxylase 1. In addition, malonyl-CoA can be converted into malonic acid and coenzyme A; which is catalyzed by the enzyme fatty acid synthase. Outside of the human body, malonyl-CoA has been detected, but not quantified in, several different foods, such as rapes, mamey sapotes, jews ears, pepper (C. chinense), and Alaska wild rhubarbs. This could make malonyl-CoA a potential biomarker for the consumption of these foods. Malonyl-CoA is a coenzyme A derivative that plays a key role in fatty acid synthesis in the cytoplasmic and microsomal systems. Malonyl-coa, also known as malonyl coenzyme a or coenzyme a, s-(hydrogen propanedioate), is a member of the class of compounds known as acyl coas. Acyl coas are organic compounds containing a coenzyme A substructure linked to an acyl chain. Thus, malonyl-coa is considered to be a fatty ester lipid molecule. Malonyl-coa is slightly soluble (in water) and an extremely strong acidic compound (based on its pKa). Malonyl-coa can be found in a number of food items such as root vegetables, sourdock, ceylon cinnamon, and buffalo currant, which makes malonyl-coa a potential biomarker for the consumption of these food products. Malonyl-coa exists in E.coli (prokaryote) and yeast (eukaryote).

   

Tylosin

2-[(11E,13E)-6-({5-[(4,5-dihydroxy-4,6-dimethyloxan-2-yl)oxy]-4-(dimethylamino)-3-hydroxy-6-methyloxan-2-yl}oxy)-16-ethyl-4-hydroxy-15-{[(5-hydroxy-3,4-dimethoxy-6-methyloxan-2-yl)oxy]methyl}-5,9,13-trimethyl-2,10-dioxo-1-oxacyclohexadeca-11,13-dien-7-yl]acetaldehyde

C46H77NO17 (915.5191232)


Tylosin is used in treatment of cattle, swine and mycoplasmas in poultry Tylosin is a macrolide-class antibiotic used in veterinary medicine. It has a broad spectrum of activity against gram positive organisms and a limited range of gram negative organisms. It is found naturally as a fermentation product of Streptomyces fradiae It is used in treatment of cattle, swine and mycoplasmas in poultry D000890 - Anti-Infective Agents > D000900 - Anti-Bacterial Agents C784 - Protein Synthesis Inhibitor > C261 - Macrolide Antibiotic CONFIDENCE standard compound; EAWAG_UCHEM_ID 187 C254 - Anti-Infective Agent > C258 - Antibiotic CONFIDENCE standard compound; INTERNAL_ID 1057 Tylosin (Tylosin A) is a macrolide antibiotic found naturally as a fermentation product of Streptomyces fradiae. Tylosin exerts potent antimicrobial activity against Gram-positive bacteria. Tylosin is widely used as a feed additive for promoting animal growth. Tylosin is used for veterinary purposes against bacterial dysentery and respiratory diseases in poultry, pigs and cattle[1][2][3].

   

Erythromycin

(3R,4S,5S,6R,7R,9R,11R,12R,13S,14R)-6-{[(2S,3R,4S,6R)-4-(dimethylamino)-3-hydroxy-6-methyltetrahydro-2H-pyran-2-yl]oxy}-14-ethyl-7,12,13-trihydroxy-4-{[(2R,4R,5S,6S)-5-hydroxy-4-methoxy-4,6-dimethyltetrahydro-2H-pyran-2-yl]oxy}-3,5,7,9,11,13-hexamethyloxacyclotetradecane-2,10-dione

C37H67NO13 (733.4612172)


Erythromycin belongs to the class of organic compounds known as xanthines. These are purine derivatives with a ketone group conjugated at carbons 2 and 6 of the purine moiety. Thus, erythromycin is considered to be a macrolide lipid molecule. Erythromycin is a very hydrophobic molecule, practically insoluble (in water), and relatively neutral. Erythromycin is a macrolide antibiotic produced by Streptomyces erythreus. It inhibits bacterial protein synthesis by binding to bacterial 50S ribosomal subunits; binding inhibits peptidyl transferase activity and interferes with the translocation of amino acids during the translation and assembly of proteins. Erythromycin may be bacteriostatic or bactericidal depending on the organism and drug concentration. J - Antiinfectives for systemic use > J01 - Antibacterials for systemic use > J01F - Macrolides, lincosamides and streptogramins > J01FA - Macrolides D - Dermatologicals > D10 - Anti-acne preparations > D10A - Anti-acne preparations for topical use > D10AF - Antiinfectives for treatment of acne S - Sensory organs > S01 - Ophthalmologicals > S01A - Antiinfectives > S01AA - Antibiotics D004791 - Enzyme Inhibitors > D011500 - Protein Synthesis Inhibitors D000890 - Anti-Infective Agents > D000900 - Anti-Bacterial Agents C784 - Protein Synthesis Inhibitor > C261 - Macrolide Antibiotic C254 - Anti-Infective Agent > C258 - Antibiotic D005765 - Gastrointestinal Agents Erythromycin is a macrolide antibiotic produced by actinomycete?Streptomyces erythreus?with a broad spectrum of antimicrobial activity. Erythromycin binds to bacterial 50S ribosomal subunits and inhibits?RNA-dependent protein synthesis?by blockage of transpeptidation and/or translocation reactions, without affecting synthesis of nucleic acid[1][2]. Erythromycin also exhibits antitumor and neuroprotective effect in different fields of research[3][4]. Erythromycin is a macrolide antibiotic produced by actinomycete?Streptomyces erythreus?with a broad spectrum of antimicrobial activity. Erythromycin binds to bacterial 50S ribosomal subunits and inhibits?RNA-dependent protein synthesis?by blockage of transpeptidation and/or translocation reactions, without affecting synthesis of nucleic acid[1][2]. Erythromycin also exhibits antitumor and neuroprotective effect in different fields of research[3][4].

   

Fosfomycin

[(2R,3S)-3-methyloxiran-2-yl]phosphonic acid

C3H7O4P (138.0081952)


Fosfomycin is only found in individuals that have used or taken this drug. It is an antibiotic produced by Streptomyces fradiae. [PubChem]Fosfomycin is a phosphoenolpyruvate analogue produced by Streptomyces that irreversibly inhibits enolpyruvate transferase (MurA), which prevents the formation of N-acetylmuramic acid, an essential element of the peptidoglycan cell wall. S - Sensory organs > S02 - Otologicals > S02A - Antiinfectives > S02AA - Antiinfectives J - Antiinfectives for systemic use > J01 - Antibacterials for systemic use C254 - Anti-Infective Agent > C255 - Urinary Anti-Infective Agent D000890 - Anti-Infective Agents > D000900 - Anti-Bacterial Agents

   

Propionic acid

propionate;Methylacetic acid

C3H6O2 (74.0367776)


Propionic acid (PA) is an organic acid. It exists a clear liquid with a pungent and unpleasant smell somewhat resembling body odor. Propionic acid (PA) is widely used as an antifungal agent in food. It is present naturally at low levels in dairy products and occurs ubiquitously, together with other short-chain fatty acids (SCFA), in the gastro-intestinal tract of humans and other mammals as an end-product of the microbial digestion of carbohydrates. The metabolism of propionic acid begins with its conversion to propionyl coenzyme A, the usual first step in the metabolism of carboxylic acids. Since propionic acid has three carbons, propionyl-CoA cannot directly enter either beta oxidation or the citric acid cycles. In most vertebrates, propionyl-CoA is carboxylated to D-methylmalonyl-CoA, which is isomerised to L-methylmalonyl-CoA. Propionic acid has significant physiological activity in animals. Propionic acid is irritant but produces no acute systemic effects and has no demonstrable genotoxic potential (PMID 1628870). The human skin is host of several species of bacteria known as Propionibacteria, which are named after their ability to produce propionic acid. The most notable one is the Cutibacterium acnes (formerly known as Propionibacterium acnes), which lives mainly in the sebaceous glands of the skin and is one of the principal causes of acne. Propionic aciduria is one of the most frequent organic acidurias, a disease that comprise many various disorders. The outcome of patients born with Propionic aciduria is poor intellectual development patterns, with 60\\\% having an IQ less than 75 and requiring special education. Successful liver and/or renal transplantations, in a few patients, have resulted in better quality of life but have not necessarily prevented neurological and various visceral complications. These results emphasize the need for permanent metabolic follow-up whatever the therapeutic strategy (PMID 15868474). Decreased early mortality, less severe symptoms at diagnosis, and more favorable short-term neurodevelopmental outcome were recorded in patients identified through expanded newborn screening. (PMID 16763906)↵ When propionic acid is infused directly into rodents brains, it produces hyperactivity, dystonia, social impairment, perseveration and brain changes (e.g., innate neuroinflammation, glutathione depletion) that may be used as a means to model autism in rats. Propionic acid is a metabolite of Bacteroides, Clostridium, Dialister, Megasphaera, Phascolarctobacterium, Propionibacterium, Propionigenum, Salmonella, Selenomonas and Veillonella (https://www.mdpi.com/2311-5637/3/2/21). Propionic acid, also known as propionate or ethanecarboxylic acid, is a member of the class of compounds known as carboxylic acids. Carboxylic acids are compounds containing a carboxylic acid group with the formula -C(=O)OH. Thus, propionic acid is considered to be a fatty acid lipid molecule. Propionic acid is soluble (in water) and a weakly acidic compound (based on its pKa). Propionic acid can be found in a number of food items such as celery stalks, burbot, sapodilla, and dock, which makes propionic acid a potential biomarker for the consumption of these food products. Propionic acid can be found primarily in most biofluids, including feces, saliva, blood, and urine, as well as throughout most human tissues. Propionic acid exists in all living species, ranging from bacteria to humans. In humans, propionic acid is involved in a couple of metabolic pathways, which include propanoate metabolism and vitamin K metabolism. Propionic acid is also involved in few metabolic disorders, which include malonic aciduria, malonyl-coa decarboxylase deficiency, and methylmalonic aciduria due to cobalamin-related disorders. Moreover, propionic acid is found to be associated with propionic acidemia. Propionic acid is a non-carcinogenic (not listed by IARC) potentially toxic compound.

   

Vistamycin

ribostamycin

C17H34N4O10 (454.2274824)


J - Antiinfectives for systemic use > J01 - Antibacterials for systemic use > J01G - Aminoglycoside antibacterials C784 - Protein Synthesis Inhibitor > C2363 - Aminoglycoside Antibiotic D000890 - Anti-Infective Agents > D000900 - Anti-Bacterial Agents C254 - Anti-Infective Agent > C258 - Antibiotic KEIO_ID R016

   

2-Deoxystreptamine

4,6-diaminocyclohexane-1,2,3-triol

C6H14N2O3 (162.1004374)


D000890 - Anti-Infective Agents > D000900 - Anti-Bacterial Agents KEIO_ID D061

   

Neomycin

(2S,3S,4R,5R,6R)-5-amino-2-(aminomethyl)-6-{[(2R,3S,4R,5S)-5-{[(1R,2R,3S,5R,6S)-3,5-diamino-2-{[(2R,3R,4R,5S,6R)-3-amino-6-(aminomethyl)-4,5-dihydroxyoxan-2-yl]oxy}-6-hydroxycyclohexyl]oxy}-4-hydroxy-2-(hydroxymethyl)oxolan-3-yl]oxy}oxane-3,4-diol

C23H46N6O13 (614.3122705999999)


A component of neomycin that is produced by Streptomyces fradiae. On hydrolysis it yields neamine and neobiosamine B. (From Merck Index, 11th ed). Neomycin is a bactericidal aminoglycoside antibiotic that binds to the 30S ribosome of susceptible organisms. Binding interferes with mRNA binding and acceptor tRNA sites and results in the production of non-functional or toxic peptides. A - Alimentary tract and metabolism > A01 - Stomatological preparations > A01A - Stomatological preparations > A01AB - Antiinfectives and antiseptics for local oral treatment A - Alimentary tract and metabolism > A07 - Antidiarrheals, intestinal antiinflammatory/antiinfective agents > A07A - Intestinal antiinfectives > A07AA - Antibiotics B - Blood and blood forming organs > B05 - Blood substitutes and perfusion solutions > B05C - Irrigating solutions > B05CA - Antiinfectives D - Dermatologicals > D09 - Medicated dressings > D09A - Medicated dressings > D09AA - Medicated dressings with antiinfectives D - Dermatologicals > D06 - Antibiotics and chemotherapeutics for dermatological use > D06A - Antibiotics for topical use S - Sensory organs > S03 - Ophthalmological and otological preparations > S03A - Antiinfectives > S03AA - Antiinfectives R - Respiratory system > R01 - Nasal preparations > R01A - Decongestants and other nasal preparations for topical use J - Antiinfectives for systemic use > J01 - Antibacterials for systemic use > J01G - Aminoglycoside antibacterials R - Respiratory system > R02 - Throat preparations > R02A - Throat preparations > R02AB - Antibiotics S - Sensory organs > S01 - Ophthalmologicals > S01A - Antiinfectives > S01AA - Antibiotics S - Sensory organs > S02 - Otologicals > S02A - Antiinfectives > S02AA - Antiinfectives C784 - Protein Synthesis Inhibitor > C2363 - Aminoglycoside Antibiotic D004791 - Enzyme Inhibitors > D011500 - Protein Synthesis Inhibitors D000890 - Anti-Infective Agents > D000900 - Anti-Bacterial Agents C254 - Anti-Infective Agent > C258 - Antibiotic KEIO_ID N022

   

Paromomycin

(2S,3S,4R,5R,6R)-5-amino-2-(aminomethyl)-6-{[(2R,3S,4R,5S)-5-{[(1R,2R,3S,5R,6S)-3,5-diamino-2-{[(2S,3R,4R,5S,6R)-3-amino-4,5-dihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-6-hydroxycyclohexyl]oxy}-4-hydroxy-2-(hydroxymethyl)oxolan-3-yl]oxy}oxane-3,4-diol

C23H45N5O14 (615.296287)


Paromomycin is only found in individuals that have used or taken this drug. It is an oligosaccharide antibiotic produced by various streptomyces. [PubChem]Paromomycin inhibits protein synthesis by binding to 16S ribosomal RNA. Bacterial proteins are synthesized by ribosomal RNA complexes which are composed of 2 subunits, a large subunit (50s) and small (30s) subunit, which forms a 70s ribosomal subunit. tRNA binds to the top of this ribosomal structure. Paramomycin binds to the A site, which causes defective polypeptide chains to be produced. Continuous production of defective proteins eventually leads to bacterial death. A - Alimentary tract and metabolism > A07 - Antidiarrheals, intestinal antiinflammatory/antiinfective agents > A07A - Intestinal antiinfectives > A07AA - Antibiotics D000890 - Anti-Infective Agents > D000977 - Antiparasitic Agents > D000981 - Antiprotozoal Agents C784 - Protein Synthesis Inhibitor > C2363 - Aminoglycoside Antibiotic D000890 - Anti-Infective Agents > D000900 - Anti-Bacterial Agents C254 - Anti-Infective Agent > C258 - Antibiotic KEIO_ID P126

   

Geosmin

[4S-(4alpha,4aalpha,8abeta)]-Octahydro-4,8a-dimethyl-4a(2H)-naphthalenol

C12H22O (182.1670562)


Geosmin is found in corn. Implicated in off-flavour of shellfish, freshwater fish, drinking water and some vegetables.Geosmin, which literally translates to "earth smell", is an organic compound with a distinct earthy flavour and aroma, and is responsible for the earthy taste of beets and a contributor to the strong scent that occurs in the air when rain falls after a dry spell of weather (petrichor) or when soil is disturbed. The human nose is extremely sensitive to geosmin and is able to detect it at concentrations as low as 5 parts per trillion. Implicated in off-flavour of shellfish, freshwater fish, drinking water and some vegetables

   

Macrocin

2-[6-[5-(4,5-dihydroxy-4,6-dimethyloxan-2-yl)oxy-4-(dimethylamino)-3-hydroxy-6-methyloxan-2-yl]oxy-15-[(4,5-dihydroxy-3-methoxy-6-methyloxan-2-yl)oxymethyl]-16-ethyl-4-hydroxy-5,9,13-trimethyl-2,10-dioxo-1-oxacyclohexadeca-11,13-dien-7-yl]acetaldehyde

C45H75NO17 (901.5034740000001)


A macrolide antibiotic that is tylonolide having mono- and diglycosyl moieties attached to two of its hydroxy groups. D000890 - Anti-Infective Agents > D000900 - Anti-Bacterial Agents > D007933 - Leucomycins

   

neamine

5-amino-2-(aminomethyl)-6-(4,6-diamino-2,3-dihydroxycyclohexyl)oxyoxane-3,4-diol

C12H26N4O6 (322.18522559999997)


C784 - Protein Synthesis Inhibitor > C2363 - Aminoglycoside Antibiotic C254 - Anti-Infective Agent > C258 - Antibiotic

   
   
   

staurosporine

2,3,10,11,12,13-hexahydro-10R-methoxy-9S-methyl-11R-methylamino-9S,13R-epoxy-1H,9H-diindolo[1,2,3-gh;3,2,1-lm]pyrrolo[3,4-j][1,7]benzodiazonin-1-one

C28H26N4O3 (466.2004806)


C471 - Enzyme Inhibitor > C1404 - Protein Kinase Inhibitor D004791 - Enzyme Inhibitors Staurosporine is a potent, ATP-competitive and non-selective inhibitor of protein kinases with IC50s of 6 nM, 15 nM, 2 nM, and 3 nM for PKC, PKA, c-Fgr, and Phosphorylase kinase respectively. Staurosporine also inhibits TAOK2 with an IC50 of 3 μM. Staurosporine is an apoptosis inducer[1][2][3][4][5].

   

Tylactone

Tylactone; Protylonolide

C23H38O5 (394.2719098)


A 16-membererd macrolide that is the aglycone of the antibiotic 5-O-beta-D-mycaminosyltylactone.

   
   
   
   

Landomycin A

Landomycin A

C55H74O22 (1086.4671504)


A natural product found in Streptomyces cyanogenus.

   

Methylmalonyl-CoA

Methylmalonyl-CoA

C25H40N7O19P3S (867.131248)


A member of the class of malonyl-CoAs that is malonyl-CoA carrying a methyl group on the malony side chain.

   
   
   

Frenolicin B

4-hydroxy-17-propyl-12,16-dioxatetracyclo[8.7.0.0³,⁸.0¹¹,¹⁵]heptadeca-1(10),3(8),4,6-tetraene-2,9,13-trione

C18H16O6 (328.0946836)


Antibiotic feed additive especially for poultry and pigs. Antibiotic feed additive especies for poultry and pigs.

   

Paromomycin I

5-amino-2-(aminomethyl)-6-({5-[(3,5-diamino-2-{[3-amino-4,5-dihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}-6-hydroxycyclohexyl)oxy]-4-hydroxy-2-(hydroxymethyl)oxolan-3-yl}oxy)oxane-3,4-diol

C23H45N5O14 (615.296287)


D000890 - Anti-Infective Agents > D000977 - Antiparasitic Agents > D000981 - Antiprotozoal Agents D000890 - Anti-Infective Agents > D000900 - Anti-Bacterial Agents

   

Neomycin sulfate

5-amino-2-(aminomethyl)-6-({5-[(3,5-diamino-2-{[3-amino-6-(aminomethyl)-4,5-dihydroxyoxan-2-yl]oxy}-6-hydroxycyclohexyl)oxy]-4-hydroxy-2-(hydroxymethyl)oxolan-3-yl}oxy)oxane-3,4-diol

C23H46N6O13 (614.3122705999999)


   

2-Deoxystreptamine

4,6-diaminocyclohexane-1,2,3-triol

C6H14N2O3 (162.1004374)


   

INDOLE-2-ACETIC ACID

2-(1H-indol-2-yl)acetic acid

C10H9NO2 (175.0633254)


   

midecamycin

6-{[4-(dimethylamino)-5-hydroxy-6-{[10-hydroxy-5-methoxy-9,16-dimethyl-2-oxo-7-(2-oxoethyl)-4-(propanoyloxy)-1-oxacyclohexadeca-11,13-dien-6-yl]oxy}-2-methyloxan-3-yl]oxy}-4-hydroxy-2,4-dimethyloxan-3-yl propanoic acid

C41H67NO15 (813.4510472)


   

Neamine

5-amino-2-(aminomethyl)-6-[(4,6-diamino-2,3-dihydroxycyclohexyl)oxy]oxane-3,4-diol

C12H26N4O6 (322.18522559999997)


   

ribostamycin

5-amino-2-(aminomethyl)-6-[(4,6-diamino-2-{[3,4-dihydroxy-5-(hydroxymethyl)oxolan-2-yl]oxy}-3-hydroxycyclohexyl)oxy]oxane-3,4-diol

C17H34N4O10 (454.2274824)


   

Indoleacetic acid

Indole-3-acetic acid

C10H9NO2 (175.0633254)


D006133 - Growth Substances > D010937 - Plant Growth Regulators > D007210 - Indoleacetic Acids COVID info from COVID-19 Disease Map Corona-virus Coronavirus SARS-CoV-2 COVID-19 SARS-CoV COVID19 SARS2 SARS 3-Indoleacetic acid (Indole-3-acetic acid) is the most common natural plant growth hormone of the auxin class. It can be added to cell culture medium to induce plant cell elongation and division. 3-Indoleacetic acid (Indole-3-acetic acid) is the most common natural plant growth hormone of the auxin class. It can be added to cell culture medium to induce plant cell elongation and division.

   

midecamycin

Midecamicina

C41H67NO15 (813.4510472)


J - Antiinfectives for systemic use > J01 - Antibacterials for systemic use > J01F - Macrolides, lincosamides and streptogramins > J01FA - Macrolides D000890 - Anti-Infective Agents > D000900 - Anti-Bacterial Agents > D007933 - Leucomycins C784 - Protein Synthesis Inhibitor > C261 - Macrolide Antibiotic C254 - Anti-Infective Agent > C258 - Antibiotic Midecamycin, an acetoxy-substituted macrolide antibiotic, is tested against gram-positive and gram-negative bacteria.

   
   

Erythromycin

Erythromycin (E-Mycin)

C37H67NO13 (733.4612172)


J - Antiinfectives for systemic use > J01 - Antibacterials for systemic use > J01F - Macrolides, lincosamides and streptogramins > J01FA - Macrolides D - Dermatologicals > D10 - Anti-acne preparations > D10A - Anti-acne preparations for topical use > D10AF - Antiinfectives for treatment of acne S - Sensory organs > S01 - Ophthalmologicals > S01A - Antiinfectives > S01AA - Antibiotics D004791 - Enzyme Inhibitors > D011500 - Protein Synthesis Inhibitors D000890 - Anti-Infective Agents > D000900 - Anti-Bacterial Agents C784 - Protein Synthesis Inhibitor > C261 - Macrolide Antibiotic C254 - Anti-Infective Agent > C258 - Antibiotic D005765 - Gastrointestinal Agents Origin: Microbe CONFIDENCE standard compound; INTERNAL_ID 1054 relative retention time with respect to 9-anthracene Carboxylic Acid is 1.021 CONFIDENCE standard compound; INTERNAL_ID 4074 Acquisition and generation of the data is financially supported by the Max-Planck-Society IPB_RECORD: 2341; CONFIDENCE confident structure CONFIDENCE standard compound; EAWAG_UCHEM_ID 189 Erythromycin is a macrolide antibiotic produced by actinomycete?Streptomyces erythreus?with a broad spectrum of antimicrobial activity. Erythromycin binds to bacterial 50S ribosomal subunits and inhibits?RNA-dependent protein synthesis?by blockage of transpeptidation and/or translocation reactions, without affecting synthesis of nucleic acid[1][2]. Erythromycin also exhibits antitumor and neuroprotective effect in different fields of research[3][4]. Erythromycin is a macrolide antibiotic produced by actinomycete?Streptomyces erythreus?with a broad spectrum of antimicrobial activity. Erythromycin binds to bacterial 50S ribosomal subunits and inhibits?RNA-dependent protein synthesis?by blockage of transpeptidation and/or translocation reactions, without affecting synthesis of nucleic acid[1][2]. Erythromycin also exhibits antitumor and neuroprotective effect in different fields of research[3][4].

   

Tylosin

2-[(4S,5R,6R,7S,9S,11E,13E,15S,16S)-6-[(2S,3S,4S,5R,6S)-5-[(2R,4S,5R,6R)-4,5-dihydroxy-4,6-dimethyloxan-2-yl]oxy-4-(dimethylamino)-3-hydroxy-6-methyloxan-2-yl]oxy-16-ethyl-4-hydroxy-15-[[(2S,3S,4S,5S,6S)-5-hydroxy-3,4-dimethoxy-6-methyloxan-2-yl]oxymethyl]-5,9,13-trimethyl-2,10-dioxo-1-oxacyclohexadeca-11,13-dien-7-yl]acetaldehyde

C46H77NO17 (915.5191232)


A macrolide antibiotic that is tylonolide having mono- and diglycosyl moieties attached to two of its hydroxy groups. It is found naturally as a fermentation product of Streptomyces fradiae. D000890 - Anti-Infective Agents > D000900 - Anti-Bacterial Agents C784 - Protein Synthesis Inhibitor > C261 - Macrolide Antibiotic C254 - Anti-Infective Agent > C258 - Antibiotic CONFIDENCE standard compound; INTERNAL_ID 2519 CONFIDENCE standard compound; INTERNAL_ID 1057 Tylosin (Tylosin A) is a macrolide antibiotic found naturally as a fermentation product of Streptomyces fradiae. Tylosin exerts potent antimicrobial activity against Gram-positive bacteria. Tylosin is widely used as a feed additive for promoting animal growth. Tylosin is used for veterinary purposes against bacterial dysentery and respiratory diseases in poultry, pigs and cattle[1][2][3].

   

L-Methionine

L-Methionine

C5H11NO2S (149.0510466)


The L-enantiomer of methionine. MS2 deconvoluted using MS2Dec from all ion fragmentation data, MetaboLights identifier MTBLS1040; FFEARJCKVFRZRR-BYPYZUCNSA-N_STSL_0047_Methionine_8000fmol_180416_S2_LC02_MS02_69; Spectrum acquired as described in Naz et al 2017 PMID 28641411. Preparation and submission to MassBank of North America by Chaleckis R. and Tada I. MS2 deconvoluted using CorrDec from all ion fragmentation data, MetaboLights identifier MTBLS1040; Spectrum acquired as described in Naz et al 2017 PMID 28641411. Preparation and submission to MassBank of North America by Chaleckis R. and Tada I. L-Methionine is the L-isomer of Methionine, an essential amino acid for human development. Methionine acts as a hepatoprotectant. L-Methionine is the L-isomer of Methionine, an essential amino acid for human development. Methionine acts as a hepatoprotectant.

   

3-Indoleacetic acid

Indole-3-acetic acid

C10H9NO2 (175.0633254)


A monocarboxylic acid that is acetic acid in which one of the methyl hydrogens has been replaced by a 1H-indol-3-yl group. D006133 - Growth Substances > D010937 - Plant Growth Regulators > D007210 - Indoleacetic Acids COVID info from COVID-19 Disease Map Corona-virus Coronavirus SARS-CoV-2 COVID-19 SARS-CoV COVID19 SARS2 SARS MS2 deconvoluted using MS2Dec from all ion fragmentation data, MetaboLights identifier MTBLS1040; SEOVTRFCIGRIMH-UHFFFAOYSA-N_STSL_0200_3-Indoleacetic Acid_2000fmol_180831_S2_L02M02_62; Spectrum acquired as described in Naz et al 2017 PMID 28641411. Preparation and submission to MassBank of North America by Chaleckis R. and Tada I. MS2 deconvoluted using CorrDec from all ion fragmentation data, MetaboLights identifier MTBLS1040; Spectrum acquired as described in Naz et al 2017 PMID 28641411. Preparation and submission to MassBank of North America by Chaleckis R. and Tada I. 3-Indoleacetic acid (Indole-3-acetic acid) is the most common natural plant growth hormone of the auxin class. It can be added to cell culture medium to induce plant cell elongation and division. 3-Indoleacetic acid (Indole-3-acetic acid) is the most common natural plant growth hormone of the auxin class. It can be added to cell culture medium to induce plant cell elongation and division.

   

propionic acid

propionic acid

C3H6O2 (74.0367776)


A short-chain saturated fatty acid comprising ethane attached to the carbon of a carboxy group.

   

Neomycin C

Neomycin C

C23H46N6O13 (614.3122705999999)


C784 - Protein Synthesis Inhibitor > C2363 - Aminoglycoside Antibiotic C254 - Anti-Infective Agent > C258 - Antibiotic

   

FA 3:0

propionate;Methylacetic acid

C3H6O2 (74.0367776)


   

diamino-pimelic acid

2,6-diamino-heptanedioic acid

C7H14N2O4 (190.0953524)


   

Malonyl CoA

Coenzyme A, S-(hydrogen propanedioate);S-(Hydrogen malonyl)coenzyme A

C24H38N7O19P3S (853.1155988)


   

3-IAA

InChI=1\C10H9NO2\c12-10(13)5-7-6-11-9-4-2-1-3-8(7)9\h1-4,6,11H,5H2,(H,12,13

C10H9NO2 (175.0633254)


D006133 - Growth Substances > D010937 - Plant Growth Regulators > D007210 - Indoleacetic Acids COVID info from COVID-19 Disease Map Corona-virus Coronavirus SARS-CoV-2 COVID-19 SARS-CoV COVID19 SARS2 SARS 3-Indoleacetic acid (Indole-3-acetic acid) is the most common natural plant growth hormone of the auxin class. It can be added to cell culture medium to induce plant cell elongation and division. 3-Indoleacetic acid (Indole-3-acetic acid) is the most common natural plant growth hormone of the auxin class. It can be added to cell culture medium to induce plant cell elongation and division.

   

Adofeed

Top distillation cut by-product acids, monobasic (C1-C5)

C3H6O2 (74.0367776)


   

Geosmin

[4S-(4alpha,4aalpha,8abeta)]-Octahydro-4,8a-dimethyl-4a(2H)-naphthalenol

C12H22O (182.1670562)


   

Mycinose

6-Deoxy-2,3-di-O-methyl-D-allo-hexose

C8H16O5 (192.0997686)


   
   
   

Framycetin

Framycetin

C23H46N6O13 (614.3122705999999)


A - Alimentary tract and metabolism > A01 - Stomatological preparations > A01A - Stomatological preparations > A01AB - Antiinfectives and antiseptics for local oral treatment A - Alimentary tract and metabolism > A07 - Antidiarrheals, intestinal antiinflammatory/antiinfective agents > A07A - Intestinal antiinfectives > A07AA - Antibiotics B - Blood and blood forming organs > B05 - Blood substitutes and perfusion solutions > B05C - Irrigating solutions > B05CA - Antiinfectives D - Dermatologicals > D09 - Medicated dressings > D09A - Medicated dressings > D09AA - Medicated dressings with antiinfectives D - Dermatologicals > D06 - Antibiotics and chemotherapeutics for dermatological use > D06A - Antibiotics for topical use S - Sensory organs > S03 - Ophthalmological and otological preparations > S03A - Antiinfectives > S03AA - Antiinfectives R - Respiratory system > R01 - Nasal preparations > R01A - Decongestants and other nasal preparations for topical use J - Antiinfectives for systemic use > J01 - Antibacterials for systemic use > J01G - Aminoglycoside antibacterials A tetracyclic antibacterial agent derived from neomycin, being a glycoside ester of neamine and neobiosamine B. R - Respiratory system > R02 - Throat preparations > R02A - Throat preparations > R02AB - Antibiotics S - Sensory organs > S01 - Ophthalmologicals > S01A - Antiinfectives > S01AA - Antibiotics S - Sensory organs > S02 - Otologicals > S02A - Antiinfectives > S02AA - Antiinfectives C784 - Protein Synthesis Inhibitor > C2363 - Aminoglycoside Antibiotic D000890 - Anti-Infective Agents > D000900 - Anti-Bacterial Agents C254 - Anti-Infective Agent > C258 - Antibiotic

   

Fosfomycin

Fosfomycin

C3H7O4P (138.0081952)


S - Sensory organs > S02 - Otologicals > S02A - Antiinfectives > S02AA - Antiinfectives A phosphonic acid having an (R,S)-1,2-epoxypropyl group attached to phosphorus. J - Antiinfectives for systemic use > J01 - Antibacterials for systemic use C254 - Anti-Infective Agent > C255 - Urinary Anti-Infective Agent D000890 - Anti-Infective Agents > D000900 - Anti-Bacterial Agents

   

Paromomycin

D-Streptamine,O-2,6-diamino-2,6-dideoxy-b-L-idopyranosyl-(1®3)-O-b-D-ribofuranosyl-(1®5)-O-[2-amino-2-deoxy-a-D-glucopyranosyl-(1®4)]-2-deoxy-

C23H45N5O14 (615.296287)


An amino cyclitol glycoside that is the 1-O-(2-amino-2-deoxy-alpha-D-glucopyranoside) and the 3-O-(2,6-diamino-2,6-dideoxy-beta-L-idopyranosyl)-beta-D-ribofuranoside of 4,6-diamino-2,3-dihydroxycyclohexane (the 1R,2R,3S,4R,6S diastereoisomer). It is obtained from various Streptomyces species. A broad-spectrum antibiotic, it is used (generally as the sulfate salt) for the treatment of acute and chronic intestinal protozoal infections, but is not effective for extraintestinal protozoal infections. It is also used as a therapeutic against visceral leishmaniasis. A - Alimentary tract and metabolism > A07 - Antidiarrheals, intestinal antiinflammatory/antiinfective agents > A07A - Intestinal antiinfectives > A07AA - Antibiotics D000890 - Anti-Infective Agents > D000977 - Antiparasitic Agents > D000981 - Antiprotozoal Agents C784 - Protein Synthesis Inhibitor > C2363 - Aminoglycoside Antibiotic D000890 - Anti-Infective Agents > D000900 - Anti-Bacterial Agents C254 - Anti-Infective Agent > C258 - Antibiotic

   

ribostamycin

ribostamycin

C17H34N4O10 (454.2274824)


An amino cyclitol glycoside that is 4,6-diaminocyclohexane-1,2,3-triol having a 2,6-diamino-2,6-dideoxy-alpha-D-glucosyl residue attached at position 1 and a beta-D-ribosyl residue attached at position 2. It is an antibiotic produced by Streptomyces ribosidificus (formerly S. thermoflavus). J - Antiinfectives for systemic use > J01 - Antibacterials for systemic use > J01G - Aminoglycoside antibacterials C784 - Protein Synthesis Inhibitor > C2363 - Aminoglycoside Antibiotic D000890 - Anti-Infective Agents > D000900 - Anti-Bacterial Agents C254 - Anti-Infective Agent > C258 - Antibiotic

   

(6S,2S)-Diaminopimelic acid

(2S,6S)-2,6-diaminoheptanedioic acid

C7H14N2O4 (190.0953524)


   

Malonyl-CoA

Malonyl-CoA

C24H38N7O19P3S (853.1155988)


The S-malonyl derivative of coenzyme A.

   

6-(2,3,4a,8,12b-pentahydroxy-3-methyl-1,7,12-trioxo-2,4-dihydrotetraphen-9-yl)-2-methyloxan-3-yl 7-(2-acetyl-2,5-dimethyl-1,3-dioxolan-4-yl)hepta-2,4,6-trienoate

6-(2,3,4a,8,12b-pentahydroxy-3-methyl-1,7,12-trioxo-2,4-dihydrotetraphen-9-yl)-2-methyloxan-3-yl 7-(2-acetyl-2,5-dimethyl-1,3-dioxolan-4-yl)hepta-2,4,6-trienoate

C39H42O14 (734.2574432)


   

(2s,4s,5s)-2,4-dimethyl-5-[(1e,3e,5e)-7-oxoocta-1,3,5-trien-1-yl]-1,3-dioxolane-2-carboxylic acid

(2s,4s,5s)-2,4-dimethyl-5-[(1e,3e,5e)-7-oxoocta-1,3,5-trien-1-yl]-1,3-dioxolane-2-carboxylic acid

C14H18O5 (266.1154178)


   

(4r)-4-{[(1s)-1-{[(3s,9r,15s,18r,21s,24s,30s,31r)-18-(4-aminobutyl)-15-[carboxy(hydroxy)methyl]-6-(2-carboxyethyl)-21-(carboxymethyl)-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-24,28,31-trimethyl-2,29-dioxo-3-(sec-butyl)-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-hydroxy-2-(c-hydroxycarbonimidoyl)ethyl]-c-hydroxycarbonimidoyl}-4-{[(2s)-1-hydroxy-2-[(1-hydroxy-8-methyldecylidene)amino]-3-(1h-indol-3-yl)propylidene]amino}butanoic acid

(4r)-4-{[(1s)-1-{[(3s,9r,15s,18r,21s,24s,30s,31r)-18-(4-aminobutyl)-15-[carboxy(hydroxy)methyl]-6-(2-carboxyethyl)-21-(carboxymethyl)-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-24,28,31-trimethyl-2,29-dioxo-3-(sec-butyl)-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-hydroxy-2-(c-hydroxycarbonimidoyl)ethyl]-c-hydroxycarbonimidoyl}-4-{[(2s)-1-hydroxy-2-[(1-hydroxy-8-methyldecylidene)amino]-3-(1h-indol-3-yl)propylidene]amino}butanoic acid

C72H109N17O27 (1643.7678444)


   

methyl 3-[(4,5-dihydroxy-6-methyloxan-2-yl)oxy]-6a,7,10a,12-tetrahydroxy-8-methoxy-1-methyl-6,10,11-trioxo-7h-tetracene-2-carboxylate

methyl 3-[(4,5-dihydroxy-6-methyloxan-2-yl)oxy]-6a,7,10a,12-tetrahydroxy-8-methoxy-1-methyl-6,10,11-trioxo-7h-tetracene-2-carboxylate

C28H28O14 (588.1478988)


   

methyl (6ar,7r,10ar)-3,6a,7,8,10a,12-hexahydroxy-1-methyl-6,10,11-trioxo-7h-tetracene-2-carboxylate

methyl (6ar,7r,10ar)-3,6a,7,8,10a,12-hexahydroxy-1-methyl-6,10,11-trioxo-7h-tetracene-2-carboxylate

C21H16O11 (444.0692586)


   

(4r)-4-{[(1s)-1-{[(3s,9r,15s,18r,21s,24s,30s,31r)-18-(4-aminobutyl)-15-[carboxy(hydroxy)methyl]-6-(2-carboxyethyl)-21-(carboxymethyl)-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-24,28,31-trimethyl-2,29-dioxo-3-(sec-butyl)-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-(c-hydroxycarbonimidoyl)ethyl]-c-hydroxycarbonimidoyl}-4-{[(2s)-1-hydroxy-2-[(1-hydroxy-8-methyldecylidene)amino]-3-(1h-indol-3-yl)propylidene]amino}butanoic acid

(4r)-4-{[(1s)-1-{[(3s,9r,15s,18r,21s,24s,30s,31r)-18-(4-aminobutyl)-15-[carboxy(hydroxy)methyl]-6-(2-carboxyethyl)-21-(carboxymethyl)-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-24,28,31-trimethyl-2,29-dioxo-3-(sec-butyl)-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-(c-hydroxycarbonimidoyl)ethyl]-c-hydroxycarbonimidoyl}-4-{[(2s)-1-hydroxy-2-[(1-hydroxy-8-methyldecylidene)amino]-3-(1h-indol-3-yl)propylidene]amino}butanoic acid

C72H109N17O26 (1627.7729294)


   

(3s,6r,8r)-15-[(4r,5r,6r)-4-{[(2s,5s,6s)-5-{[(2s,4r,5s,6r)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}-6-methyloxan-2-yl]oxy}-5-hydroxy-6-methyloxan-2-yl]-6,8,14-trihydroxy-3-{[(2s,5s,6s)-5-hydroxy-6-methyloxan-2-yl]oxy}-18-(1h-indol-3-yl)-6-methyl-20-oxapentacyclo[11.7.1.0²,¹¹.0³,⁸.0¹⁷,²¹]henicosa-1(21),2(11),9,13,15,17-hexaene-4,12,19-trione

(3s,6r,8r)-15-[(4r,5r,6r)-4-{[(2s,5s,6s)-5-{[(2s,4r,5s,6r)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}-6-methyloxan-2-yl]oxy}-5-hydroxy-6-methyloxan-2-yl]-6,8,14-trihydroxy-3-{[(2s,5s,6s)-5-hydroxy-6-methyloxan-2-yl]oxy}-18-(1h-indol-3-yl)-6-methyl-20-oxapentacyclo[11.7.1.0²,¹¹.0³,⁸.0¹⁷,²¹]henicosa-1(21),2(11),9,13,15,17-hexaene-4,12,19-trione

C53H61NO18 (999.3888446000001)


   

15-[4-({5-[(4,5-dihydroxy-6-methyloxan-2-yl)oxy]-6-methyloxan-2-yl}oxy)-5-hydroxy-6-methyloxan-2-yl]-6,8,12-trihydroxy-3-[(5-hydroxy-6-methyloxan-2-yl)oxy]-18-(4-hydroxyphenyl)-6-methyl-19-oxapentacyclo[11.6.1.0²,¹¹.0³,⁸.0¹⁷,²⁰]icosa-1,9,11,13(20),15,17-hexaene-4,14-dione

15-[4-({5-[(4,5-dihydroxy-6-methyloxan-2-yl)oxy]-6-methyloxan-2-yl}oxy)-5-hydroxy-6-methyloxan-2-yl]-6,8,12-trihydroxy-3-[(5-hydroxy-6-methyloxan-2-yl)oxy]-18-(4-hydroxyphenyl)-6-methyl-19-oxapentacyclo[11.6.1.0²,¹¹.0³,⁸.0¹⁷,²⁰]icosa-1,9,11,13(20),15,17-hexaene-4,14-dione

C50H60O18 (948.3779460000001)


   

4-[(1-{[18-(4-aminobutyl)-15-[carboxy(hydroxy)methyl]-6-(2-carboxyethyl)-21-(carboxymethyl)-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-24,28,31-trimethyl-2,29-dioxo-3-(sec-butyl)-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-hydroxy-2-(c-hydroxycarbonimidoyl)ethyl)-c-hydroxycarbonimidoyl]-4-({1-hydroxy-2-[(1-hydroxy-8-methyldecylidene)amino]-3-(1h-indol-3-yl)propylidene}amino)butanoic acid

4-[(1-{[18-(4-aminobutyl)-15-[carboxy(hydroxy)methyl]-6-(2-carboxyethyl)-21-(carboxymethyl)-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-24,28,31-trimethyl-2,29-dioxo-3-(sec-butyl)-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-hydroxy-2-(c-hydroxycarbonimidoyl)ethyl)-c-hydroxycarbonimidoyl]-4-({1-hydroxy-2-[(1-hydroxy-8-methyldecylidene)amino]-3-(1h-indol-3-yl)propylidene}amino)butanoic acid

C72H109N17O27 (1643.7678444)


   

(4r)-4-{[(1s,2r)-1-{[(3s,6s,9r,15s,18r,21s,24s,30s,31r)-18-(4-aminobutyl)-3-[(2s)-butan-2-yl]-15-[(r)-carboxy(methoxy)methyl]-21-(carboxymethyl)-6-[(2r)-1-carboxypropan-2-yl]-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-24,28,31-trimethyl-2,29-dioxo-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-hydroxy-2-(c-hydroxycarbonimidoyl)ethyl]-c-hydroxycarbonimidoyl}-4-{[(2s)-1-hydroxy-2-[(1-hydroxy-8-methyldecylidene)amino]-3-(1h-indol-3-yl)propylidene]amino}butanoic acid

(4r)-4-{[(1s,2r)-1-{[(3s,6s,9r,15s,18r,21s,24s,30s,31r)-18-(4-aminobutyl)-3-[(2s)-butan-2-yl]-15-[(r)-carboxy(methoxy)methyl]-21-(carboxymethyl)-6-[(2r)-1-carboxypropan-2-yl]-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-24,28,31-trimethyl-2,29-dioxo-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-hydroxy-2-(c-hydroxycarbonimidoyl)ethyl]-c-hydroxycarbonimidoyl}-4-{[(2s)-1-hydroxy-2-[(1-hydroxy-8-methyldecylidene)amino]-3-(1h-indol-3-yl)propylidene]amino}butanoic acid

C74H113N17O27 (1671.7991428)


   

(3s,6r,8r)-15-[(2r,4s,5r,6r)-4-{[(2s,5s,6s)-5-{[(2s,4r,5s,6r)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}-6-methyloxan-2-yl]oxy}-5-hydroxy-6-methyloxan-2-yl]-6,8,12-trihydroxy-3-{[(2s,5s,6s)-5-hydroxy-6-methyloxan-2-yl]oxy}-18-(4-hydroxyphenyl)-6-methyl-20-oxapentacyclo[11.7.1.0²,¹¹.0³,⁸.0¹⁷,²¹]henicosa-1,9,11,13(21),15,17-hexaene-4,14,19-trione

(3s,6r,8r)-15-[(2r,4s,5r,6r)-4-{[(2s,5s,6s)-5-{[(2s,4r,5s,6r)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}-6-methyloxan-2-yl]oxy}-5-hydroxy-6-methyloxan-2-yl]-6,8,12-trihydroxy-3-{[(2s,5s,6s)-5-hydroxy-6-methyloxan-2-yl]oxy}-18-(4-hydroxyphenyl)-6-methyl-20-oxapentacyclo[11.7.1.0²,¹¹.0³,⁸.0¹⁷,²¹]henicosa-1,9,11,13(21),15,17-hexaene-4,14,19-trione

C51H60O19 (976.3728610000001)


   

(2s,4s,5s)-2,4-dimethyl-5-[(1e,3e,5e)-7-{[(2r,3s,6r)-2-methyl-6-(2,3,5,8-tetrahydroxy-3-methyl-1,7,12-trioxo-2,4-dihydrotetraphen-9-yl)oxan-3-yl]oxy}-7-oxohepta-1,3,5-trien-1-yl]-1,3-dioxolane-2-carboxylic acid

(2s,4s,5s)-2,4-dimethyl-5-[(1e,3e,5e)-7-{[(2r,3s,6r)-2-methyl-6-(2,3,5,8-tetrahydroxy-3-methyl-1,7,12-trioxo-2,4-dihydrotetraphen-9-yl)oxan-3-yl]oxy}-7-oxohepta-1,3,5-trien-1-yl]-1,3-dioxolane-2-carboxylic acid

C38H38O14 (718.2261447999999)


   

2-[(4r,5r,6s,7r,9s,11z,13e,15r,16r)-6-{[(2s,3s,4r,5s,6r)-5-{[(2r,4s,5s,6r)-4,5-dihydroxy-4,6-dimethyloxan-2-yl]oxy}-4-(dimethylamino)-3-hydroxy-6-methyloxan-2-yl]oxy}-16-ethyl-4-hydroxy-5,9,13-trimethyl-2,10-dioxo-15-({[(2s,3s,4r,5s,6r)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxy}methyl)-1-oxacyclohexadeca-11,13-dien-7-yl]acetaldehyde

2-[(4r,5r,6s,7r,9s,11z,13e,15r,16r)-6-{[(2s,3s,4r,5s,6r)-5-{[(2r,4s,5s,6r)-4,5-dihydroxy-4,6-dimethyloxan-2-yl]oxy}-4-(dimethylamino)-3-hydroxy-6-methyloxan-2-yl]oxy}-16-ethyl-4-hydroxy-5,9,13-trimethyl-2,10-dioxo-15-({[(2s,3s,4r,5s,6r)-3,4,5-trihydroxy-6-methyloxan-2-yl]oxy}methyl)-1-oxacyclohexadeca-11,13-dien-7-yl]acetaldehyde

C44H73NO17 (887.4878248)


   

(4r)-4-{[(1s)-1-{[(3s,9r,15s,18r,21s,24s,30s,31r)-18-(4-aminobutyl)-15,21-bis(carboxymethyl)-6-(1-carboxypropan-2-yl)-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-24,28,31-trimethyl-2,29-dioxo-3-(sec-butyl)-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-carboxyethyl]-c-hydroxycarbonimidoyl}-4-{[(2s)-1-hydroxy-2-[(1-hydroxy-8-methyldecylidene)amino]-3-(1h-indol-3-yl)propylidene]amino}butanoic acid

(4r)-4-{[(1s)-1-{[(3s,9r,15s,18r,21s,24s,30s,31r)-18-(4-aminobutyl)-15,21-bis(carboxymethyl)-6-(1-carboxypropan-2-yl)-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-24,28,31-trimethyl-2,29-dioxo-3-(sec-butyl)-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-carboxyethyl]-c-hydroxycarbonimidoyl}-4-{[(2s)-1-hydroxy-2-[(1-hydroxy-8-methyldecylidene)amino]-3-(1h-indol-3-yl)propylidene]amino}butanoic acid

C73H110N16O26 (1626.77768)


   

n1-[(6s,9r,10s,13s,16s,18ar)-9-(chloromethyl)-11-hydroxy-13-isopropyl-2,5,6,16-tetramethyl-1,4,7,14,17-pentaoxo-3h,6h,9h,10h,13h,16h,18h,18ah-pyrrolo[2,1-i]1-oxa-4,7,10,13-tetraazacyclohexadecan-10-yl]-n9-[(6r,9r,10s,13r,16r,18as)-11-hydroxy-6,13-diisopropyl-2,5,9,16-tetramethyl-1,4,7,14-tetraoxo-3h,6h,9h,10h,13h,16h,17h,18h,18ah-pyrrolo[2,1-i]1-oxa-4,7,10,13-tetraazacyclohexadecan-10-yl]-2-amino-4,6-dimethyl-3-oxophenoxazine-1,9-dicarboximidic acid

n1-[(6s,9r,10s,13s,16s,18ar)-9-(chloromethyl)-11-hydroxy-13-isopropyl-2,5,6,16-tetramethyl-1,4,7,14,17-pentaoxo-3h,6h,9h,10h,13h,16h,18h,18ah-pyrrolo[2,1-i]1-oxa-4,7,10,13-tetraazacyclohexadecan-10-yl]-n9-[(6r,9r,10s,13r,16r,18as)-11-hydroxy-6,13-diisopropyl-2,5,9,16-tetramethyl-1,4,7,14-tetraoxo-3h,6h,9h,10h,13h,16h,17h,18h,18ah-pyrrolo[2,1-i]1-oxa-4,7,10,13-tetraazacyclohexadecan-10-yl]-2-amino-4,6-dimethyl-3-oxophenoxazine-1,9-dicarboximidic acid

C62H83ClN12O17 (1302.5687378)


   

3-hydroxy-3-{[4-(n-hydroxyacetamido)butyl]-c-hydroxycarbonimidoyl}-4-{[3-(n-hydroxyacetamido)propyl]-c-hydroxycarbonimidoyl}butanoic acid

3-hydroxy-3-{[4-(n-hydroxyacetamido)butyl]-c-hydroxycarbonimidoyl}-4-{[3-(n-hydroxyacetamido)propyl]-c-hydroxycarbonimidoyl}butanoic acid

C17H30N4O9 (434.201269)


   

(3s)-3-amino-n-[(4s)-4-amino-5-{[(2r,3r,4s,5r,6r)-2-{[(7r)-4,7-dihydroxy-3h,3ah,6h,7h,7ah-imidazo[4,5-c]pyridin-2-yl]amino}-4-hydroxy-5-(c-hydroxycarbonimidoyloxy)-6-(hydroxymethyl)oxan-3-yl]-c-hydroxycarbonimidoyl}pentyl]-6-{[(3s)-3-amino-6-{[(3s)-3-amino-6-{[(3s)-3,6-diamino-1-hydroxyhexylidene]amino}-1-hydroxyhexylidene]amino}-1-hydroxyhexylidene]amino}hexanimidic acid

(3s)-3-amino-n-[(4s)-4-amino-5-{[(2r,3r,4s,5r,6r)-2-{[(7r)-4,7-dihydroxy-3h,3ah,6h,7h,7ah-imidazo[4,5-c]pyridin-2-yl]amino}-4-hydroxy-5-(c-hydroxycarbonimidoyloxy)-6-(hydroxymethyl)oxan-3-yl]-c-hydroxycarbonimidoyl}pentyl]-6-{[(3s)-3-amino-6-{[(3s)-3-amino-6-{[(3s)-3,6-diamino-1-hydroxyhexylidene]amino}-1-hydroxyhexylidene]amino}-1-hydroxyhexylidene]amino}hexanimidic acid

C43H82N16O12 (1014.6297812)


   

(4r)-4-{[(1s,2r)-1-{[(3s,6s,9r,15s,18r,21s,24s,30s,31r)-18-(4-aminobutyl)-3-[(2s)-butan-2-yl]-15-[(r)-carboxy(methoxy)methyl]-21-(carboxymethyl)-6-[(2r)-1-carboxypropan-2-yl]-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-24,28,31-trimethyl-2,29-dioxo-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-hydroxy-2-(c-hydroxycarbonimidoyl)ethyl]-c-hydroxycarbonimidoyl}-4-{[(2s)-1-hydroxy-2-[(1-hydroxy-8-methylnonylidene)amino]-3-(1h-indol-3-yl)propylidene]amino}butanoic acid

(4r)-4-{[(1s,2r)-1-{[(3s,6s,9r,15s,18r,21s,24s,30s,31r)-18-(4-aminobutyl)-3-[(2s)-butan-2-yl]-15-[(r)-carboxy(methoxy)methyl]-21-(carboxymethyl)-6-[(2r)-1-carboxypropan-2-yl]-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-24,28,31-trimethyl-2,29-dioxo-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-hydroxy-2-(c-hydroxycarbonimidoyl)ethyl]-c-hydroxycarbonimidoyl}-4-{[(2s)-1-hydroxy-2-[(1-hydroxy-8-methylnonylidene)amino]-3-(1h-indol-3-yl)propylidene]amino}butanoic acid

C73H111N17O27 (1657.7834936)


   

(4r)-4-{[(1s)-1-{[(3s,9r,15s,18r,21s,24s,30s,31r)-18-(4-aminobutyl)-15-[carboxy(methoxy)methyl]-6-(2-carboxyethyl)-21-(carboxymethyl)-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-24,28,31-trimethyl-2,29-dioxo-3-(sec-butyl)-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-(c-hydroxycarbonimidoyl)ethyl]-c-hydroxycarbonimidoyl}-4-{[(2s)-1-hydroxy-2-[(1-hydroxy-8-methyldecylidene)amino]-3-(1h-indol-3-yl)propylidene]amino}butanoic acid

(4r)-4-{[(1s)-1-{[(3s,9r,15s,18r,21s,24s,30s,31r)-18-(4-aminobutyl)-15-[carboxy(methoxy)methyl]-6-(2-carboxyethyl)-21-(carboxymethyl)-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-24,28,31-trimethyl-2,29-dioxo-3-(sec-butyl)-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-(c-hydroxycarbonimidoyl)ethyl]-c-hydroxycarbonimidoyl}-4-{[(2s)-1-hydroxy-2-[(1-hydroxy-8-methyldecylidene)amino]-3-(1h-indol-3-yl)propylidene]amino}butanoic acid

C73H111N17O26 (1641.7885786)


   

(3s,4ar,12br)-9-[(2s,4r,5r,6s)-4-{[(2s,5r,6s)-5-{[(2r,4s,5s,6s)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}-6-methyloxan-2-yl]oxy}-5-hydroxy-6-methyloxan-2-yl]-3,4a,8-trihydroxy-12b-{[(2r,5r,6s)-5-hydroxy-6-methyloxan-2-yl]oxy}-3-methyl-5-(methylsulfanyl)-2,4-dihydrotetraphene-1,7,12-trione

(3s,4ar,12br)-9-[(2s,4r,5r,6s)-4-{[(2s,5r,6s)-5-{[(2r,4s,5s,6s)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}-6-methyloxan-2-yl]oxy}-5-hydroxy-6-methyloxan-2-yl]-3,4a,8-trihydroxy-12b-{[(2r,5r,6s)-5-hydroxy-6-methyloxan-2-yl]oxy}-3-methyl-5-(methylsulfanyl)-2,4-dihydrotetraphene-1,7,12-trione

C44H58O17S (890.3394538)


   

n9-[(6r,9r,10s,13s,16r,18s,18ar)-11,18-dihydroxy-6,13-diisopropyl-2,5,9,16-tetramethyl-1,4,7,14-tetraoxo-3h,6h,9h,10h,13h,16h,17h,18h,18ah-pyrrolo[2,1-i]1-oxa-4,7,10,13-tetraazacyclohexadecan-10-yl]-n1-[(6s,9r,10s,13s,16s,18ar)-9-(chloromethyl)-11-hydroxy-13-isopropyl-2,5,6,16-tetramethyl-1,4,7,14,17-pentaoxo-3h,6h,9h,10h,13h,16h,18h,18ah-pyrrolo[2,1-i]1-oxa-4,7,10,13-tetraazacyclohexadecan-10-yl]-2-amino-4,6-dimethyl-3-oxophenoxazine-1,9-dicarboximidic acid

n9-[(6r,9r,10s,13s,16r,18s,18ar)-11,18-dihydroxy-6,13-diisopropyl-2,5,9,16-tetramethyl-1,4,7,14-tetraoxo-3h,6h,9h,10h,13h,16h,17h,18h,18ah-pyrrolo[2,1-i]1-oxa-4,7,10,13-tetraazacyclohexadecan-10-yl]-n1-[(6s,9r,10s,13s,16s,18ar)-9-(chloromethyl)-11-hydroxy-13-isopropyl-2,5,6,16-tetramethyl-1,4,7,14,17-pentaoxo-3h,6h,9h,10h,13h,16h,18h,18ah-pyrrolo[2,1-i]1-oxa-4,7,10,13-tetraazacyclohexadecan-10-yl]-2-amino-4,6-dimethyl-3-oxophenoxazine-1,9-dicarboximidic acid

C62H83ClN12O18 (1318.5636528)


   

(3r)-9-[(4r,5r,6r)-4-{[(2s,5s,6s)-5-{[(2s,4r,5s,6r)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}-6-methyloxan-2-yl]oxy}-5-hydroxy-6-methyloxan-2-yl]-3,8-dihydroxy-3-methyl-2,4-dihydrotetraphene-1,7,12-trione

(3r)-9-[(4r,5r,6r)-4-{[(2s,5s,6s)-5-{[(2s,4r,5s,6r)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}-6-methyloxan-2-yl]oxy}-5-hydroxy-6-methyloxan-2-yl]-3,8-dihydroxy-3-methyl-2,4-dihydrotetraphene-1,7,12-trione

C37H44O13 (696.2781774)


   

4-[(1-{[18-(4-aminobutyl)-15-[carboxy(hydroxy)methyl]-6-(2-carboxyethyl)-21-(carboxymethyl)-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-24,28,31-trimethyl-2,29-dioxo-3-(sec-butyl)-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-(c-hydroxycarbonimidoyl)ethyl)-c-hydroxycarbonimidoyl]-4-({1-hydroxy-2-[(1-hydroxy-8-methyldecylidene)amino]-3-(1h-indol-3-yl)propylidene}amino)butanoic acid

4-[(1-{[18-(4-aminobutyl)-15-[carboxy(hydroxy)methyl]-6-(2-carboxyethyl)-21-(carboxymethyl)-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-24,28,31-trimethyl-2,29-dioxo-3-(sec-butyl)-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-(c-hydroxycarbonimidoyl)ethyl)-c-hydroxycarbonimidoyl]-4-({1-hydroxy-2-[(1-hydroxy-8-methyldecylidene)amino]-3-(1h-indol-3-yl)propylidene}amino)butanoic acid

C72H109N17O26 (1627.7729294)


   

4-[(1-{[18-(4-aminobutyl)-15-[carboxy(hydroxy)methyl]-21-(carboxymethyl)-6-(1-carboxypropan-2-yl)-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-24,28,31-trimethyl-2,29-dioxo-3-(sec-butyl)-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-(c-hydroxycarbonimidoyl)ethyl)-c-hydroxycarbonimidoyl]-4-({1-hydroxy-2-[(1-hydroxy-8-methyldecylidene)amino]-3-(1h-indol-3-yl)propylidene}amino)butanoic acid

4-[(1-{[18-(4-aminobutyl)-15-[carboxy(hydroxy)methyl]-21-(carboxymethyl)-6-(1-carboxypropan-2-yl)-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-24,28,31-trimethyl-2,29-dioxo-3-(sec-butyl)-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-(c-hydroxycarbonimidoyl)ethyl)-c-hydroxycarbonimidoyl]-4-({1-hydroxy-2-[(1-hydroxy-8-methyldecylidene)amino]-3-(1h-indol-3-yl)propylidene}amino)butanoic acid

C73H111N17O26 (1641.7885786)


   

(4e,5'r,6r,6'r,7s,8r,10s,11s,12r,14s,15r,16s,18e,20e,22s,27s,28r,29s)-22-ethyl-7,11,14,15-tetrahydroxy-6'-[(2s)-2-hydroxypropyl]-5',6,8,10,12,14,16,28,29-nonamethyl-2,26-dioxaspiro[bicyclo[23.3.1]nonacosane-27,2'-oxane]-4,18,20-triene-3,9,13-trione

(4e,5'r,6r,6'r,7s,8r,10s,11s,12r,14s,15r,16s,18e,20e,22s,27s,28r,29s)-22-ethyl-7,11,14,15-tetrahydroxy-6'-[(2s)-2-hydroxypropyl]-5',6,8,10,12,14,16,28,29-nonamethyl-2,26-dioxaspiro[bicyclo[23.3.1]nonacosane-27,2'-oxane]-4,18,20-triene-3,9,13-trione

C45H74O11 (790.5230854)


   

(3r,4ar,12bs)-9-[(4r,5r,6r)-4-{[(2s,5s,6s)-5-{[(2s,4r,5s,6r)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}-6-methyloxan-2-yl]oxy}-5-hydroxy-6-methyloxan-2-yl]-3,4a,8-trihydroxy-12b-{[(2s,5s,6s)-5-hydroxy-6-methyloxan-2-yl]oxy}-3-methyl-2,4-dihydrotetraphene-1,7,12-trione

(3r,4ar,12bs)-9-[(4r,5r,6r)-4-{[(2s,5s,6s)-5-{[(2s,4r,5s,6r)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}-6-methyloxan-2-yl]oxy}-5-hydroxy-6-methyloxan-2-yl]-3,4a,8-trihydroxy-12b-{[(2s,5s,6s)-5-hydroxy-6-methyloxan-2-yl]oxy}-3-methyl-2,4-dihydrotetraphene-1,7,12-trione

C43H56O17 (844.3517326000001)


   

(4r)-4-{[(1s)-1-{[(3s,9r,15s,18r,21s,24s,30s,31r)-18-(4-aminobutyl)-6-(2-carboxyethyl)-15,21-bis(carboxymethyl)-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-24,28,31-trimethyl-2,29-dioxo-3-(sec-butyl)-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-hydroxy-2-(c-hydroxycarbonimidoyl)ethyl]-c-hydroxycarbonimidoyl}-4-{[(2s)-1-hydroxy-2-[(1-hydroxy-8-methyldecylidene)amino]-3-(1h-indol-3-yl)propylidene]amino}butanoic acid

(4r)-4-{[(1s)-1-{[(3s,9r,15s,18r,21s,24s,30s,31r)-18-(4-aminobutyl)-6-(2-carboxyethyl)-15,21-bis(carboxymethyl)-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-24,28,31-trimethyl-2,29-dioxo-3-(sec-butyl)-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-hydroxy-2-(c-hydroxycarbonimidoyl)ethyl]-c-hydroxycarbonimidoyl}-4-{[(2s)-1-hydroxy-2-[(1-hydroxy-8-methyldecylidene)amino]-3-(1h-indol-3-yl)propylidene]amino}butanoic acid

C72H109N17O26 (1627.7729294)


   

4-hydroxy-17-propyl-12,16-dioxatetracyclo[8.7.0.0³,⁸.0¹¹,¹⁵]heptadeca-1(10),3,5,7-tetraene-2,9,13-trione

4-hydroxy-17-propyl-12,16-dioxatetracyclo[8.7.0.0³,⁸.0¹¹,¹⁵]heptadeca-1(10),3,5,7-tetraene-2,9,13-trione

C18H16O6 (328.0946836)


   

4-[(1-{[18-(4-aminobutyl)-15,21-bis(carboxymethyl)-6-(1-carboxypropan-2-yl)-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-24,28,31-trimethyl-2,29-dioxo-3-(sec-butyl)-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-(c-hydroxycarbonimidoyl)ethyl)-c-hydroxycarbonimidoyl]-4-({1-hydroxy-2-[(1-hydroxy-8-methyldecylidene)amino]-3-(1h-indol-3-yl)propylidene}amino)butanoic acid

4-[(1-{[18-(4-aminobutyl)-15,21-bis(carboxymethyl)-6-(1-carboxypropan-2-yl)-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-24,28,31-trimethyl-2,29-dioxo-3-(sec-butyl)-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-(c-hydroxycarbonimidoyl)ethyl)-c-hydroxycarbonimidoyl]-4-({1-hydroxy-2-[(1-hydroxy-8-methyldecylidene)amino]-3-(1h-indol-3-yl)propylidene}amino)butanoic acid

C73H111N17O25 (1625.7936636)


   

(3r,4ar,12bs)-9-[(2s,4r,5s,6s)-4-{[(2s,5s,6s)-5-{[(2r,4s,5r,6s)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}-6-methyloxan-2-yl]oxy}-5-hydroxy-6-methyloxan-2-yl]-3,4a,8-trihydroxy-12b-{[(2s,5s,6r)-5-hydroxy-6-methyloxan-2-yl]oxy}-3-methyl-2,4-dihydrotetraphene-1,7,12-trione

(3r,4ar,12bs)-9-[(2s,4r,5s,6s)-4-{[(2s,5s,6s)-5-{[(2r,4s,5r,6s)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}-6-methyloxan-2-yl]oxy}-5-hydroxy-6-methyloxan-2-yl]-3,4a,8-trihydroxy-12b-{[(2s,5s,6r)-5-hydroxy-6-methyloxan-2-yl]oxy}-3-methyl-2,4-dihydrotetraphene-1,7,12-trione

C43H56O17 (844.3517326000001)


   

(3s,6r,8r)-15-[(2r,4r,5r,6r)-4-{[(2s,5s,6s)-5-{[(2s,4r,5s,6r)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}-6-methyloxan-2-yl]oxy}-5-hydroxy-6-methyloxan-2-yl]-6,8,14-trihydroxy-3-{[(2s,5s,6r)-5-hydroxy-6-methyloxan-2-yl]oxy}-18-(4-hydroxyphenyl)-6-methyl-20-oxapentacyclo[11.7.1.0²,¹¹.0³,⁸.0¹⁷,²¹]henicosa-1(21),2(11),9,13,15,17-hexaene-4,12,19-trione

(3s,6r,8r)-15-[(2r,4r,5r,6r)-4-{[(2s,5s,6s)-5-{[(2s,4r,5s,6r)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}-6-methyloxan-2-yl]oxy}-5-hydroxy-6-methyloxan-2-yl]-6,8,14-trihydroxy-3-{[(2s,5s,6r)-5-hydroxy-6-methyloxan-2-yl]oxy}-18-(4-hydroxyphenyl)-6-methyl-20-oxapentacyclo[11.7.1.0²,¹¹.0³,⁸.0¹⁷,²¹]henicosa-1(21),2(11),9,13,15,17-hexaene-4,12,19-trione

C51H60O19 (976.3728610000001)


   

2-[(4r,5s,6s,7r,9r,11e,13e,15r,16r)-6-{[(2r,3r,4s,5s,6r)-4-(dimethylamino)-3,5-dihydroxy-6-methyloxan-2-yl]oxy}-16-ethyl-4-hydroxy-15-({[(2r,3r,4r,5r,6r)-5-hydroxy-3,4-dimethoxy-6-methyloxan-2-yl]oxy}methyl)-5,9,13-trimethyl-2,10-dioxo-1-oxacyclohexadeca-11,13-dien-7-yl]acetaldehyde

2-[(4r,5s,6s,7r,9r,11e,13e,15r,16r)-6-{[(2r,3r,4s,5s,6r)-4-(dimethylamino)-3,5-dihydroxy-6-methyloxan-2-yl]oxy}-16-ethyl-4-hydroxy-15-({[(2r,3r,4r,5r,6r)-5-hydroxy-3,4-dimethoxy-6-methyloxan-2-yl]oxy}methyl)-5,9,13-trimethyl-2,10-dioxo-1-oxacyclohexadeca-11,13-dien-7-yl]acetaldehyde

C39H65NO14 (771.440483)


   

(4r)-4-{[(1s)-1-{[(3s,9r,15s,18r,21s,24s,30s,31r)-18-(4-aminobutyl)-15,21-bis(carboxymethyl)-6-(1-carboxypropan-2-yl)-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-24,28,31-trimethyl-2,29-dioxo-3-(sec-butyl)-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-hydroxy-2-(c-hydroxycarbonimidoyl)ethyl]-c-hydroxycarbonimidoyl}-4-{[(2s)-1-hydroxy-2-[(1-hydroxy-8-methyldecylidene)amino]-3-(1h-indol-3-yl)propylidene]amino}butanoic acid

(4r)-4-{[(1s)-1-{[(3s,9r,15s,18r,21s,24s,30s,31r)-18-(4-aminobutyl)-15,21-bis(carboxymethyl)-6-(1-carboxypropan-2-yl)-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-24,28,31-trimethyl-2,29-dioxo-3-(sec-butyl)-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-hydroxy-2-(c-hydroxycarbonimidoyl)ethyl]-c-hydroxycarbonimidoyl}-4-{[(2s)-1-hydroxy-2-[(1-hydroxy-8-methyldecylidene)amino]-3-(1h-indol-3-yl)propylidene]amino}butanoic acid

C73H111N17O26 (1641.7885786)


   

(4r,5r,6s,7r,9s,11e,13e,15s,16r)-7,16-diethyl-4,6-dihydroxy-5,9,13,15-tetramethyl-1-oxacyclohexadeca-11,13-diene-2,10-dione

(4r,5r,6s,7r,9s,11e,13e,15s,16r)-7,16-diethyl-4,6-dihydroxy-5,9,13,15-tetramethyl-1-oxacyclohexadeca-11,13-diene-2,10-dione

C23H38O5 (394.2719098)


   

(3r,4as,6ar,12as,12br)-3,4a,8,12a,12b-pentahydroxy-3-methyl-4,5,6,6a-tetrahydro-2h-tetraphene-1,7,12-trione

(3r,4as,6ar,12as,12br)-3,4a,8,12a,12b-pentahydroxy-3-methyl-4,5,6,6a-tetrahydro-2h-tetraphene-1,7,12-trione

C19H20O8 (376.115812)


   

15-[4-({5-[(4,5-dihydroxy-6-methyloxan-2-yl)oxy]-6-methyloxan-2-yl}oxy)-5-hydroxy-6-methyloxan-2-yl]-6,8,14-trihydroxy-3-[(5-hydroxy-6-methyloxan-2-yl)oxy]-18-(4-hydroxyphenyl)-6-methyl-19-oxapentacyclo[11.6.1.0²,¹¹.0³,⁸.0¹⁷,²⁰]icosa-1(20),2(11),9,13,15,17-hexaene-4,12-dione

15-[4-({5-[(4,5-dihydroxy-6-methyloxan-2-yl)oxy]-6-methyloxan-2-yl}oxy)-5-hydroxy-6-methyloxan-2-yl]-6,8,14-trihydroxy-3-[(5-hydroxy-6-methyloxan-2-yl)oxy]-18-(4-hydroxyphenyl)-6-methyl-19-oxapentacyclo[11.6.1.0²,¹¹.0³,⁸.0¹⁷,²⁰]icosa-1(20),2(11),9,13,15,17-hexaene-4,12-dione

C50H60O18 (948.3779460000001)


   

n9-[(6s,9s,10s,13r,16r,18as)-11-hydroxy-6,13-diisopropyl-2,5,9,16-tetramethyl-1,4,7,14-tetraoxo-3h,6h,9h,10h,13h,16h,17h,18h,18ah-pyrrolo[2,1-i]1-oxa-4,7,10,13-tetraazacyclohexadecan-10-yl]-n1-[(6s,9r,10s,13r,16r,18as)-9-(chloromethyl)-11-hydroxy-13-isopropyl-2,5,6,16-tetramethyl-1,4,7,14,17-pentaoxo-3h,6h,9h,10h,13h,16h,18h,18ah-pyrrolo[2,1-i]1-oxa-4,7,10,13-tetraazacyclohexadecan-10-yl]-2-amino-4,6-dimethyl-3-oxophenoxazine-1,9-dicarboximidic acid

n9-[(6s,9s,10s,13r,16r,18as)-11-hydroxy-6,13-diisopropyl-2,5,9,16-tetramethyl-1,4,7,14-tetraoxo-3h,6h,9h,10h,13h,16h,17h,18h,18ah-pyrrolo[2,1-i]1-oxa-4,7,10,13-tetraazacyclohexadecan-10-yl]-n1-[(6s,9r,10s,13r,16r,18as)-9-(chloromethyl)-11-hydroxy-13-isopropyl-2,5,6,16-tetramethyl-1,4,7,14,17-pentaoxo-3h,6h,9h,10h,13h,16h,18h,18ah-pyrrolo[2,1-i]1-oxa-4,7,10,13-tetraazacyclohexadecan-10-yl]-2-amino-4,6-dimethyl-3-oxophenoxazine-1,9-dicarboximidic acid

C62H83ClN12O17 (1302.5687378)


   

(3r,4as,12bs)-9-[(4r,5r,6r)-4-{[(2s,5s,6s)-5-{[(2s,4r,5s,6r)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}-6-methyloxan-2-yl]oxy}-5-hydroxy-6-methyloxan-2-yl]-3,4a,8-trihydroxy-12b-{[(2s,5s,6s)-5-hydroxy-6-methyloxan-2-yl]oxy}-3-methyl-5-(methylsulfanyl)-2,4-dihydrotetraphene-1,7,12-trione

(3r,4as,12bs)-9-[(4r,5r,6r)-4-{[(2s,5s,6s)-5-{[(2s,4r,5s,6r)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}-6-methyloxan-2-yl]oxy}-5-hydroxy-6-methyloxan-2-yl]-3,4a,8-trihydroxy-12b-{[(2s,5s,6s)-5-hydroxy-6-methyloxan-2-yl]oxy}-3-methyl-5-(methylsulfanyl)-2,4-dihydrotetraphene-1,7,12-trione

C44H58O17S (890.3394538)


   

(2s,3r,4r,6r)-4-[cyano(methyl)amino]-3-methoxy-2-methyl-29-oxa-1,7,17-triazaoctacyclo[12.12.2.1²,⁶.0⁷,²⁸.0⁸,¹³.0¹⁵,¹⁹.0²⁰,²⁷.0²¹,²⁶]nonacosa-8(13),9,11,14(28),15(19),16,20(27),21(26),22,24-decaen-16-ol

(2s,3r,4r,6r)-4-[cyano(methyl)amino]-3-methoxy-2-methyl-29-oxa-1,7,17-triazaoctacyclo[12.12.2.1²,⁶.0⁷,²⁸.0⁸,¹³.0¹⁵,¹⁹.0²⁰,²⁷.0²¹,²⁶]nonacosa-8(13),9,11,14(28),15(19),16,20(27),21(26),22,24-decaen-16-ol

C29H25N5O3 (491.19573)


   

2-amino-n9-{11,18-dihydroxy-6,13-diisopropyl-2,5,9,16-tetramethyl-1,4,7,14-tetraoxo-3h,6h,9h,10h,13h,16h,17h,18h,18ah-pyrrolo[2,1-i]1-oxa-4,7,10,13-tetraazacyclohexadecan-10-yl}-n1-{11-hydroxy-13-isopropyl-2,5,6,9,16-pentamethyl-1,4,7,14,17-pentaoxo-3h,6h,9h,10h,13h,16h,18h,18ah-pyrrolo[2,1-i]1-oxa-4,7,10,13-tetraazacyclohexadecan-10-yl}-4,6-dimethyl-3-oxophenoxazine-1,9-dicarboximidic acid

2-amino-n9-{11,18-dihydroxy-6,13-diisopropyl-2,5,9,16-tetramethyl-1,4,7,14-tetraoxo-3h,6h,9h,10h,13h,16h,17h,18h,18ah-pyrrolo[2,1-i]1-oxa-4,7,10,13-tetraazacyclohexadecan-10-yl}-n1-{11-hydroxy-13-isopropyl-2,5,6,9,16-pentamethyl-1,4,7,14,17-pentaoxo-3h,6h,9h,10h,13h,16h,18h,18ah-pyrrolo[2,1-i]1-oxa-4,7,10,13-tetraazacyclohexadecan-10-yl}-4,6-dimethyl-3-oxophenoxazine-1,9-dicarboximidic acid

C62H84N12O18 (1284.6026244)


   

(4r)-4-{[(1s)-1-{[(3s,9r,15s,18r,21s,24s,30s,31r)-18-(4-aminobutyl)-15-[carboxy(methoxy)methyl]-21-(carboxymethyl)-6-(1-carboxypropan-2-yl)-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-3-isopropyl-24,28,31-trimethyl-2,29-dioxo-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-hydroxy-2-(c-hydroxycarbonimidoyl)ethyl]-c-hydroxycarbonimidoyl}-4-{[(2s)-1-hydroxy-3-(1h-indol-3-yl)-2-[(8-methyldecyl)amino]propylidene]amino}butanoic acid

(4r)-4-{[(1s)-1-{[(3s,9r,15s,18r,21s,24s,30s,31r)-18-(4-aminobutyl)-15-[carboxy(methoxy)methyl]-21-(carboxymethyl)-6-(1-carboxypropan-2-yl)-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-3-isopropyl-24,28,31-trimethyl-2,29-dioxo-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-hydroxy-2-(c-hydroxycarbonimidoyl)ethyl]-c-hydroxycarbonimidoyl}-4-{[(2s)-1-hydroxy-3-(1h-indol-3-yl)-2-[(8-methyldecyl)amino]propylidene]amino}butanoic acid

C73H113N17O26 (1643.8042278)


   

(3s,6r,8r)-15-[(2r,4r,5r,6r)-4-{[(2s,5s,6s)-5-{[(2s,4r,5s,6r)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}-6-methyloxan-2-yl]oxy}-5-hydroxy-6-methyloxan-2-yl]-6,8,12-trihydroxy-3-{[(2s,5s,6s)-5-hydroxy-6-methyloxan-2-yl]oxy}-18-(1h-indol-3-yl)-6-methyl-20-oxapentacyclo[11.7.1.0²,¹¹.0³,⁸.0¹⁷,²¹]henicosa-1,9,11,13(21),15,17-hexaene-4,14,19-trione

(3s,6r,8r)-15-[(2r,4r,5r,6r)-4-{[(2s,5s,6s)-5-{[(2s,4r,5s,6r)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}-6-methyloxan-2-yl]oxy}-5-hydroxy-6-methyloxan-2-yl]-6,8,12-trihydroxy-3-{[(2s,5s,6s)-5-hydroxy-6-methyloxan-2-yl]oxy}-18-(1h-indol-3-yl)-6-methyl-20-oxapentacyclo[11.7.1.0²,¹¹.0³,⁸.0¹⁷,²¹]henicosa-1,9,11,13(21),15,17-hexaene-4,14,19-trione

C53H61NO18 (999.3888446000001)


   

(4as,6ar,12as,12br)-4a,8,12a,12b-tetrahydroxy-3-methyl-4,5,6,6a-tetrahydrotetraphene-1,7,12-trione

(4as,6ar,12as,12br)-4a,8,12a,12b-tetrahydroxy-3-methyl-4,5,6,6a-tetrahydrotetraphene-1,7,12-trione

C19H18O7 (358.10524780000003)


   

(2s,3r,4r,6r)-3-methoxy-2-methyl-4-(methylamino)-29-oxa-1,7,17-triazaoctacyclo[12.12.2.1²,⁶.0⁷,²⁸.0⁸,¹³.0¹⁵,¹⁹.0²⁰,²⁷.0²¹,²⁶]nonacosa-8(13),9,11,14(28),15(19),16,20(27),21(26),22,24-decaen-16-ol

(2s,3r,4r,6r)-3-methoxy-2-methyl-4-(methylamino)-29-oxa-1,7,17-triazaoctacyclo[12.12.2.1²,⁶.0⁷,²⁸.0⁸,¹³.0¹⁵,¹⁹.0²⁰,²⁷.0²¹,²⁶]nonacosa-8(13),9,11,14(28),15(19),16,20(27),21(26),22,24-decaen-16-ol

C28H26N4O3 (466.2004806)


   

2-amino-n1-[9-(chloromethyl)-11-hydroxy-13-isopropyl-2,5,6,16-tetramethyl-1,4,7,14,17-pentaoxo-3h,6h,9h,10h,13h,16h,18h,18ah-pyrrolo[2,1-i]1-oxa-4,7,10,13-tetraazacyclohexadecan-10-yl]-n9-{11-hydroxy-6,13-diisopropyl-2,5,9,16-tetramethyl-1,4,7,14-tetraoxo-3h,6h,9h,10h,13h,16h,17h,18h,18ah-pyrrolo[2,1-i]1-oxa-4,7,10,13-tetraazacyclohexadecan-10-yl}-4,6-dimethyl-3-oxophenoxazine-1,9-dicarboximidic acid

2-amino-n1-[9-(chloromethyl)-11-hydroxy-13-isopropyl-2,5,6,16-tetramethyl-1,4,7,14,17-pentaoxo-3h,6h,9h,10h,13h,16h,18h,18ah-pyrrolo[2,1-i]1-oxa-4,7,10,13-tetraazacyclohexadecan-10-yl]-n9-{11-hydroxy-6,13-diisopropyl-2,5,9,16-tetramethyl-1,4,7,14-tetraoxo-3h,6h,9h,10h,13h,16h,17h,18h,18ah-pyrrolo[2,1-i]1-oxa-4,7,10,13-tetraazacyclohexadecan-10-yl}-4,6-dimethyl-3-oxophenoxazine-1,9-dicarboximidic acid

C62H83ClN12O17 (1302.5687378)


   

(6r)-9-[(4s,5r,6s)-4-{[(2s,5r,6r)-5-{[(2r,4r,5r,6s)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}-6-methyloxan-2-yl]oxy}-5-hydroxy-6-methyloxan-2-yl]-3,4a,6,8-tetrahydroxy-12b-{[(5r,6s)-5-hydroxy-6-methyloxan-2-yl]oxy}-3-methyl-2,4,5,6-tetrahydrotetraphene-1,7,12-trione

(6r)-9-[(4s,5r,6s)-4-{[(2s,5r,6r)-5-{[(2r,4r,5r,6s)-4,5-dihydroxy-6-methyloxan-2-yl]oxy}-6-methyloxan-2-yl]oxy}-5-hydroxy-6-methyloxan-2-yl]-3,4a,6,8-tetrahydroxy-12b-{[(5r,6s)-5-hydroxy-6-methyloxan-2-yl]oxy}-3-methyl-2,4,5,6-tetrahydrotetraphene-1,7,12-trione

C43H58O18 (862.3622968)


   

2-[(4r,5r,6s,7r,9r,11z,13e,15s,16r)-6-{[(2s,3r,4s,5s,6s)-5-{[(2s,4s,5r,6s)-4,5-dihydroxy-4,6-dimethyloxan-2-yl]oxy}-4-(dimethylamino)-3-hydroxy-6-methyloxan-2-yl]oxy}-16-ethyl-4-hydroxy-15-(hydroxymethyl)-5,9,13-trimethyl-2,10-dioxo-1-oxacyclohexadeca-11,13-dien-7-yl]acetaldehyde

2-[(4r,5r,6s,7r,9r,11z,13e,15s,16r)-6-{[(2s,3r,4s,5s,6s)-5-{[(2s,4s,5r,6s)-4,5-dihydroxy-4,6-dimethyloxan-2-yl]oxy}-4-(dimethylamino)-3-hydroxy-6-methyloxan-2-yl]oxy}-16-ethyl-4-hydroxy-15-(hydroxymethyl)-5,9,13-trimethyl-2,10-dioxo-1-oxacyclohexadeca-11,13-dien-7-yl]acetaldehyde

C38H63NO13 (741.4299188)


   

(3r,4as,6ar,12as,12br)-3,4a,8,12a-tetrahydroxy-12b-{[(2s,5s,6s)-5-hydroxy-6-methyloxan-2-yl]oxy}-3-methyl-4,5,6,6a-tetrahydro-2h-tetraphene-1,7,12-trione

(3r,4as,6ar,12as,12br)-3,4a,8,12a-tetrahydroxy-12b-{[(2s,5s,6s)-5-hydroxy-6-methyloxan-2-yl]oxy}-3-methyl-4,5,6,6a-tetrahydro-2h-tetraphene-1,7,12-trione

C25H30O10 (490.183888)


   

(3e,5e,7e,9e,11e)-19,21,23,25,27,29,31,33,35-nonahydroxy-15-isopropyl-12,16-dimethyl-14,37-dioxabicyclo[31.3.1]heptatriaconta-3,5,7,9,11-pentaen-13-one

(3e,5e,7e,9e,11e)-19,21,23,25,27,29,31,33,35-nonahydroxy-15-isopropyl-12,16-dimethyl-14,37-dioxabicyclo[31.3.1]heptatriaconta-3,5,7,9,11-pentaen-13-one

C40H66O12 (738.4554036000001)


   

4-[(1-{[18-(4-aminobutyl)-15,21-bis(carboxymethyl)-6-(1-carboxypropan-2-yl)-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-24,28,31-trimethyl-2,29-dioxo-3-(sec-butyl)-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-carboxyethyl)-c-hydroxycarbonimidoyl]-4-({1-hydroxy-2-[(1-hydroxy-8-methyldecylidene)amino]-3-(1h-indol-3-yl)propylidene}amino)butanoic acid

4-[(1-{[18-(4-aminobutyl)-15,21-bis(carboxymethyl)-6-(1-carboxypropan-2-yl)-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-24,28,31-trimethyl-2,29-dioxo-3-(sec-butyl)-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-carboxyethyl)-c-hydroxycarbonimidoyl]-4-({1-hydroxy-2-[(1-hydroxy-8-methyldecylidene)amino]-3-(1h-indol-3-yl)propylidene}amino)butanoic acid

C73H110N16O26 (1626.77768)


   

4-[(1-{[18-(4-aminobutyl)-15-[carboxy(methoxy)methyl]-6-(2-carboxyethyl)-21-(carboxymethyl)-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-24,28,31-trimethyl-2,29-dioxo-3-(sec-butyl)-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-(c-hydroxycarbonimidoyl)ethyl)-c-hydroxycarbonimidoyl]-4-({1-hydroxy-2-[(1-hydroxy-8-methyldecylidene)amino]-3-(1h-indol-3-yl)propylidene}amino)butanoic acid

4-[(1-{[18-(4-aminobutyl)-15-[carboxy(methoxy)methyl]-6-(2-carboxyethyl)-21-(carboxymethyl)-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-24,28,31-trimethyl-2,29-dioxo-3-(sec-butyl)-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-(c-hydroxycarbonimidoyl)ethyl)-c-hydroxycarbonimidoyl]-4-({1-hydroxy-2-[(1-hydroxy-8-methyldecylidene)amino]-3-(1h-indol-3-yl)propylidene}amino)butanoic acid

C73H111N17O26 (1641.7885786)


   

(4r)-4-{[(1s,2r)-1-{[(3s,6s,9r,15s,18r,21s,24s,30s,31r)-18-(4-aminobutyl)-3-[(2s)-butan-2-yl]-15-[(r)-carboxy(methoxy)methyl]-6-(2-carboxyethyl)-21-(carboxymethyl)-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-24,28,31-trimethyl-2,29-dioxo-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-hydroxy-2-(c-hydroxycarbonimidoyl)ethyl]-c-hydroxycarbonimidoyl}-4-{[(2s)-1-hydroxy-2-[(1-hydroxydecylidene)amino]-3-(1h-indol-3-yl)propylidene]amino}butanoic acid

(4r)-4-{[(1s,2r)-1-{[(3s,6s,9r,15s,18r,21s,24s,30s,31r)-18-(4-aminobutyl)-3-[(2s)-butan-2-yl]-15-[(r)-carboxy(methoxy)methyl]-6-(2-carboxyethyl)-21-(carboxymethyl)-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-24,28,31-trimethyl-2,29-dioxo-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-hydroxy-2-(c-hydroxycarbonimidoyl)ethyl]-c-hydroxycarbonimidoyl}-4-{[(2s)-1-hydroxy-2-[(1-hydroxydecylidene)amino]-3-(1h-indol-3-yl)propylidene]amino}butanoic acid

C72H109N17O27 (1643.7678444)


   

(4r)-4-{[(1s)-1-{[(3s,9r,15s,18r,21s,24s,30s,31r)-18-(4-aminobutyl)-15,21-bis(carboxymethyl)-6-(1-carboxypropan-2-yl)-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-24,28,31-trimethyl-2,29-dioxo-3-(sec-butyl)-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-(c-hydroxycarbonimidoyl)ethyl]-c-hydroxycarbonimidoyl}-4-{[(2s)-1-hydroxy-2-[(1-hydroxy-8-methyldecylidene)amino]-3-(1h-indol-3-yl)propylidene]amino}butanoic acid

(4r)-4-{[(1s)-1-{[(3s,9r,15s,18r,21s,24s,30s,31r)-18-(4-aminobutyl)-15,21-bis(carboxymethyl)-6-(1-carboxypropan-2-yl)-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-24,28,31-trimethyl-2,29-dioxo-3-(sec-butyl)-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-(c-hydroxycarbonimidoyl)ethyl]-c-hydroxycarbonimidoyl}-4-{[(2s)-1-hydroxy-2-[(1-hydroxy-8-methyldecylidene)amino]-3-(1h-indol-3-yl)propylidene]amino}butanoic acid

C73H111N17O25 (1625.7936636)


   

4-[(1-{[18-(4-aminobutyl)-6-(2-carboxyethyl)-15,21-bis(carboxymethyl)-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-24,28,31-trimethyl-2,29-dioxo-3-(sec-butyl)-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-hydroxy-2-(c-hydroxycarbonimidoyl)ethyl)-c-hydroxycarbonimidoyl]-4-({1-hydroxy-2-[(1-hydroxy-8-methyldecylidene)amino]-3-(1h-indol-3-yl)propylidene}amino)butanoic acid

4-[(1-{[18-(4-aminobutyl)-6-(2-carboxyethyl)-15,21-bis(carboxymethyl)-5,8,11,14,17,20,23,26-octahydroxy-9-(c-hydroxycarbonimidoylmethyl)-24,28,31-trimethyl-2,29-dioxo-3-(sec-butyl)-1-oxa-4,7,10,13,16,19,22,25,28-nonaazacyclohentriaconta-4,7,10,13,16,19,22,25-octaen-30-yl]-c-hydroxycarbonimidoyl}-2-hydroxy-2-(c-hydroxycarbonimidoyl)ethyl)-c-hydroxycarbonimidoyl]-4-({1-hydroxy-2-[(1-hydroxy-8-methyldecylidene)amino]-3-(1h-indol-3-yl)propylidene}amino)butanoic acid

C72H109N17O26 (1627.7729294)


   

1,6,11-trihydroxy-8-{[4-hydroxy-5-({5-hydroxy-4-[(5-{[4-hydroxy-5-({5-hydroxy-4-[(5-hydroxy-6-methyloxan-2-yl)oxy]-6-methyloxan-2-yl}oxy)-6-methyloxan-2-yl]oxy}-6-methyloxan-2-yl)oxy]-6-methyloxan-2-yl}oxy)-6-methyloxan-2-yl]oxy}-3-methyl-5,6-dihydrotetraphene-7,12-dione

1,6,11-trihydroxy-8-{[4-hydroxy-5-({5-hydroxy-4-[(5-{[4-hydroxy-5-({5-hydroxy-4-[(5-hydroxy-6-methyloxan-2-yl)oxy]-6-methyloxan-2-yl}oxy)-6-methyloxan-2-yl]oxy}-6-methyloxan-2-yl)oxy]-6-methyloxan-2-yl}oxy)-6-methyloxan-2-yl]oxy}-3-methyl-5,6-dihydrotetraphene-7,12-dione

C55H74O22 (1086.4671504)