Cyprodinil (BioDeep_00000001145)

 

Secondary id: BioDeep_00000419502

human metabolite


代谢物信息卡片


4-Cyclopropyl-6-methyl-N-phenyl-2-pyrimidinamine, 9ci

化学式: C14H15N3 (225.1266)
中文名称: 嘧菌环胺
谱图信息: 最多检出来源 Homo sapiens(plant) 4.78%

分子结构信息

SMILES: c1ccccc1Nc1nc(C2CC2)cc(C)n1
InChI: InChI=1S/C14H15N3/c1-10-9-13(11-7-8-11)17-14(15-10)16-12-5-3-2-4-6-12/h2-6,9,11H,7-8H2,1H3,(H,15,16,17)

描述信息

CONFIDENCE standard compound; INTERNAL_ID 810; DATASET 20200303_ENTACT_RP_MIX508; DATA_PROCESSING MERGING RMBmix ver. 0.2.7; DATA_PROCESSING PRESCREENING Shinyscreen ver. 0.8.0; ORIGINAL_ACQUISITION_NO 9314; ORIGINAL_PRECURSOR_SCAN_NO 9312
CONFIDENCE standard compound; INTERNAL_ID 810; DATASET 20200303_ENTACT_RP_MIX508; DATA_PROCESSING MERGING RMBmix ver. 0.2.7; DATA_PROCESSING PRESCREENING Shinyscreen ver. 0.8.0; ORIGINAL_ACQUISITION_NO 9293; ORIGINAL_PRECURSOR_SCAN_NO 9292
CONFIDENCE standard compound; INTERNAL_ID 810; DATASET 20200303_ENTACT_RP_MIX508; DATA_PROCESSING MERGING RMBmix ver. 0.2.7; DATA_PROCESSING PRESCREENING Shinyscreen ver. 0.8.0; ORIGINAL_ACQUISITION_NO 9313; ORIGINAL_PRECURSOR_SCAN_NO 9312
CONFIDENCE standard compound; INTERNAL_ID 810; DATASET 20200303_ENTACT_RP_MIX505; DATA_PROCESSING MERGING RMBmix ver. 0.2.7; DATA_PROCESSING PRESCREENING Shinyscreen ver. 0.8.0; ORIGINAL_ACQUISITION_NO 9269; ORIGINAL_PRECURSOR_SCAN_NO 9268
CONFIDENCE standard compound; INTERNAL_ID 810; DATASET 20200303_ENTACT_RP_MIX505; DATA_PROCESSING MERGING RMBmix ver. 0.2.7; DATA_PROCESSING PRESCREENING Shinyscreen ver. 0.8.0; ORIGINAL_ACQUISITION_NO 9257; ORIGINAL_PRECURSOR_SCAN_NO 9256
CONFIDENCE standard compound; INTERNAL_ID 810; DATASET 20200303_ENTACT_RP_MIX508; DATA_PROCESSING MERGING RMBmix ver. 0.2.7; DATA_PROCESSING PRESCREENING Shinyscreen ver. 0.8.0; ORIGINAL_ACQUISITION_NO 9258; ORIGINAL_PRECURSOR_SCAN_NO 9257
CONFIDENCE standard compound; EAWAG_UCHEM_ID 148
CONFIDENCE standard compound; INTERNAL_ID 2569
KEIO_ID C172; [MS2] KO008908
Cyprodinil is a fungicide.
Cyprodinil is a fungicide
KEIO_ID C172

同义名列表

10 个代谢物同义名

4-Cyclopropyl-6-methyl-N-phenyl-2-pyrimidinamine, 9ci; 4-Cyclopropyl-6-methyl-N-phenylpyrimidin-2-amine; 4-Cyclopropyl-6-methyl-N-phenyl-2-pyrimidinamine; 2-Anilino-4-cyclopropyl-6-methylpyrimidine; CGA 219417; Cyprodinil; HSDB 7019; Chorus; Unix; Cyprodinil



数据库引用编号

48 个数据库交叉引用编号

分类词条

相关代谢途径

Reactome(0)

BioCyc(0)

PlantCyc(0)

代谢反应

0 个相关的代谢反应过程信息。

Reactome(0)

BioCyc(0)

WikiPathways(0)

Plant Reactome(0)

INOH(0)

PlantCyc(0)

COVID-19 Disease Map(0)

PathBank(0)

PharmGKB(0)

1 个相关的物种来源信息

在这里通过桑基图来展示出与当前的这个代谢物在我们的BioDeep知识库中具有相关联信息的其他代谢物。在这里进行关联的信息来源主要有：

  • PubMed: 来源于PubMed文献库中的文献信息，我们通过自然语言数据挖掘得到的在同一篇文献中被同时提及的相关代谢物列表，这个列表按照代谢物同时出现的文献数量降序排序，取前10个代谢物作为相关研究中关联性很高的代谢物集合展示在桑基图中。
  • NCBI Taxonomy: 通过文献数据挖掘，得到的代谢物物种来源信息关联。这个关联信息同样按照出现的次数降序排序，取前10个代谢物作为高关联度的代谢物集合展示在桑吉图上。
  • Chemical Taxonomy: 在物质分类上处于同一个分类集合中的其他代谢物
  • Chemical Reaction: 在化学反应过程中，存在为当前代谢物相关联的生化反应过程中的反应底物或者反应产物的关联代谢物信息。

点击图上的相关代谢物的名称，可以跳转到相关代谢物的信息页面。

亚细胞结构定位 关联基因列表
Cytoplasm 7 AHR, AR, CCND1, CYP1A1, MC2R, POMC, TBX5
Peripheral membrane protein 2 CYP1A1, SDHB
Endosome membrane 1 CTSD
Endoplasmic reticulum membrane 2 CYP19A1, CYP1A1
Nucleus 5 AHR, AR, CCND1, GATA4, TBX5
cytosol 4 AHR, AR, CCND1, TNNT2
dendrite 1 TRPM5
mitochondrial membrane 1 SDHB
nuclear body 1 GATA4
centrosome 1 CCND1
nucleoplasm 6 AHR, AR, CCND1, GATA4, SDHB, TBX5
RNA polymerase II transcription regulator complex 1 GATA4
Cell membrane 3 GNRHR, MC2R, TRPM5
Multi-pass membrane protein 6 CATSPER3, CYP19A1, GNRHR, MC2R, MT-CYB, TRPM5
Synapse 1 CRH
cell surface 1 CD46
Golgi membrane 1 INS
lysosomal membrane 1 CTSD
mitochondrial inner membrane 3 CYP1A1, MT-CYB, SDHB
neuronal cell body 1 TRPM5
Lysosome 1 CTSD
acrosomal vesicle 1 CATSPER3
plasma membrane 8 AR, CATSPER3, CD46, GNRHR, GNRHR2, MC2R, SDHB, TRPM5
Membrane 7 AR, CD46, CYP19A1, GNRHR, GNRHR2, MT-CYB, TRPM5
extracellular exosome 2 CD46, CTSD
endoplasmic reticulum 2 CATSPER3, CYP19A1
extracellular space 5 CD46, CRH, CTSD, INS, POMC
lysosomal lumen 1 CTSD
bicellular tight junction 1 CCND1
mitochondrion 3 CYP1A1, MT-CYB, SDHB
protein-containing complex 3 AHR, AR, TBX5
intracellular membrane-bounded organelle 1 CYP1A1
Microsome membrane 2 CYP19A1, CYP1A1
Single-pass type I membrane protein 1 CD46
Secreted 3 CRH, INS, POMC
extracellular region 4 CRH, CTSD, INS, POMC
mitochondrial matrix 1 SDHB
transcription regulator complex 2 AHR, TBX5
motile cilium 1 CATSPER3
Nucleus membrane 1 CCND1
nuclear membrane 1 CCND1
varicosity 1 CRH
neuronal dense core vesicle lumen 1 CRH
perikaryon 1 CRH
Mitochondrion inner membrane 3 CYP1A1, MT-CYB, SDHB
Matrix side 1 SDHB
Membrane raft 1 CTSD
focal adhesion 1 CD46
collagen-containing extracellular matrix 1 CTSD
secretory granule 1 POMC
nuclear speck 1 AR
sarcomere 1 TNNT2
chromatin 4 AHR, AR, GATA4, TBX5
endosome lumen 2 CTSD, INS
Cell projection, cilium, flagellum membrane 1 CATSPER3
monoatomic ion channel complex 1 TRPM5
aryl hydrocarbon receptor complex 1 AHR
Melanosome 1 CTSD
ficolin-1-rich granule lumen 1 CTSD
secretory granule lumen 2 INS, POMC
Golgi lumen 1 INS
endoplasmic reticulum lumen 1 INS
transcription repressor complex 1 CCND1
specific granule lumen 1 CTSD
tertiary granule lumen 1 CTSD
transport vesicle 1 INS
Endoplasmic reticulum-Golgi intermediate compartment membrane 1 INS
respiratory chain complex II (succinate dehydrogenase) 1 SDHB
respiratory chain complex III 1 MT-CYB
protein-DNA complex 1 TBX5
cyclin-dependent protein kinase holoenzyme complex 1 CCND1
cardiac myofibril 1 TNNT2
troponin complex 1 TNNT2
cyclin D1-CDK4 complex 1 CCND1
Cytoplasmic vesicle, secretory vesicle, acrosome inner membrane 1 CD46
inner acrosomal membrane 1 CD46
cardiac Troponin complex 1 TNNT2
cyclin D1-CDK6 complex 1 CCND1
nuclear aryl hydrocarbon receptor complex 1 AHR
striated muscle thin filament 1 TNNT2
cytosolic aryl hydrocarbon receptor complex 1 AHR
CatSper complex 1 CATSPER3


文献列表

  • Yeju Kim, Ceyhun Bereketoglu, Onur Sercinoglu, Ajay Pradhan. In Vitro, In Vivo, and In Silico Analysis of Pyraclostrobin and Cyprodinil and Their Mixture Reveal New Targets and Signaling Mechanisms. Chemical research in toxicology. 2024 03; 37(3):497-512. doi: 10.1021/acs.chemrestox.3c00371. [PMID: 38419406]
  • Ping-Hu Wu, Min-Nan Tseng, Ying-Hong Lin, Chang-Hsin Kuo, Hao-Xun Chang. Identification of Cyprodinil+Fludioxonil to Manage Soybean Red Crown Rot using the Microplate-based High Throughput Screening and Pot Assay. Plant disease. 2022 Oct; ?(?):. doi: 10.1094/pdis-08-22-1976-re. [PMID: 36302731]
  • Liana C Arnaud, Thierry Gauthier, Augustin Le Naour, Saleha Hashim, Nathalie Naud, Jerry W Shay, Fabrice H Pierre, Elisa Boutet-Robinet, Laurence Huc. Short-Term and Long-Term Carcinogenic Effects of Food Contaminants (4-Hydroxynonenal and Pesticides) on Colorectal Human Cells: Involvement of Genotoxic and Non-Genomic Mechanisms. Cancers. 2021 Aug; 13(17):. doi: 10.3390/cancers13174337. [PMID: 34503147]
  • Xuzhi Hu, Haoning Gong, Zongyi Li, Sean Ruane, Huayang Liu, Peter Hollowell, Elias Pambou, Carlo Bawn, Stephen King, Sarah Rogers, Kun Ma, Peixun Li, Faheem Padia, Gordon Bell, Jian Ren Lu. How does solubilisation of plant waxes into nonionic surfactant micelles affect pesticide release?. Journal of colloid and interface science. 2019 Nov; 556(?):650-657. doi: 10.1016/j.jcis.2019.08.098. [PMID: 31499436]
  • W X Yin, M Adnan, Y Shang, Y Lin, C X Luo. Sensitivity of Botrytis cinerea From Nectarine/Cherry in China to Six Fungicides and Characterization of Resistant Isolates. Plant disease. 2018 12; 102(12):2578-2585. doi: 10.1094/pdis-02-18-0244-re. [PMID: 30299208]
  • A Amiri, A I Zuniga, N A Peres. Potential Impact of Populations Drift on Botrytis Occurrence and Resistance to Multi- and Single-Site Fungicides in Florida Southern Highbush Blueberry Fields. Plant disease. 2018 11; 102(11):2142-2148. doi: 10.1094/pdis-11-17-1810-re. [PMID: 30169135]
  • Guopeng Miao, Juan Han, Tao Ye, Zhina Chen, Kegui Zhang. Efficiency and Safety Assurance of Six Fungicides Applied on Postharvest Cabbages Stored in a Natural Environment. Journal of agricultural and food chemistry. 2018 Oct; 66(41):10864-10870. doi: 10.1021/acs.jafc.8b03910. [PMID: 30272962]
  • Stacey E Haack, Kelly L Ivors, Gerald J Holmes, Helga Förster, James E Adaskaveg. Natamycin, a New Biofungicide for Managing Crown Rot of Strawberry Caused by QoI-Resistant Colletotrichum acutatum. Plant disease. 2018 Sep; 102(9):1687-1695. doi: 10.1094/pdis-12-17-2033-re. [PMID: 30125151]
  • Christian Imholt, Tariq Abdulla, Alexander Stevens, Peter Edwards, Jens Jacob, David Woods, Elaine Rogers, Leon Aarons, Daniel Segelcke. Establishment and validation of microsampling techniques in wild rodents for ecotoxicological research. Journal of applied toxicology : JAT. 2018 09; 38(9):1244-1250. doi: 10.1002/jat.3635. [PMID: 29766525]
  • Yi-Ping Hou, Xue-Wei Mao, Xiang-Pu Qu, Jian-Xin Wang, Chang-Jun Chen, Ming-Guo Zhou. Molecular and biological characterization of Sclerotinia sclerotiorum resistant to the anilinopyrimidine fungicide cyprodinil. Pesticide biochemistry and physiology. 2018 Apr; 146(?):80-89. doi: 10.1016/j.pestbp.2018.03.001. [PMID: 29626996]
  • Bartosz Piechowicz, Karolina Mróz, Ewa Szpyrka, Aneta Zwolak, Przemysław Grodzicki. Transfer of plant protection products from raspberry crops of Laszka and Seedling varieties to beehives. Environmental monitoring and assessment. 2018 Feb; 190(3):135. doi: 10.1007/s10661-018-6491-z. [PMID: 29435675]
  • Madeline E Dowling, Patricia K Bryson, Harriet G Boatwright, Jennifer R Wilson, Zhen Fan, Sydney E Everhart, Phillip M Brannen, Guido Schnabel. Effect of Fungicide Applications on Monilinia fructicola Population Diversity and Transposon Movement. Phytopathology. 2016 12; 106(12):1504-1512. doi: 10.1094/phyto-03-16-0127-r. [PMID: 27452900]
  • Meng-Jun Hu, Kerik D Cox, Guido Schnabel. Resistance to Increasing Chemical Classes of Fungicides by Virtue of 'Selection by Association' in Botrytis cinerea. Phytopathology. 2016 12; 106(12):1513-1520. doi: 10.1094/phyto-04-16-0161-r. [PMID: 27503370]
  • Magdalena Jankowska, Piotr Kaczynski, Izabela Hrynko, Bozena Lozowicka. Dissipation of six fungicides in greenhouse-grown tomatoes with processing and health risk. Environmental science and pollution research international. 2016 Jun; 23(12):11885-900. doi: 10.1007/s11356-016-6260-x. [PMID: 26957431]
  • Jochen P Zubrod, Dominic Englert, Alexander Feckler, Natalia Koksharova, Marco Konschak, Rebecca Bundschuh, Nadja Schnetzer, Katja Englert, Ralf Schulz, Mirco Bundschuh. Does the current fungicide risk assessment provide sufficient protection for key drivers in aquatic ecosystem functioning?. Environmental science & technology. 2015 Jan; 49(2):1173-81. doi: 10.1021/es5050453. [PMID: 25517729]
  • Magdalena Słowik-Borowiec, Ewa Szpyrka, Julian Rupar, Aneta Matyaszek, Magdalena Podbielska. Pesticide residues in stone fruits from the south-eastern region of Poland in 2012-2104. Roczniki Panstwowego Zakladu Higieny. 2015; 66(3):211-6. doi: . [PMID: 26400116]
  • N N Misra, S K Pankaj, Tony Walsh, Finbarr O'Regan, Paula Bourke, P J Cullen. In-package nonthermal plasma degradation of pesticides on fresh produce. Journal of hazardous materials. 2014 Apr; 271(?):33-40. doi: 10.1016/j.jhazmat.2014.02.005. [PMID: 24598029]
  • Pierre Leroux, Michel Gredt, Florent Remuson, Annie Micoud, Anne-Sophie Walker. Fungicide resistance status in French populations of the wheat eyespot fungi Oculimacula acuformis and Oculimacula yallundae. Pest management science. 2013 Jan; 69(1):15-26. doi: 10.1002/ps.3408. [PMID: 23073993]
  • Aneta Matyaszek, Ewa Szpyrka, Magdalena Podbielska, Magdalena Słowik-Borowiec, Anna Kurdziel. Pesticide residues in berries harvested from South-Eastern Poland (2009-2011). Roczniki Panstwowego Zakladu Higieny. 2013; 64(1):25-9. doi: . [PMID: 23789309]
  • Xuyang Liang, Xingang Liu, Fengshou Dong, Jun Xu, Dongmei Qin, Yuanbo Li, Yingying Tian, Ying Zhang, Yongtao Han, Yongquan Zheng. Simultaneous determination of pyrimethanil, cyprodinil, mepanipyrim and its metabolite in fresh and home-processed fruit and vegetables by a QuEChERS method coupled with UPLC-MS/MS. Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment. 2013; 30(4):713-21. doi: 10.1080/19440049.2013.768777. [PMID: 23410121]
  • Thomas Veloukas, George S Karaoglanidis. Biological activity of the succinate dehydrogenase inhibitor fluopyram against Botrytis cinerea and fungal baseline sensitivity. Pest management science. 2012 Jun; 68(6):858-64. doi: 10.1002/ps.3241. [PMID: 22262495]
  • Francesc A Esteve-Turrillas, Consuelo Agulló, Antonio Abad-Fuentes, Antonio Abad-Somovilla, Josep V Mercader. Immunoreagent generation and competitive assay development for cyprodinil analysis. Journal of agricultural and food chemistry. 2012 May; 60(19):4803-11. doi: 10.1021/jf300319n. [PMID: 22500467]
  • Arnaud Auber, Marc Roucaute, Anne Togola, Thierry Caquet. Structural and functional effects of conventional and low pesticide input crop-protection programs on benthic macroinvertebrate communities in outdoor pond mesocosms. Ecotoxicology (London, England). 2011 Nov; 20(8):2042-55. doi: 10.1007/s10646-011-0747-5. [PMID: 21792661]
  • José Fenoll, Encarnación Ruiz, Pilar Hellín, Pilar Flores, Simón Navarro. Heterogeneous photocatalytic oxidation of cyprodinil and fludioxonil in leaching water under solar irradiation. Chemosphere. 2011 Nov; 85(8):1262-8. doi: 10.1016/j.chemosphere.2011.07.022. [PMID: 21840030]
  • George S Karaoglanidis, Anastasios N Markoglou, George A Bardas, Eleftherios G Doukas, Sotiris Konstantinou, John F Kalampokis. Sensitivity of Penicillium expansum field isolates to tebuconazole, iprodione, fludioxonil and cyprodinil and characterization of fitness parameters and patulin production. International journal of food microbiology. 2011 Jan; 145(1):195-204. doi: 10.1016/j.ijfoodmicro.2010.12.017. [PMID: 21251724]
  • David E Wedge, Jerome A Klun, Nurhayat Tabanca, Betul Demirci, Temel Ozek, Kemal Husnu Can Baser, Zhijun Liu, Sui Zhang, Charles L Cantrell, Jian Zhang. Bioactivity-guided fractionation and GC/MS fingerprinting of Angelica sinensis and Angelica archangelica root components for antifungal and mosquito deterrent activity. Journal of agricultural and food chemistry. 2009 Jan; 57(2):464-70. doi: 10.1021/jf802820d. [PMID: 19113871]
  • Mark P McQuilken, J Thomson. Evaluation of anilinopyrimidine and other fungicides for control of grey mould (Botrytis cinerea) in container-grown Calluna vulgaris. Pest management science. 2008 Jul; 64(7):748-54. doi: 10.1002/ps.1552. [PMID: 18286666]
  • G A Bardas, C K Myresiotis, G S Karaoglanidis. Stability and fitness of anilinopyrimidine-resistant strains of Botrytis cinerea. Phytopathology. 2008 Apr; 98(4):443-50. doi: 10.1094/phyto-98-4-0443. [PMID: 18944193]
  • Anna Machowska, Magdalena Słowik-Borowiec, Ewa Szpyrka, Stanisław Sadło. [Occurrence of plant protection product residues in apples in 2007]. Roczniki Panstwowego Zakladu Higieny. 2008; 59(3):293-300. doi: ". [PMID: 19143426]
  • Xiuzhu Yu, F R van de Voort, J Sedman. Determination of peroxide value of edible oils by FTIR spectroscopy with the use of the spectral reconstitution technique. Talanta. 2007 Nov; 74(2):241-6. doi: 10.1016/j.talanta.2007.06.004. [PMID: 18371636]
  • Vera Meyer, Robbert A Damveld, Mark Arentshorst, Ulf Stahl, Cees A M J J van den Hondel, Arthur F J Ram. Survival in the presence of antifungals: genome-wide expression profiling of Aspergillus niger in response to sublethal concentrations of caspofungin and fenpropimorph. The Journal of biological chemistry. 2007 Nov; 282(45):32935-48. doi: 10.1074/jbc.m705856200. [PMID: 17804411]
  • Nurhayat Tabanca, Betul Demirci, Sara L Crockett, Kemal Hüsnü Can Başer, David E Wedge. Chemical composition and antifungal activity of Arnica longifolia, Aster hesperius, and Chrysothamnus nauseosus essential oils. Journal of agricultural and food chemistry. 2007 Oct; 55(21):8430-5. doi: 10.1021/jf071379c. [PMID: 17894463]
  • Nurhayat Tabanca, Betul Demirci, Kemal Husnu Can Baser, Zeki Aytac, Murat Ekici, Shabana I Khan, Melissa R Jacob, David E Wedge. Chemical composition and antifungal activity of Salvia macrochlamys and Salvia recognita essential oils. Journal of agricultural and food chemistry. 2006 Sep; 54(18):6593-7. doi: 10.1021/jf0608773. [PMID: 16939314]
  • José Eugenio López-Periago, Manuel Arias-Estévez, Benedicto Soto-González, Sara Trelles-Reinoso, Jesús Simal-Gándara. Influence of methanol on the dynamics of the retention and release of cyprodinil by an agricultural soil. Journal of agricultural and food chemistry. 2006 Jun; 54(13):4751-7. doi: 10.1021/jf053128e. [PMID: 16787024]
  • M Arias, A C Torrente, E López, B Soto, J Simal-Gándara. Adsorption-desorption dynamics of cyprodinil and fludioxonil in vineyard soils. Journal of agricultural and food chemistry. 2005 Jul; 53(14):5675-81. doi: 10.1021/jf048023a. [PMID: 15998132]
  • Larissa Dsikowitzky, Jan Schwarzbauer, Alexander Kronimus, Ralf Littke. The anthropogenic contribution to the organic load of the Lippe River (Germany). Part I: Qualitative characterisation of low-molecular weight organic compounds. Chemosphere. 2004 Dec; 57(10):1275-88. doi: 10.1016/j.chemosphere.2004.08.052. [PMID: 15519372]
  • Melanie Sapp, Tanya Ertunç, Inken Bringmann, Andreas Schäffer, Burkhard Schmidt. Characterization of the bound residues of the fungicide cyprodinil formed in plant cell suspension cultures of wheat. Pest management science. 2004 Jan; 60(1):65-74. doi: 10.1002/ps.787. [PMID: 14727743]
  • B H Lipshutz, P A Blomgren. Efficient scavenging of Ph3P and Ph3P=O with high-loading merrifield resin. Organic letters. 2001 Jun; 3(12):1869-71. doi: 10.1021/ol0159219. [PMID: 11405732]
  • A Ruíz, M J Ayora Cañada, B Lendl. A rapid method for peroxide value determination in edible oils based on flow analysis with Fourier transform infrared spectroscopic detection. The Analyst. 2001 Feb; 126(2):242-6. doi: 10.1039/b008688f. [PMID: 11235111]
  • S Takeda, P G Sim, D F Horrobin, T Sanford, K A Chisholm, V Simmons. Mechanism of lipid peroxidation in cancer cells in response to gamma-linolenic acid (GLA) analyzed by GC-MS(I): Conjugated dienes with peroxyl (or hydroperoxyl) groups and cell-killing effects. Anticancer research. 1993 Jan; 13(1):193-9. doi: . [PMID: 8386494]
  • B Raman, V M Shinde. Extraction, separation and spectrophotometric determination of cadmium and mercury using triphenylphosphine oxide and its application to environmental samples. The Analyst. 1990 Jan; 115(1):93-8. doi: 10.1039/an9901500093. [PMID: 2334057]