NCBI Taxonomy: 52476

Imperatoria (ncbi_taxid: 52476)

found 27 associated metabolites at genus taxonomy rank level.

Ancestor: Selineae

Child Taxonomies: none taxonomy data.

Isoimperatorin

7,4-[(3-methyl-2-butenyl)oxy]-7H-furo[3,2-g]-1-benzopyran-7-one

C16H14O4 (270.0892044)


Isoimperatorin is a member of the class of compounds known as psoralens. Psoralens are organic compounds containing a psoralen moiety, which consists of a furan fused to a chromenone to for 7H-furo[3,2-g]chromen-7-one. Isoimperatorin is practically insoluble (in water) and an extremely weak basic (essentially neutral) compound (based on its pKa). Isoimperatorin can be found in a number of food items such as parsley, lime, wild celery, and parsnip, which makes isoimperatorin a potential biomarker for the consumption of these food products. Isoimperatorin is a non-carcinogenic (not listed by IARC) potentially toxic compound. If the compound has been ingested, rapid gastric lavage should be performed using 5\\\\% sodium bicarbonate. For skin contact, the skin should be washed with soap and water. If the compound has entered the eyes, they should be washed with large quantities of isotonic saline or water. In serious cases, atropine and/or pralidoxime should be administered. Anti-cholinergic drugs work to counteract the effects of excess acetylcholine and reactivate AChE. Atropine can be used as an antidote in conjunction with pralidoxime or other pyridinium oximes (such as trimedoxime or obidoxime), though the use of -oximes has been found to be of no benefit, or possibly harmful, in at least two meta-analyses. Atropine is a muscarinic antagonist, and thus blocks the action of acetylcholine peripherally (T3DB). D011838 - Radiation-Sensitizing Agents > D017319 - Photosensitizing Agents > D011564 - Furocoumarins Isoimperatorin is a methanolic extract of the roots of Angelica dahurica shows significant inhibitory effects on acetylcholinesterase (AChE) with the IC50 of 74.6 μM. Isoimperatorin is a methanolic extract of the roots of Angelica dahurica shows significant inhibitory effects on acetylcholinesterase (AChE) with the IC50 of 74.6 μM.

   

Imperatorin

InChI=1/C16H14O4/c1-10(2)5-7-19-16-14-12(6-8-18-14)9-11-3-4-13(17)20-15(11)16/h3-6,8-9H,7H2,1-2H

C16H14O4 (270.0892044)


Imperatorin is a member of the class of psoralens that is psoralen substituted by a prenyloxy group at position 8. Isolated from Angelica dahurica and Angelica koreana, it acts as a acetylcholinesterase inhibitor. It has a role as an EC 3.1.1.7 (acetylcholinesterase) inhibitor and a metabolite. Imperatorin is a natural product found in Allium wallichii, Ammi visnaga, and other organisms with data available. Imperatorin is found in anise. Imperatorin is present in Aegle marmelos (bael fruit) and seeds of Pastinaca sativa (parsnip).Imperatorin is a furocoumarin and a phytochemical that has been isolated from Urena lobata L. (Malvaceae). It is biosynthesized from umbelliferone, a coumarin derivative.Imperatorin has been shown to exhibit anti-hypertrophic and anti-convulsant functions (A7784, A7785).Imperatorin belongs to the family of Furanocoumarins. These are polycyclic aromatic compounds containing a furan ring fused to a coumarin moeity. See also: Angelica Dahurica Root (part of); Aegle marmelos fruit (part of); Ammi majus seed (part of) ... View More ... Imperatorin is found in anise. Imperatorin is present in Aegle marmelos (bael fruit) and seeds of Pastinaca sativa (parsnip).Imperatorin is a furocoumarin and a phytochemical that has been isolated from Urena lobata L. (Malvaceae). It is biosynthesized from umbelliferone, a coumarin derivative A member of the class of psoralens that is psoralen substituted by a prenyloxy group at position 8. Isolated from Angelica dahurica and Angelica koreana, it acts as a acetylcholinesterase inhibitor. D011838 - Radiation-Sensitizing Agents > D017319 - Photosensitizing Agents > D011564 - Furocoumarins Present in Aegle marmelos (bael fruit) and seeds of Pastinaca sativa (parsnip) INTERNAL_ID 2244; CONFIDENCE Reference Standard (Level 1) CONFIDENCE Reference Standard (Level 1); INTERNAL_ID 2244 Imperatorin is an effective of NO synthesis inhibitor (IC50=9.2 μmol), which also is a BChE inhibitor (IC50=31.4 μmol). Imperatorin is a weak agonist of TRPV1 with EC50 of 12.6±3.2 μM. Imperatorin is an effective of NO synthesis inhibitor (IC50=9.2 μmol), which also is a BChE inhibitor (IC50=31.4 μmol). Imperatorin is a weak agonist of TRPV1 with EC50 of 12.6±3.2 μM.

   

Ostruthin

2H-1-Benzopyran-2-one, 6-(3,7-dimethyl-2,6-octadienyl)-7-hydroxy-, (E)- (9CI)

C19H22O3 (298.15688620000003)


A natural product found in Peucedanum ostruthium.

   

Cnidilide

(3S,3aS,7aR)-3-butyl-3a,4,5,7a-tetrahydro-3H-2-benzofuran-1-one

C12H18O2 (194.1306728)


Cnidilide is a member of the class of compounds known as isobenzofurans. Isobenzofurans are organic aromatic compounds containing an isobenzofuran moiety. Cnidilide is practically insoluble (in water) and an extremely weak basic (essentially neutral) compound (based on its pKa). Cnidilide can be found in wild celery, which makes cnidilide a potential biomarker for the consumption of this food product.

   

Ligustilide

(3E)-3-butylidene-1,3,4,5-tetrahydro-2-benzofuran-1-one

C12H14O2 (190.09937440000002)


Constituent of Angelica subspecies Ligustilide is found in wild celery, lovage, and herbs and spices. Ligustilide is found in herbs and spices. Ligustilide is a constituent of Angelica specie

   

Oxypeucedanin hydrate

4-(2,3-dihydroxy-3-methylbutoxy)-7H-furo[3,2-g]chromen-7-one

C16H16O6 (304.0946836)


   

Imperatorin

Imperatorin

C16H14O4 (270.0892044)


Imperatorin is an effective of NO synthesis inhibitor (IC50=9.2 μmol), which also is a BChE inhibitor (IC50=31.4 μmol). Imperatorin is a weak agonist of TRPV1 with EC50 of 12.6±3.2 μM. Imperatorin is an effective of NO synthesis inhibitor (IC50=9.2 μmol), which also is a BChE inhibitor (IC50=31.4 μmol). Imperatorin is a weak agonist of TRPV1 with EC50 of 12.6±3.2 μM.

   

4-(2,3-dihydroxy-3-methylbutoxy)furo[3,2-g]chromen-7-one

NCGC00169070-02!4-(2,3-dihydroxy-3-methylbutoxy)furo[3,2-g]chromen-7-one

C16H16O6 (304.0946836)


   

Isoimperatorin

Isoimperatorin

C16H14O4 (270.0892044)


D011838 - Radiation-Sensitizing Agents > D017319 - Photosensitizing Agents > D011564 - Furocoumarins Origin: Plant, Coumarins Isoimperatorin is a methanolic extract of the roots of Angelica dahurica shows significant inhibitory effects on acetylcholinesterase (AChE) with the IC50 of 74.6 μM. Isoimperatorin is a methanolic extract of the roots of Angelica dahurica shows significant inhibitory effects on acetylcholinesterase (AChE) with the IC50 of 74.6 μM.

   

Osthole

Osthole

C15H16O3 (244.1099386)


Annotation level-1

   

Ostruthol

Ostruthol

C21H22O7 (386.1365462)


A natural product found in Peucedanum ostruthium.

   

Cnidilide

1(3H)-Isobenzofuranone, 3-butyl-3a,4,5,7a-tetrahydro-, (3S-(3alpha,3abeta,7abeta))-

C12H18O2 (194.1306728)


   

Senkyunolide A

1(3H)-Isobenzofuranone, 3-butyl-4,5-dihydro-, (S)-

C12H16O2 (192.1150236)


Senkyunolide A, isolated from Ligusticum chuanxiong Hort, has cytoprotective and antiproliferative activities. Anti-tumor activity[1][2]. Senkyunolide A, isolated from Ligusticum chuanxiong Hort, has cytoprotective and antiproliferative activities. Anti-tumor activity[1][2].

   

Oxypeucedanin

Oxypeucedanin

C16H14O5 (286.0841194)


A furanocoumarin that is 7H-furo[3,2-g][1]benzopyran-7-one substituted by a [(2S)-3,3-dimethyloxiran-2-yl]methoxy group at position 4. D011838 - Radiation-Sensitizing Agents > D017319 - Photosensitizing Agents > D011564 - Furocoumarins

   

(+)-oxypeucedanin

(+)-oxypeucedanin

C16H14O5 (286.0841194)


A natural product found in Citrus hystrix.

   

3-hydroxy-2-methyl-4-({7-oxofuro[3,2-g]chromen-4-yl}oxy)butan-2-yl acetate

3-hydroxy-2-methyl-4-({7-oxofuro[3,2-g]chromen-4-yl}oxy)butan-2-yl acetate

C18H18O7 (346.10524780000003)


   

(2e)-4-(7-hydroxy-2-oxochromen-6-yl)-2-methylbut-2-enoic acid

(2e)-4-(7-hydroxy-2-oxochromen-6-yl)-2-methylbut-2-enoic acid

C14H12O5 (260.0684702)


   

4-(3-hydroxy-3-methyl-2-{[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}butoxy)furo[3,2-g]chromen-7-one

4-(3-hydroxy-3-methyl-2-{[3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}butoxy)furo[3,2-g]chromen-7-one

C22H26O11 (466.14750460000005)


   

4-[(2s)-3-hydroxy-3-methyl-2-{[(2r,3r,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}butoxy]furo[3,2-g]chromen-7-one

4-[(2s)-3-hydroxy-3-methyl-2-{[(2r,3r,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy}butoxy]furo[3,2-g]chromen-7-one

C22H26O11 (466.14750460000005)


   

(3r)-3-hydroxy-2-methyl-4-({7-oxofuro[3,2-g]chromen-4-yl}oxy)butan-2-yl acetate

(3r)-3-hydroxy-2-methyl-4-({7-oxofuro[3,2-g]chromen-4-yl}oxy)butan-2-yl acetate

C18H18O7 (346.10524780000003)


   

4-(7-hydroxy-2-oxochromen-6-yl)-2-methylbut-2-enoic acid

4-(7-hydroxy-2-oxochromen-6-yl)-2-methylbut-2-enoic acid

C14H12O5 (260.0684702)


   

3-hydroxy-3-methyl-1-({7-oxofuro[3,2-g]chromen-4-yl}oxy)butan-2-yl 2-methylbut-2-enoate

3-hydroxy-3-methyl-1-({7-oxofuro[3,2-g]chromen-4-yl}oxy)butan-2-yl 2-methylbut-2-enoate

C21H22O7 (386.1365462)


   

(1s,2s,4s,5s,6s,7s,8s,9r,12r)-6-(hydroxymethyl)-2,10,10-trimethyl-11-oxatricyclo[7.2.1.0¹,⁶]dodecane-4,5,7,8,12-pentol

(1s,2s,4s,5s,6s,7s,8s,9r,12r)-6-(hydroxymethyl)-2,10,10-trimethyl-11-oxatricyclo[7.2.1.0¹,⁶]dodecane-4,5,7,8,12-pentol

C15H26O7 (318.16784459999997)


   

5,7-dihydroxy-2-methyl-6-(3-methylbut-2-en-1-yl)chromen-4-one

5,7-dihydroxy-2-methyl-6-(3-methylbut-2-en-1-yl)chromen-4-one

C15H16O4 (260.1048536)


   

6-(3,7-dimethylocta-2,6-dien-1-yl)-7-hydroxychromen-2-one

6-(3,7-dimethylocta-2,6-dien-1-yl)-7-hydroxychromen-2-one

C19H22O3 (298.15688620000003)


   

(2r)-3-hydroxy-3-methyl-1-({7-oxofuro[3,2-g]chromen-4-yl}oxy)butan-2-yl (2e)-2-methylbut-2-enoate

(2r)-3-hydroxy-3-methyl-1-({7-oxofuro[3,2-g]chromen-4-yl}oxy)butan-2-yl (2e)-2-methylbut-2-enoate

C21H22O7 (386.1365462)


   

(2r)-3-hydroxy-3-methyl-1-({7-oxofuro[3,2-g]chromen-4-yl}oxy)butan-2-yl 2-methylbut-2-enoate

(2r)-3-hydroxy-3-methyl-1-({7-oxofuro[3,2-g]chromen-4-yl}oxy)butan-2-yl 2-methylbut-2-enoate

C21H22O7 (386.1365462)