NCBI Taxonomy: 2741557

Marquandomyces (ncbi_taxid: 2741557)

found 50 associated metabolites at genus taxonomy rank level.

Ancestor: Clavicipitaceae

Child Taxonomies: Marquandomyces marquandii, unclassified Marquandomyces, Marquandomyces cf. marquandii

Cyclo(Leu-Phe)

(3S,6S)-3-benzyl-6-(2-methylpropyl)-3,6-dihydropyrazine-2,5-diol

C15H20N2O2 (260.15247)


Cyclo(leu-phe), also known as cyclo(Phe-leu) or cFL, is classified as an alpha amino acid or an Alpha amino acid derivative. Alpha amino acids are amino acids in which the amino group is attached to the carbon atom immediately adjacent to the carboxylate group (alpha carbon), or a derivative thereof. Cyclo(leu-phe) is considered to be a practically insoluble (in water) and a moderately acidic compound. Cyclo(leu-phe) can be found in feces.

   

L,L-Cyclo(leucylprolyl)

(3S,8aS)-1-hydroxy-3-(2-methylpropyl)-3H,4H,6H,7H,8H,8aH-pyrrolo[1,2-a]pyrazin-4-one

C11H18N2O2 (210.1368208)


L,L-Cyclo(leucylprolyl) is found in alcoholic beverages. L,L-Cyclo(leucylprolyl) is produced by microorganisms and is a bitter component of sake and contributes to the flavour of beer. L,L-Cyclo(leucylprolyl), also known as cyclo(leu-pro) or cyclo(L-prolyl-L-leucyl), belongs to the class of organic compounds known as alpha amino acids and derivatives. These are amino acids in which the amino group is attached to the carbon atom immediately adjacent to the carboxylate group (alpha carbon), or a derivative thereof. L,L-Cyclo(leucylprolyl) is a secondary metabolite. Secondary metabolites are metabolically or physiologically non-essential metabolites that may serve a role as defense or signalling molecules. In some cases they are simply molecules that arise from the incomplete metabolism of other secondary metabolites. Based on a literature review a significant number of articles have been published on L,L-Cyclo(leucylprolyl). L-Leucyl-L-proline lactam. CAS Common Chemistry. CAS, a division of the American Chemical Society, n.d. https://commonchemistry.cas.org/detail?cas_rn=2873-36-1 (retrieved 2024-07-10) (CAS RN: 2873-36-1). Licensed under the Attribution-Noncommercial 4.0 International License (CC BY-NC 4.0). Cyclo(L-Leu-L-Pro) is an inhibitory substance targeting to production of norsolorinic acid (NA,a precursor of aflatoxin),which can be isolated from A. xylosoxidans NFRI-A1. Cyclo(L-Leu-L-Pro) inhibits accumulation of NA by A. parasiticus NFRI-95 and inhibits spore formation. Cyclo(L-Leu-L-Pro) inhibits aflatoxin production with an IC50 of 0.2 mg/mL in A. parasiticus SYS-4[1].

   

(3r)-n-{1-[(1-{[(1s)-1-{[1-({1-[(2-{[(2s)-1-(dimethylamino)propan-2-yl]-c-hydroxycarbonimidoyl}ethyl)-c-hydroxycarbonimidoyl]-1-methylethyl}-c-hydroxycarbonimidoyl)-1-methylethyl]-c-hydroxycarbonimidoyl}-3-methylbutyl]-c-hydroxycarbonimidoyl}-3-methylbutyl)-c-hydroxycarbonimidoyl]-1-methylethyl}-3-hydroxy-2-{[(2s)-1-hydroxy-2-({hydroxy[(2s,4s)-4-methyl-1-[(2e,4r)-4-methylhex-2-enoyl]pyrrolidin-2-yl]methylidene}amino)-4-methylpentylidene]amino}-4-methylpentanimidic acid

(3r)-n-{1-[(1-{[(1s)-1-{[1-({1-[(2-{[(2s)-1-(dimethylamino)propan-2-yl]-c-hydroxycarbonimidoyl}ethyl)-c-hydroxycarbonimidoyl]-1-methylethyl}-c-hydroxycarbonimidoyl)-1-methylethyl]-c-hydroxycarbonimidoyl}-3-methylbutyl]-c-hydroxycarbonimidoyl}-3-methylbutyl)-c-hydroxycarbonimidoyl]-1-methylethyl}-3-hydroxy-2-{[(2s)-1-hydroxy-2-({hydroxy[(2s,4s)-4-methyl-1-[(2e,4r)-4-methylhex-2-enoyl]pyrrolidin-2-yl]methylidene}amino)-4-methylpentylidene]amino}-4-methylpentanimidic acid

C57H103N11O11 (1117.7838128)


   

1-hydroxy-3-(2-methylpropyl)-3h,6h,7h,8h,8ah-pyrrolo[1,2-a]pyrazin-4-one

1-hydroxy-3-(2-methylpropyl)-3h,6h,7h,8h,8ah-pyrrolo[1,2-a]pyrazin-4-one

C11H18N2O2 (210.1368208)


   

4-hydroxy-3-[4-hydroxy-1-(4-hydroxy-5-methyl-2-oxo-5h-furan-3-yl)hexyl]-5-methyl-5h-furan-2-one

4-hydroxy-3-[4-hydroxy-1-(4-hydroxy-5-methyl-2-oxo-5h-furan-3-yl)hexyl]-5-methyl-5h-furan-2-one

C16H22O7 (326.1365462)


   

(2s,4s,6r)-n-[(1s,2r)-1-[(1-{[(1s)-1-{[(1s)-1-{[1-({1-[(2-{[(2s)-1-(dimethylamino)propan-2-yl]-c-hydroxycarbonimidoyl}ethyl)-c-hydroxycarbonimidoyl]-1-methylethyl}-c-hydroxycarbonimidoyl)-1-methylethyl]-c-hydroxycarbonimidoyl}-3-methylbutyl]-c-hydroxycarbonimidoyl}-3-methylbutyl]-c-hydroxycarbonimidoyl}-1-methylethyl)-c-hydroxycarbonimidoyl]-2-hydroxy-3-methylbutyl]-6-hydroxy-2-({hydroxy[(2s,4s)-4-methyl-1-[(2e,4s)-4-methylhex-2-enoyl]pyrrolidin-2-yl]methylidene}amino)-4-methyl-8-oxodecanimidic acid

(2s,4s,6r)-n-[(1s,2r)-1-[(1-{[(1s)-1-{[(1s)-1-{[1-({1-[(2-{[(2s)-1-(dimethylamino)propan-2-yl]-c-hydroxycarbonimidoyl}ethyl)-c-hydroxycarbonimidoyl]-1-methylethyl}-c-hydroxycarbonimidoyl)-1-methylethyl]-c-hydroxycarbonimidoyl}-3-methylbutyl]-c-hydroxycarbonimidoyl}-3-methylbutyl]-c-hydroxycarbonimidoyl}-1-methylethyl)-c-hydroxycarbonimidoyl]-2-hydroxy-3-methylbutyl]-6-hydroxy-2-({hydroxy[(2s,4s)-4-methyl-1-[(2e,4s)-4-methylhex-2-enoyl]pyrrolidin-2-yl]methylidene}amino)-4-methyl-8-oxodecanimidic acid

C62H111N11O13 (1217.8362396)


   

(3s,6s)-3-[(2s)-butan-2-yl]-6-(2-methylpropyl)-3,6-dihydropyrazine-2,5-diol

(3s,6s)-3-[(2s)-butan-2-yl]-6-(2-methylpropyl)-3,6-dihydropyrazine-2,5-diol

C12H22N2O2 (226.1681192)


   

(2r,4r,6s)-n-[(1r,2r)-1-[(1-{[(1s)-1-{[(1s)-1-{[1-({1-[(2-{[(2s)-1-(dimethyl-oxo-λ⁵-azanyl)propan-2-yl]-c-hydroxycarbonimidoyl}ethyl)-c-hydroxycarbonimidoyl]-1-methylethyl}-c-hydroxycarbonimidoyl)-1-methylethyl]-c-hydroxycarbonimidoyl}-3-methylbutyl]-c-hydroxycarbonimidoyl}-3-methylbutyl]-c-hydroxycarbonimidoyl}-1-methylethyl)-c-hydroxycarbonimidoyl]-2-hydroxy-3-methylbutyl]-6-hydroxy-2-({hydroxy[(2s,4s)-4-methyl-1-[(2e,4r)-4-methylhex-2-enoyl]pyrrolidin-2-yl]methylidene}amino)-4-methyl-8-oxodecanimidic acid

(2r,4r,6s)-n-[(1r,2r)-1-[(1-{[(1s)-1-{[(1s)-1-{[1-({1-[(2-{[(2s)-1-(dimethyl-oxo-λ⁵-azanyl)propan-2-yl]-c-hydroxycarbonimidoyl}ethyl)-c-hydroxycarbonimidoyl]-1-methylethyl}-c-hydroxycarbonimidoyl)-1-methylethyl]-c-hydroxycarbonimidoyl}-3-methylbutyl]-c-hydroxycarbonimidoyl}-3-methylbutyl]-c-hydroxycarbonimidoyl}-1-methylethyl)-c-hydroxycarbonimidoyl]-2-hydroxy-3-methylbutyl]-6-hydroxy-2-({hydroxy[(2s,4s)-4-methyl-1-[(2e,4r)-4-methylhex-2-enoyl]pyrrolidin-2-yl]methylidene}amino)-4-methyl-8-oxodecanimidic acid

C62H111N11O14 (1233.8311546)


   

n-(1-{[1-({1-[(1-{[1-({1-[(2-{[1-(dimethylamino)propan-2-yl]-c-hydroxycarbonimidoyl}ethyl)-c-hydroxycarbonimidoyl]-1-methylethyl}-c-hydroxycarbonimidoyl)-1-methylethyl]-c-hydroxycarbonimidoyl}-3-methylbutyl)-c-hydroxycarbonimidoyl]-3-methylbutyl}-c-hydroxycarbonimidoyl)-1-methylethyl]-c-hydroxycarbonimidoyl}-2-hydroxy-3-methylbutyl)-6-hydroxy-2-{[hydroxy({4-methyl-1-[(2e)-4-methylhex-2-enoyl]pyrrolidin-2-yl})methylidene]amino}-4-methyl-8-oxodecanimidic acid

n-(1-{[1-({1-[(1-{[1-({1-[(2-{[1-(dimethylamino)propan-2-yl]-c-hydroxycarbonimidoyl}ethyl)-c-hydroxycarbonimidoyl]-1-methylethyl}-c-hydroxycarbonimidoyl)-1-methylethyl]-c-hydroxycarbonimidoyl}-3-methylbutyl)-c-hydroxycarbonimidoyl]-3-methylbutyl}-c-hydroxycarbonimidoyl)-1-methylethyl]-c-hydroxycarbonimidoyl}-2-hydroxy-3-methylbutyl)-6-hydroxy-2-{[hydroxy({4-methyl-1-[(2e)-4-methylhex-2-enoyl]pyrrolidin-2-yl})methylidene]amino}-4-methyl-8-oxodecanimidic acid

C62H111N11O13 (1217.8362396)


   

3-(2-methylpropyl)-6-(sec-butyl)-3,6-dihydropyrazine-2,5-diol

3-(2-methylpropyl)-6-(sec-butyl)-3,6-dihydropyrazine-2,5-diol

C12H22N2O2 (226.1681192)


   

4-(3-hydroxyphenyl)-3h-quinoline-2,3,4-triol

4-(3-hydroxyphenyl)-3h-quinoline-2,3,4-triol

C15H13NO4 (271.0844538)


   

3-benzyl-6-isopropyl-3,6-dihydropyrazine-2,5-diol

3-benzyl-6-isopropyl-3,6-dihydropyrazine-2,5-diol

C14H18N2O2 (246.1368208)


   

n-(1-{[1-({1-[(1-{[1-({1-[(2-{[1-(dimethyl-oxo-λ⁵-azanyl)propan-2-yl]-c-hydroxycarbonimidoyl}ethyl)-c-hydroxycarbonimidoyl]-1-methylethyl}-c-hydroxycarbonimidoyl)-1-methylethyl]-c-hydroxycarbonimidoyl}-3-methylbutyl)-c-hydroxycarbonimidoyl]-3-methylbutyl}-c-hydroxycarbonimidoyl)-1-methylethyl]-c-hydroxycarbonimidoyl}-2-hydroxy-3-methylbutyl)-6-hydroxy-2-({hydroxy[4-methyl-1-(4-methylhex-2-enoyl)pyrrolidin-2-yl]methylidene}amino)-4-methyl-8-oxodecanimidic acid

n-(1-{[1-({1-[(1-{[1-({1-[(2-{[1-(dimethyl-oxo-λ⁵-azanyl)propan-2-yl]-c-hydroxycarbonimidoyl}ethyl)-c-hydroxycarbonimidoyl]-1-methylethyl}-c-hydroxycarbonimidoyl)-1-methylethyl]-c-hydroxycarbonimidoyl}-3-methylbutyl)-c-hydroxycarbonimidoyl]-3-methylbutyl}-c-hydroxycarbonimidoyl)-1-methylethyl]-c-hydroxycarbonimidoyl}-2-hydroxy-3-methylbutyl)-6-hydroxy-2-({hydroxy[4-methyl-1-(4-methylhex-2-enoyl)pyrrolidin-2-yl]methylidene}amino)-4-methyl-8-oxodecanimidic acid

C62H111N11O14 (1233.8311546)


   

3-benzyl-6-(2-methylpropyl)-3,6-dihydropyrazine-2,5-diol

3-benzyl-6-(2-methylpropyl)-3,6-dihydropyrazine-2,5-diol

C15H20N2O2 (260.15247)


   

n-(1-{[1-({1-[(1-{[1-({1-[(2-{[5-(aminooxy)pentan-2-yl]-c-hydroxycarbonimidoyl}ethyl)-c-hydroxycarbonimidoyl]-1-methylethyl}-c-hydroxycarbonimidoyl)-1-methylethyl]-c-hydroxycarbonimidoyl}-3-methylbutyl)-c-hydroxycarbonimidoyl]-3-methylbutyl}-c-hydroxycarbonimidoyl)-1-methylethyl]-c-hydroxycarbonimidoyl}-2-hydroxy-3-methylbutyl)-6-hydroxy-2-{[hydroxy({4-methyl-1-[(2e,4r)-4-methylhex-2-enoyl]pyrrolidin-2-yl})methylidene]amino}-4-methyl-8-oxodecanimidic acid

n-(1-{[1-({1-[(1-{[1-({1-[(2-{[5-(aminooxy)pentan-2-yl]-c-hydroxycarbonimidoyl}ethyl)-c-hydroxycarbonimidoyl]-1-methylethyl}-c-hydroxycarbonimidoyl)-1-methylethyl]-c-hydroxycarbonimidoyl}-3-methylbutyl)-c-hydroxycarbonimidoyl]-3-methylbutyl}-c-hydroxycarbonimidoyl)-1-methylethyl]-c-hydroxycarbonimidoyl}-2-hydroxy-3-methylbutyl)-6-hydroxy-2-{[hydroxy({4-methyl-1-[(2e,4r)-4-methylhex-2-enoyl]pyrrolidin-2-yl})methylidene]amino}-4-methyl-8-oxodecanimidic acid

C62H111N11O14 (1233.8311546)


   

(5r)-4-hydroxy-3-[(4s)-4-hydroxy-1-[(5r)-4-hydroxy-5-methyl-2-oxo-5h-furan-3-yl]hexyl]-5-methyl-5h-furan-2-one

(5r)-4-hydroxy-3-[(4s)-4-hydroxy-1-[(5r)-4-hydroxy-5-methyl-2-oxo-5h-furan-3-yl]hexyl]-5-methyl-5h-furan-2-one

C16H22O7 (326.1365462)


   

{4-[(3-acetyl-2,6-dihydroxy-5-methylphenyl)methyl]-3-hydroxy-5-oxo-2h-furan-2-yl}acetic acid

{4-[(3-acetyl-2,6-dihydroxy-5-methylphenyl)methyl]-3-hydroxy-5-oxo-2h-furan-2-yl}acetic acid

C16H16O8 (336.0845136)


   

(2r,3s)-n-(1-{[(1s)-1-{[(1s)-1-{[1-({1-[(2-{[(2s)-1-(dimethyl-oxo-λ⁵-azanyl)propan-2-yl]-c-hydroxycarbonimidoyl}ethyl)-c-hydroxycarbonimidoyl]-1-methylethyl}-c-hydroxycarbonimidoyl)-1-methylethyl]-c-hydroxycarbonimidoyl}-3-methylbutyl]-c-hydroxycarbonimidoyl}-3-methylbutyl]-c-hydroxycarbonimidoyl}-1-methylethyl)-3-hydroxy-2-{[(2s)-1-hydroxy-2-({hydroxy[(2r,4s)-4-methyl-1-[(2z,4r)-4-methylhex-2-enoyl]pyrrolidin-2-yl]methylidene}amino)-4-methylpentylidene]amino}-4-methylpentanimidic acid

(2r,3s)-n-(1-{[(1s)-1-{[(1s)-1-{[1-({1-[(2-{[(2s)-1-(dimethyl-oxo-λ⁵-azanyl)propan-2-yl]-c-hydroxycarbonimidoyl}ethyl)-c-hydroxycarbonimidoyl]-1-methylethyl}-c-hydroxycarbonimidoyl)-1-methylethyl]-c-hydroxycarbonimidoyl}-3-methylbutyl]-c-hydroxycarbonimidoyl}-3-methylbutyl]-c-hydroxycarbonimidoyl}-1-methylethyl)-3-hydroxy-2-{[(2s)-1-hydroxy-2-({hydroxy[(2r,4s)-4-methyl-1-[(2z,4r)-4-methylhex-2-enoyl]pyrrolidin-2-yl]methylidene}amino)-4-methylpentylidene]amino}-4-methylpentanimidic acid

C57H103N11O12 (1133.7787278)


   

4,9-dihydroxy-10-(1-hydroxyhexa-2,4-dien-1-ylidene)-7,9-dimethyl-3,5-diazatricyclo[5.2.2.0²,⁶]undec-3-ene-8,11-dione

4,9-dihydroxy-10-(1-hydroxyhexa-2,4-dien-1-ylidene)-7,9-dimethyl-3,5-diazatricyclo[5.2.2.0²,⁶]undec-3-ene-8,11-dione

C17H20N2O5 (332.137215)


   

(1r,2s,6r,7r,9s,10z)-4,9-dihydroxy-10-[(2e,4e)-1-hydroxyhexa-2,4-dien-1-ylidene]-7,9-dimethyl-3,5-diazatricyclo[5.2.2.0²,⁶]undec-3-ene-8,11-dione

(1r,2s,6r,7r,9s,10z)-4,9-dihydroxy-10-[(2e,4e)-1-hydroxyhexa-2,4-dien-1-ylidene]-7,9-dimethyl-3,5-diazatricyclo[5.2.2.0²,⁶]undec-3-ene-8,11-dione

C17H20N2O5 (332.137215)


   

(3r,4r)-4-(3-hydroxyphenyl)-3h-quinoline-2,3,4-triol

(3r,4r)-4-(3-hydroxyphenyl)-3h-quinoline-2,3,4-triol

C15H13NO4 (271.0844538)


   

n-[1-({1-[(1-{[1-({1-[(2-{[1-(dimethylamino)propan-2-yl]-c-hydroxycarbonimidoyl}ethyl)-c-hydroxycarbonimidoyl]-1-methylethyl}-c-hydroxycarbonimidoyl)-1-methylethyl]-c-hydroxycarbonimidoyl}-3-methylbutyl)-c-hydroxycarbonimidoyl]-3-methylbutyl}-c-hydroxycarbonimidoyl)-1-methylethyl]-3-hydroxy-2-[(1-hydroxy-2-{[hydroxy({4-methyl-1-[(2e)-4-methylhex-2-enoyl]pyrrolidin-2-yl})methylidene]amino}-4-methylpentylidene)amino]-4-methylpentanimidic acid

n-[1-({1-[(1-{[1-({1-[(2-{[1-(dimethylamino)propan-2-yl]-c-hydroxycarbonimidoyl}ethyl)-c-hydroxycarbonimidoyl]-1-methylethyl}-c-hydroxycarbonimidoyl)-1-methylethyl]-c-hydroxycarbonimidoyl}-3-methylbutyl)-c-hydroxycarbonimidoyl]-3-methylbutyl}-c-hydroxycarbonimidoyl)-1-methylethyl]-3-hydroxy-2-[(1-hydroxy-2-{[hydroxy({4-methyl-1-[(2e)-4-methylhex-2-enoyl]pyrrolidin-2-yl})methylidene]amino}-4-methylpentylidene)amino]-4-methylpentanimidic acid

C57H103N11O11 (1117.7838128)


   

n-[1-({1-[(1-{[1-({1-[(2-{[1-(dimethyl-oxo-λ⁵-azanyl)propan-2-yl]-c-hydroxycarbonimidoyl}ethyl)-c-hydroxycarbonimidoyl]-1-methylethyl}-c-hydroxycarbonimidoyl)-1-methylethyl]-c-hydroxycarbonimidoyl}-3-methylbutyl)-c-hydroxycarbonimidoyl]-3-methylbutyl}-c-hydroxycarbonimidoyl)-1-methylethyl]-3-hydroxy-2-{[1-hydroxy-2-({hydroxy[4-methyl-1-(4-methylhex-2-enoyl)pyrrolidin-2-yl]methylidene}amino)-4-methylpentylidene]amino}-4-methylpentanimidic acid

n-[1-({1-[(1-{[1-({1-[(2-{[1-(dimethyl-oxo-λ⁵-azanyl)propan-2-yl]-c-hydroxycarbonimidoyl}ethyl)-c-hydroxycarbonimidoyl]-1-methylethyl}-c-hydroxycarbonimidoyl)-1-methylethyl]-c-hydroxycarbonimidoyl}-3-methylbutyl)-c-hydroxycarbonimidoyl]-3-methylbutyl}-c-hydroxycarbonimidoyl)-1-methylethyl]-3-hydroxy-2-{[1-hydroxy-2-({hydroxy[4-methyl-1-(4-methylhex-2-enoyl)pyrrolidin-2-yl]methylidene}amino)-4-methylpentylidene]amino}-4-methylpentanimidic acid

C57H103N11O12 (1133.7787278)


   

n-[1-({1-[(1-{[1-({1-[(2-{[5-(aminooxy)pentan-2-yl]-c-hydroxycarbonimidoyl}ethyl)-c-hydroxycarbonimidoyl]-1-methylethyl}-c-hydroxycarbonimidoyl)-1-methylethyl]-c-hydroxycarbonimidoyl}-3-methylbutyl)-c-hydroxycarbonimidoyl]-3-methylbutyl}-c-hydroxycarbonimidoyl)-1-methylethyl]-3-hydroxy-2-[(1-hydroxy-2-{[hydroxy({4-methyl-1-[(2e,4r)-4-methylhex-2-enoyl]pyrrolidin-2-yl})methylidene]amino}-4-methylpentylidene)amino]-4-methylpentanimidic acid

n-[1-({1-[(1-{[1-({1-[(2-{[5-(aminooxy)pentan-2-yl]-c-hydroxycarbonimidoyl}ethyl)-c-hydroxycarbonimidoyl]-1-methylethyl}-c-hydroxycarbonimidoyl)-1-methylethyl]-c-hydroxycarbonimidoyl}-3-methylbutyl)-c-hydroxycarbonimidoyl]-3-methylbutyl}-c-hydroxycarbonimidoyl)-1-methylethyl]-3-hydroxy-2-[(1-hydroxy-2-{[hydroxy({4-methyl-1-[(2e,4r)-4-methylhex-2-enoyl]pyrrolidin-2-yl})methylidene]amino}-4-methylpentylidene)amino]-4-methylpentanimidic acid

C57H103N11O12 (1133.7787278)


   

(3s,6s)-3-benzyl-6-isopropyl-3,6-dihydropyrazine-2,5-diol

(3s,6s)-3-benzyl-6-isopropyl-3,6-dihydropyrazine-2,5-diol

C14H18N2O2 (246.1368208)