NCBI Taxonomy: 255780

Dichotomomyces (ncbi_taxid: 255780)

found 43 associated metabolites at genus taxonomy rank level.

Ancestor: Aspergillaceae

Child Taxonomies: unclassified Dichotomomyces

Patulin

(2,4-Dihydroxy-2H-pyran-3(6H)-ylidene)acetic acid, 3,4-lactone

C7H6O4 (154.0266076)


Patulin is found in pomes. Mycotoxin, found as a contaminant of foods, e.g. apple juice. Sometimes detd. in apple juice Patulin is a mycotoxin produced by a variety of molds, particularly Aspergillus and Penicillium. It is commonly found in rotting apples, and the amount of patulin in apple products is generally viewed as a measure of the quality of the apples used in production. It is not a particularly potent toxin, but a number of studies have shown that it is genotoxic, which has led to some theories that it may be a carcinogen, though animal studies have remained inconclusive. Patulin is also an antibiotic. Several countries have instituted patulin restrictions in apple products. The World Health Organization recommends a maximum concentration of 50 µg/L in apple juice Mycotoxin, found as a contaminant of foods, e.g. apple juice. Sometimes detd. in apple juice D009676 - Noxae > D011042 - Poisons > D009183 - Mycotoxins D009676 - Noxae > D009153 - Mutagens Patulin (Terinin) is a mycotoxin produced by fungi including the Aspergillus, Penicillium, and Byssochlamys species, is suspected to be clastogenic, mutagenic, teratogenic and cytotoxic. Patulin induces autophagy-dependent apoptosis through lysosomal-mitochondrial axis, and causes DNA damage[1][2][3][4].

   

Gliotoxin

10H-3,10a-Epidithiopyrazino(1,2-a)indole-1,4-dione, 2,3,5a,6-hydroxy-3- (hydroxymethyl)-2-methyl-, (3R-(3-alpha,5a-beta,6-beta,10a-alpha))-

C13H14N2O4S2 (326.0394964)


Gliotoxin is a pyrazinoindole with a disulfide bridge spanning a dioxo-substituted pyrazine ring; mycotoxin produced by several species of fungi. It has a role as a mycotoxin, an immunosuppressive agent, an EC 2.5.1.58 (protein farnesyltransferase) inhibitor, a proteasome inhibitor and an antifungal agent. It is an organic disulfide, a pyrazinoindole, an organic heterotetracyclic compound and a dipeptide. Gliotoxin is a natural product found in Streptomyces, Aspergillus cejpii, and other organisms with data available. Gliotoxin is a sulfur-containing antibiotic produced by several species of fungi, some of which are pathogens of humans such as Aspergillus, and also by species of Trichoderma, and Penicillium. Gliotoxin possesses immunosuppressive properties as it may suppress and cause apoptosis in certain types of cells of the immune system, including neutrophils, eosinophils, granulocytes, macrophages, and thymocytes. (L1941) A fungal toxin produced by various species of Trichoderma, Gladiocladium fimbriatum, Aspergillus fumigatus, and Penicillium. It is used as an immunosuppressive agent. A pyrazinoindole with a disulfide bridge spanning a dioxo-substituted pyrazine ring; mycotoxin produced by several species of fungi. D007155 - Immunologic Factors > D007166 - Immunosuppressive Agents D009676 - Noxae > D011042 - Poisons > D009183 - Mycotoxins C308 - Immunotherapeutic Agent > C574 - Immunosuppressant

   

Gliotoxin

7-hydroxy-11-(hydroxymethyl)-15-methyl-12,13-dithia-9,15-diazatetracyclo[9.2.2.0¹,⁹.0³,⁸]pentadeca-3,5-diene-10,14-dione

C13H14N2O4S2 (326.0394964)


   
   

patulin

patulin

C7H6O4 (154.0266076)


D009676 - Noxae > D011042 - Poisons > D009183 - Mycotoxins CONFIDENCE standard compound; INTERNAL_ID 5971 D009676 - Noxae > D009153 - Mutagens CONFIDENCE Reference Standard (Level 1) Patulin (Terinin) is a mycotoxin produced by fungi including the Aspergillus, Penicillium, and Byssochlamys species, is suspected to be clastogenic, mutagenic, teratogenic and cytotoxic. Patulin induces autophagy-dependent apoptosis through lysosomal-mitochondrial axis, and causes DNA damage[1][2][3][4].

   

(5as,6s,10ar)-10a-hydroxy-2-methyl-3-methylidene-1,4-dioxo-5ah,6h,10h-pyrazino[1,2-a]indol-6-yl acetate

(5as,6s,10ar)-10a-hydroxy-2-methyl-3-methylidene-1,4-dioxo-5ah,6h,10h-pyrazino[1,2-a]indol-6-yl acetate

C15H16N2O5 (304.1059166)


   

(3s,5as,6s,10ar)-10a-{[(3s,5as,6s,10ar)-6-(acetyloxy)-10a-hydroxy-3-(hydroxymethyl)-2-methyl-1,4-dioxo-5ah,6h,10h-pyrazino[1,2-a]indol-3-yl]disulfanyl}-3-(hydroxymethyl)-2-methyl-3-(methylsulfanyl)-1,4-dioxo-5ah,6h,10h-pyrazino[1,2-a]indol-6-yl acetate

(3s,5as,6s,10ar)-10a-{[(3s,5as,6s,10ar)-6-(acetyloxy)-10a-hydroxy-3-(hydroxymethyl)-2-methyl-1,4-dioxo-5ah,6h,10h-pyrazino[1,2-a]indol-3-yl]disulfanyl}-3-(hydroxymethyl)-2-methyl-3-(methylsulfanyl)-1,4-dioxo-5ah,6h,10h-pyrazino[1,2-a]indol-6-yl acetate

C31H36N4O11S3 (736.1542625999999)


   

n-(1-hydroxy-4-methylhexan-2-yl)-2-methylhexa-2,4-dienimidic acid

n-(1-hydroxy-4-methylhexan-2-yl)-2-methylhexa-2,4-dienimidic acid

C14H25NO2 (239.188519)


   

(2r,3s,4s,5s,6r)-2-(hydroxymethyl)-6-{[(1s,12s,15r,16s,17s,20s)-1,16,20-trimethyl-16-(4-methylpent-3-en-1-yl)-3-azapentacyclo[10.8.0.0²,¹⁰.0⁴,⁹.0¹⁵,²⁰]icosa-2(10),4,6,8-tetraen-17-yl]oxy}oxane-3,4,5-triol

(2r,3s,4s,5s,6r)-2-(hydroxymethyl)-6-{[(1s,12s,15r,16s,17s,20s)-1,16,20-trimethyl-16-(4-methylpent-3-en-1-yl)-3-azapentacyclo[10.8.0.0²,¹⁰.0⁴,⁹.0¹⁵,²⁰]icosa-2(10),4,6,8-tetraen-17-yl]oxy}oxane-3,4,5-triol

C34H49NO6 (567.3559694)


   

(1s,7s,8s,11s)-11-(hydroxymethyl)-12-methyl-10,13-dioxo-14-thia-9,12-diazatetracyclo[9.2.1.0¹,⁹.0³,⁸]tetradeca-3,5-dien-7-yl acetate

(1s,7s,8s,11s)-11-(hydroxymethyl)-12-methyl-10,13-dioxo-14-thia-9,12-diazatetracyclo[9.2.1.0¹,⁹.0³,⁸]tetradeca-3,5-dien-7-yl acetate

C15H16N2O5S (336.0779886)


   

n-(1-{[2-(1h-indol-3-yl)acetyl]oxy}-4-methylpentan-2-yl)-2-methylhexa-2,4-dienimidic acid

n-(1-{[2-(1h-indol-3-yl)acetyl]oxy}-4-methylpentan-2-yl)-2-methylhexa-2,4-dienimidic acid

C23H30N2O3 (382.225631)


   

(1r,7s,8s,11r)-11-(hydroxymethyl)-17-methyl-10,16-dioxo-12,13,14,15-tetrathia-9,17-diazatetracyclo[9.4.2.0¹,⁹.0³,⁸]heptadeca-3,5-dien-7-yl acetate

(1r,7s,8s,11r)-11-(hydroxymethyl)-17-methyl-10,16-dioxo-12,13,14,15-tetrathia-9,17-diazatetracyclo[9.4.2.0¹,⁹.0³,⁸]heptadeca-3,5-dien-7-yl acetate

C15H16N2O5S4 (431.9942046)


   

2-methanesulfinyl-1,4-dimethoxynaphthalene

2-methanesulfinyl-1,4-dimethoxynaphthalene

C13H14O3S (250.0663614)


   

2-methyl-3-(methylsulfanyl)-3h-pyrazino[1,2-a]indole-1,4-dione

2-methyl-3-(methylsulfanyl)-3h-pyrazino[1,2-a]indole-1,4-dione

C13H12N2O2S (260.0619452)


   

3-(hydroxymethyl)-2-methyl-3-(methylsulfanyl)pyrazino[1,2-a]indole-1,4-dione

3-(hydroxymethyl)-2-methyl-3-(methylsulfanyl)pyrazino[1,2-a]indole-1,4-dione

C14H14N2O3S (290.07250940000006)


   

(2z,4e)-n-[(2s)-1-hydroxy-4-methylpentan-2-yl]-2-methylhexa-2,4-dienimidic acid

(2z,4e)-n-[(2s)-1-hydroxy-4-methylpentan-2-yl]-2-methylhexa-2,4-dienimidic acid

C13H23NO2 (225.1728698)


   

4-[(1z,3z)-2,3-diisocyano-4-(4-methoxyphenyl)buta-1,3-dien-1-yl]phenol

4-[(1z,3z)-2,3-diisocyano-4-(4-methoxyphenyl)buta-1,3-dien-1-yl]phenol

C19H14N2O2 (302.1055224)


   

2-(hydroxymethyl)-6-{[1,16,20-trimethyl-16-(4-methylpent-3-en-1-yl)-3-azapentacyclo[10.8.0.0²,¹⁰.0⁴,⁹.0¹⁵,²⁰]icosa-2(10),4,6,8-tetraen-17-yl]oxy}oxane-3,4,5-triol

2-(hydroxymethyl)-6-{[1,16,20-trimethyl-16-(4-methylpent-3-en-1-yl)-3-azapentacyclo[10.8.0.0²,¹⁰.0⁴,⁹.0¹⁵,²⁰]icosa-2(10),4,6,8-tetraen-17-yl]oxy}oxane-3,4,5-triol

C34H49NO6 (567.3559694)


   

(3r)-3-(hydroxymethyl)-2-methyl-3-(methylsulfanyl)pyrazino[1,2-a]indole-1,4-dione

(3r)-3-(hydroxymethyl)-2-methyl-3-(methylsulfanyl)pyrazino[1,2-a]indole-1,4-dione

C14H14N2O3S (290.07250940000006)


   

(3s,5as,6s,10ar)-3-{[(3s,5as,6s,10ar)-6-hydroxy-3-(hydroxymethyl)-2-methyl-3-(methylsulfanyl)-1,4-dioxo-5ah,6h,10h-pyrazino[1,2-a]indol-10a-yl]disulfanyl}-10a-hydroxy-3-(hydroxymethyl)-2-methyl-1,4-dioxo-5ah,6h,10h-pyrazino[1,2-a]indol-6-yl acetate

(3s,5as,6s,10ar)-3-{[(3s,5as,6s,10ar)-6-hydroxy-3-(hydroxymethyl)-2-methyl-3-(methylsulfanyl)-1,4-dioxo-5ah,6h,10h-pyrazino[1,2-a]indol-10a-yl]disulfanyl}-10a-hydroxy-3-(hydroxymethyl)-2-methyl-1,4-dioxo-5ah,6h,10h-pyrazino[1,2-a]indol-6-yl acetate

C29H34N4O10S3 (694.1436984)


   

1,2,9-trimethyl-7-(2-methylprop-1-en-1-yl)-6-oxa-22-azahexacyclo[11.10.0.0²,¹⁰.0⁵,⁹.0¹⁵,²³.0¹⁶,²¹]tricosa-15(23),16,18,20-tetraene

1,2,9-trimethyl-7-(2-methylprop-1-en-1-yl)-6-oxa-22-azahexacyclo[11.10.0.0²,¹⁰.0⁵,⁹.0¹⁵,²³.0¹⁶,²¹]tricosa-15(23),16,18,20-tetraene

C28H37NO (403.2874992)


   

(3s,5ar,6r,9ar,10as)-9a-hydroxy-3-(hydroxymethyl)-2-methyl-3,10a-bis(methylsulfanyl)-1,4,7-trioxo-5ah,6h,10h-pyrazino[1,2-a]indol-6-yl acetate

(3s,5ar,6r,9ar,10as)-9a-hydroxy-3-(hydroxymethyl)-2-methyl-3,10a-bis(methylsulfanyl)-1,4,7-trioxo-5ah,6h,10h-pyrazino[1,2-a]indol-6-yl acetate

C17H22N2O7S2 (430.0868382)


   

10a-hydroxy-2-methyl-3-methylidene-1,4-dioxo-5ah,6h,10h-pyrazino[1,2-a]indol-6-yl acetate

10a-hydroxy-2-methyl-3-methylidene-1,4-dioxo-5ah,6h,10h-pyrazino[1,2-a]indol-6-yl acetate

C15H16N2O5 (304.1059166)


   

(3s,5as,6s,10ar)-3-{[(3s,5as,6s,10ar)-6-(acetyloxy)-3-hydroxy-3-(hydroxymethyl)-2-methyl-1,4-dioxo-5ah,6h,10h-pyrazino[1,2-a]indol-10a-yl]disulfanyl}-10a-hydroxy-3-(hydroxymethyl)-2-methyl-1,4-dioxo-5ah,6h,10h-pyrazino[1,2-a]indol-6-yl acetate

(3s,5as,6s,10ar)-3-{[(3s,5as,6s,10ar)-6-(acetyloxy)-3-hydroxy-3-(hydroxymethyl)-2-methyl-1,4-dioxo-5ah,6h,10h-pyrazino[1,2-a]indol-10a-yl]disulfanyl}-10a-hydroxy-3-(hydroxymethyl)-2-methyl-1,4-dioxo-5ah,6h,10h-pyrazino[1,2-a]indol-6-yl acetate

C30H34N4O12S2 (706.1614564000001)


   

(1s,12s,15r,16s,17s,20s)-16-(4-methoxy-4-methylpent-2-en-1-yl)-1,16,20-trimethyl-3-azapentacyclo[10.8.0.0²,¹⁰.0⁴,⁹.0¹⁵,²⁰]icosa-2(10),4,6,8-tetraen-17-ol

(1s,12s,15r,16s,17s,20s)-16-(4-methoxy-4-methylpent-2-en-1-yl)-1,16,20-trimethyl-3-azapentacyclo[10.8.0.0²,¹⁰.0⁴,⁹.0¹⁵,²⁰]icosa-2(10),4,6,8-tetraen-17-ol

C29H41NO2 (435.31371260000003)


   

(2z,4e)-n-[(2s,4r)-1-hydroxy-4-methylhexan-2-yl]-2-methylhexa-2,4-dienimidic acid

(2z,4e)-n-[(2s,4r)-1-hydroxy-4-methylhexan-2-yl]-2-methylhexa-2,4-dienimidic acid

C14H25NO2 (239.188519)


   

7-(2-hydroxypropyl)-1,3,6-trimethyl-1,2,3,4-tetrahydronaphthalen-2-ol

7-(2-hydroxypropyl)-1,3,6-trimethyl-1,2,3,4-tetrahydronaphthalen-2-ol

C16H24O2 (248.1776204)


   

11-(hydroxymethyl)-12-methyl-10,13-dioxo-14-thia-9,12-diazatetracyclo[9.2.1.0¹,⁹.0³,⁸]tetradeca-3,5-dien-7-yl acetate

11-(hydroxymethyl)-12-methyl-10,13-dioxo-14-thia-9,12-diazatetracyclo[9.2.1.0¹,⁹.0³,⁸]tetradeca-3,5-dien-7-yl acetate

C15H16N2O5S (336.0779886)


   

(1s,2s,5s,7r,9s,10r,13s)-1,2,9-trimethyl-7-(2-methylprop-1-en-1-yl)-6-oxa-22-azahexacyclo[11.10.0.0²,¹⁰.0⁵,⁹.0¹⁵,²³.0¹⁶,²¹]tricosa-15(23),16,18,20-tetraene

(1s,2s,5s,7r,9s,10r,13s)-1,2,9-trimethyl-7-(2-methylprop-1-en-1-yl)-6-oxa-22-azahexacyclo[11.10.0.0²,¹⁰.0⁵,⁹.0¹⁵,²³.0¹⁶,²¹]tricosa-15(23),16,18,20-tetraene

C28H37NO (403.2874992)


   

4-(4-methoxyphenyl)-1-(3,4,5-trimethoxyphenyl)butan-2-one

4-(4-methoxyphenyl)-1-(3,4,5-trimethoxyphenyl)butan-2-one

C20H24O5 (344.1623654)


   

9a-hydroxy-3-(hydroxymethyl)-2-methyl-3,10a-bis(methylsulfanyl)-1,4,7-trioxo-5ah,6h,10h-pyrazino[1,2-a]indol-6-yl acetate

9a-hydroxy-3-(hydroxymethyl)-2-methyl-3,10a-bis(methylsulfanyl)-1,4,7-trioxo-5ah,6h,10h-pyrazino[1,2-a]indol-6-yl acetate

C17H22N2O7S2 (430.0868382)


   

n-(1-hydroxy-4-methylpentan-2-yl)-2-methylhexa-2,4-dienimidic acid

n-(1-hydroxy-4-methylpentan-2-yl)-2-methylhexa-2,4-dienimidic acid

C13H23NO2 (225.1728698)


   

5,6,7-trimethoxy-4-(4-methoxyphenyl)-3h-naphtho[2,3-d]imidazol-2-ol

5,6,7-trimethoxy-4-(4-methoxyphenyl)-3h-naphtho[2,3-d]imidazol-2-ol

C21H20N2O5 (380.137215)


   

(3s,10ar)-10a-hydroxy-3-(hydroxymethyl)-2-methyl-3h,10h-pyrazino[1,2-a]indole-1,4-dione

(3s,10ar)-10a-hydroxy-3-(hydroxymethyl)-2-methyl-3h,10h-pyrazino[1,2-a]indole-1,4-dione

C13H14N2O4 (262.0953524)


   

16-(4-methoxy-4-methylpent-2-en-1-yl)-1,16,20-trimethyl-3-azapentacyclo[10.8.0.0²,¹⁰.0⁴,⁹.0¹⁵,²⁰]icosa-2(10),4,6,8-tetraen-17-ol

16-(4-methoxy-4-methylpent-2-en-1-yl)-1,16,20-trimethyl-3-azapentacyclo[10.8.0.0²,¹⁰.0⁴,⁹.0¹⁵,²⁰]icosa-2(10),4,6,8-tetraen-17-ol

C29H41NO2 (435.31371260000003)


   

10a-hydroxy-3-(hydroxymethyl)-2-methyl-3h,10h-pyrazino[1,2-a]indole-1,4-dione

10a-hydroxy-3-(hydroxymethyl)-2-methyl-3h,10h-pyrazino[1,2-a]indole-1,4-dione

C13H14N2O4 (262.0953524)


   

methyl 6-[(4-methoxyphenyl)methyl]-5-[(3,4,5-trimethoxyphenyl)methyl]pyrazine-2-carboxylate

methyl 6-[(4-methoxyphenyl)methyl]-5-[(3,4,5-trimethoxyphenyl)methyl]pyrazine-2-carboxylate

C24H26N2O6 (438.1790776)


   

(2z,4e)-n-[(2s)-1-methoxy-4-methylpentan-2-yl]-2-methylhexa-2,4-dienimidic acid

(2z,4e)-n-[(2s)-1-methoxy-4-methylpentan-2-yl]-2-methylhexa-2,4-dienimidic acid

C14H25NO2 (239.188519)


   

n-(1-methoxy-4-methylpentan-2-yl)-2-methylhexa-2,4-dienimidic acid

n-(1-methoxy-4-methylpentan-2-yl)-2-methylhexa-2,4-dienimidic acid

C14H25NO2 (239.188519)


   

(2z,4e)-n-[(2s)-1-{[2-(1h-indol-3-yl)acetyl]oxy}-4-methylpentan-2-yl]-2-methylhexa-2,4-dienimidic acid

(2z,4e)-n-[(2s)-1-{[2-(1h-indol-3-yl)acetyl]oxy}-4-methylpentan-2-yl]-2-methylhexa-2,4-dienimidic acid

C23H30N2O3 (382.225631)


   

(1r,2r,3r)-7-[(2s)-2-hydroxypropyl]-1,3,6-trimethyl-1,2,3,4-tetrahydronaphthalen-2-ol

(1r,2r,3r)-7-[(2s)-2-hydroxypropyl]-1,3,6-trimethyl-1,2,3,4-tetrahydronaphthalen-2-ol

C16H24O2 (248.1776204)