Phenylacetaldoxime (BioDeep_00000013021)
Secondary id: BioDeep_00000897228, BioDeep_00001868678
natural product
代谢物信息卡片
N-(2-Phenylethylidene)hydroxylamine
化学式: C8H9NO (135.0684)
中文名称:
谱图信息:
最多检出来源 Viridiplantae(plant) 9.76%
分子结构信息
SMILES: C1=CC=C(C=C1)CC=NO
InChI: InChI=1S/C8H9NO/c10-9-7-6-8-4-2-1-3-5-8/h1-5,7,10H,6H2
数据库引用编号
17 个数据库交叉引用编号
- ChEBI: CHEBI:50723
- ChEBI: CHEBI:47793
- ChEBI: CHEBI:47791
- KEGG: C16075
- KEGG: C19714
- PubChem: 9638853
- PubChem: 99748
- Metlin: METLIN63615
- MetaCyc: PHENYLACETALDOXIME
- CAS: 7028-48-0
- CAS: 20268-21-7
- PMhub: MS000027377
- PubChem: 47205385
- NIKKAJI: J81.316H
- PubChem: 135626182
- KNApSAcK: C00007327
- LOTUS: LTS0269999
分类词条
相关代谢途径
Reactome(0)
代谢反应
24 个相关的代谢反应过程信息。
Reactome(0)
BioCyc(5)
- prunasin and amygdalin biosynthesis:
(R)-prunasin + UDP-α-D-glucose ⟶ (R)-amygdalin + H+ + UDP - glucosinolate biosynthesis from phenylalanine:
(Z)-2-phenyl-1-thioacetohydroximate + UDP-α-D-glucose ⟶ UDP + desulfoglucotropaeolin - glucosinolate biosynthesis from phenylalanine:
(Z)-2-phenyl-1-thioacetohydroximate + UDP-α-D-glucose ⟶ UDP + desulfoglucotropeolin - phenylethanol biosynthesis:
2-phenylethylamine + H2O + O2 ⟶ ammonium + hydrogen peroxide + phenylacetaldehyde - phenylethanol biosynthesis:
H2O + O2 + phe ⟶ CO2 + ammonia + hydrogen peroxide + phenylacetaldehyde
WikiPathways(1)
- Glucosinolate biosynthesis (from aromatic amino acid):
L-Tyrosine ⟶ (E)-4-Hydroxyphenylacetaldehyde oxime
Plant Reactome(0)
INOH(0)
PlantCyc(18)
- prunasin and amygdalin biosynthesis:
(R)-prunasin + UDP-α-D-glucose ⟶ (R)-amygdalin + H+ + UDP - glucosinolate biosynthesis from phenylalanine:
PAPS + desulfoglucotropaeolin ⟶ 3',5'-ADP + H+ + glucotropaeolin - glucosinolate biosynthesis from phenylalanine:
(Z)-1-(L-cystein-S-yl)-N-hydroxy-2-phenylethan-1-imine + H2O ⟶ (Z)-2-phenyl-1-thioacetohydroximate + H+ + ammonium + pyruvate - glucosinolate biosynthesis from phenylalanine:
(Z)-1-(L-cystein-S-yl)-N-hydroxy-2-phenylethan-1-imine + H2O ⟶ (Z)-2-phenyl-1-thioacetohydroximate + H+ + ammonium + pyruvate - glucosinolate biosynthesis from phenylalanine:
(Z)-1-(L-cystein-S-yl)-N-hydroxy-2-phenylethan-1-imine + H2O ⟶ (Z)-2-phenyl-1-thioacetohydroximate + H+ + ammonium + pyruvate - glucosinolate biosynthesis from phenylalanine:
(Z)-1-(L-cystein-S-yl)-N-hydroxy-2-phenylethan-1-imine + H2O ⟶ (Z)-2-phenyl-1-thioacetohydroximate + H+ + ammonium + pyruvate - glucosinolate biosynthesis from phenylalanine:
(Z)-1-(L-cystein-S-yl)-N-hydroxy-2-phenylethan-1-imine + H2O ⟶ (Z)-2-phenyl-1-thioacetohydroximate + H+ + ammonium + pyruvate - glucosinolate biosynthesis from phenylalanine:
(Z)-1-(L-cystein-S-yl)-N-hydroxy-2-phenylethan-1-imine + H2O ⟶ (Z)-2-phenyl-1-thioacetohydroximate + H+ + ammonium + pyruvate - glucosinolate biosynthesis from phenylalanine:
PAPS + desulfoglucotropaeolin ⟶ 3',5'-ADP + H+ + glucotropaeolin - glucosinolate biosynthesis from phenylalanine:
(Z)-1-(L-cystein-S-yl)-N-hydroxy-2-phenylethan-1-imine + H2O ⟶ (Z)-2-phenyl-1-thioacetohydroximate + H+ + ammonium + pyruvate - glucosinolate biosynthesis from phenylalanine:
(Z)-1-(L-cystein-S-yl)-N-hydroxy-2-phenylethan-1-imine + H2O ⟶ (Z)-2-phenyl-1-thioacetohydroximate + H+ + ammonium + pyruvate - glucosinolate biosynthesis from phenylalanine:
(Z)-2-phenyl-1-thioacetohydroximate + UDP-α-D-glucose ⟶ UDP + desulfoglucotropaeolin - glucosinolate biosynthesis from phenylalanine:
(Z)-1-(L-cystein-S-yl)-N-hydroxy-2-phenylethan-1-imine + H2O ⟶ (Z)-2-phenyl-1-thioacetohydroximate + H+ + ammonium + pyruvate - glucosinolate biosynthesis from phenylalanine:
(Z)-1-(L-cystein-S-yl)-N-hydroxy-2-phenylethan-1-imine + H2O ⟶ (Z)-2-phenyl-1-thioacetohydroximate + H+ + ammonium + pyruvate - glucosinolate biosynthesis from phenylalanine:
(Z)-1-(L-cystein-S-yl)-N-hydroxy-2-phenylethan-1-imine + H2O ⟶ (Z)-2-phenyl-1-thioacetohydroximate + H+ + ammonium + pyruvate - glucosinolate biosynthesis from phenylalanine:
(Z)-1-(L-cystein-S-yl)-N-hydroxy-2-phenylethan-1-imine + H2O ⟶ (Z)-2-phenyl-1-thioacetohydroximate + H+ + ammonium + pyruvate - glucosinolate biosynthesis from phenylalanine:
(Z)-1-(L-cystein-S-yl)-N-hydroxy-2-phenylethan-1-imine + H2O ⟶ (Z)-2-phenyl-1-thioacetohydroximate + H+ + ammonium + pyruvate - glucosinolate biosynthesis from phenylalanine:
(Z)-1-(L-cystein-S-yl)-N-hydroxy-2-phenylethan-1-imine + H2O ⟶ (Z)-2-phenyl-1-thioacetohydroximate + H+ + ammonium + pyruvate
COVID-19 Disease Map(0)
PathBank(0)
PharmGKB(0)
9 个相关的物种来源信息
- 3701 - Arabidopsis: LTS0269999
- 3702 - Arabidopsis thaliana: 10.1074/JBC.275.19.14659
- 3702 - Arabidopsis thaliana: LTS0269999
- 3700 - Brassicaceae: LTS0269999
- 2759 - Eukaryota: LTS0269999
- 3398 - Magnoliopsida: LTS0269999
- 35493 - Streptophyta: LTS0269999
- 58023 - Tracheophyta: LTS0269999
- 33090 - Viridiplantae: LTS0269999
在这里通过桑基图来展示出与当前的这个代谢物在我们的BioDeep知识库中具有相关联信息的其他代谢物。在这里进行关联的信息来源主要有：
- PubMed: 来源于PubMed文献库中的文献信息，我们通过自然语言数据挖掘得到的在同一篇文献中被同时提及的相关代谢物列表，这个列表按照代谢物同时出现的文献数量降序排序，取前10个代谢物作为相关研究中关联性很高的代谢物集合展示在桑基图中。
- NCBI Taxonomy: 通过文献数据挖掘，得到的代谢物物种来源信息关联。这个关联信息同样按照出现的次数降序排序，取前10个代谢物作为高关联度的代谢物集合展示在桑吉图上。
- Chemical Taxonomy: 在物质分类上处于同一个分类集合中的其他代谢物
- Chemical Reaction: 在化学反应过程中，存在为当前代谢物相关联的生化反应过程中的反应底物或者反应产物的关联代谢物信息。
点击图上的相关代谢物的名称，可以跳转到相关代谢物的信息页面。
| 亚细胞结构定位 | 关联基因列表 |
|---|
文献列表
- Guadalupe L Fernández-Milmanda. What to do when your ants go marching: Ant-deprived Tococa produce protoxin phenylacetaldoxime glucoside in response to herbivory.
Plant physiology.
2023 Dec; 194(1):314-316. doi:
10.1093/plphys/kiad492. [PMID: 37675650] - Andrea T Müller, Yoko Nakamura, Michael Reichelt, Katrin Luck, Eric Cosio, Nathalie Lackus, Jonathan Gershenzon, Axel Mithöfer, Tobias G Köllner. Biosynthesis, herbivore induction, and defensive role of phenylacetaldoxime glucoside.
Plant physiology.
2023 Aug; ?(?):. doi:
10.1093/plphys/kiad448. [PMID: 37584327] - Veronica C Perez, Ru Dai, Breanna Tomiczek, Jorrel Mendoza, Emily S A Wolf, Alexander Grenning, Wilfred Vermerris, Anna K Block, Jeongim Kim. Metabolic link between auxin production and specialized metabolites in Sorghum bicolor.
Journal of experimental botany.
2023 01; 74(1):364-376. doi:
10.1093/jxb/erac421. [PMID: 36300527] - Lasse Janniche Nielsen, Birger Lindberg Møller. Scent emission profiles from Darwin's orchid--Angraecum sesquipedale: Investigation of the aldoxime metabolism using clustering analysis.
Phytochemistry.
2015 Dec; 120(?):3-18. doi:
10.1016/j.phytochem.2015.10.004. [PMID: 26603277] - Sandra Irmisch, Philipp Zeltner, Vinzenz Handrick, Jonathan Gershenzon, Tobias G Köllner. The maize cytochrome P450 CYP79A61 produces phenylacetaldoxime and indole-3-acetaldoxime in heterologous systems and might contribute to plant defense and auxin formation.
BMC plant biology.
2015 May; 15(?):128. doi:
10.1186/s12870-015-0526-1. [PMID: 26017568] - Sandra Irmisch, Andrea Clavijo McCormick, Jan Günther, Axel Schmidt, Gerhard Andreas Boeckler, Jonathan Gershenzon, Sybille B Unsicker, Tobias G Köllner. Herbivore-induced poplar cytochrome P450 enzymes of the CYP71 family convert aldoximes to nitriles which repel a generalist caterpillar.
The Plant journal : for cell and molecular biology.
2014 Dec; 80(6):1095-107. doi:
10.1111/tpj.12711. [PMID: 25335755] - Sandra Irmisch, Andrea Clavijo McCormick, G Andreas Boeckler, Axel Schmidt, Michael Reichelt, Bernd Schneider, Katja Block, Jörg-Peter Schnitzler, Jonathan Gershenzon, Sybille B Unsicker, Tobias G Köllner. Two herbivore-induced cytochrome P450 enzymes CYP79D6 and CYP79D7 catalyze the formation of volatile aldoximes involved in poplar defense.
The Plant cell.
2013 Nov; 25(11):4737-54. doi:
10.1105/tpc.113.118265. [PMID: 24220631] - . .
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