Reaction Process: BioCyc:ARA_PWYQT-4450

aliphatic glucosinolate biosynthesis, side chain elongation cycle related metabolites

find 8 related metabolites which is associated with chemical reaction(pathway) aliphatic glucosinolate biosynthesis, side chain elongation cycle

7-(methylthio)-2-oxoheptanoate + a proteinogenic amino acid ⟶ L-trihomomethionine + a 2-oxo carboxylate

dihomomethionine

(S)-2-Amino-6-(methylthio)hexanoic acid

C7H15NO2S (177.082345)


A sulfur-containing amino acid consisting of 2-aminohexanoic acid having a methylthio substituent at the 6-position.

   

trihomomethionine

(2S)-2-amino-7-(methylsulfanyl)heptanoic acid

C8H17NO2S (191.0979942)


A sulfur-containing amino acid consisting of 2-aminoheptanoic acid having a methylthio substituent at the 7-position.

   

pentahomomethionine

(2R)-2-amino-9-methylsulfanylnonanoic acid

C10H21NO2S (219.1292926)


A sulfur-containing amino acid consisting of 2-aminononanoic acid having a methylthio substituent at the 9-position.

   

hexahomomethionine

(2R)-2-amino-10-methylsulfanyldecanoic acid

C11H23NO2S (233.1449418)


A sulfur-containing amino acid consisting of 2-aminodecanoic acid having a methylthio substituent at the 10-position.

   

2-oxo-6-methylthiohexanoate

6-(Methylsulphanyl)-2-oxohexanoic acid

C7H11O3S- (175.0428876)


2-oxo-6-methylthiohexanoate, also known as 6-(methylthio)-2-oxohexanoic acid, belongs to medium-chain keto acids and derivatives class of compounds. Those are keto acids with a 6 to 12 carbon atoms long side chain. 2-oxo-6-methylthiohexanoate is practically insoluble (in water) and a weakly acidic compound (based on its pKa). 2-oxo-6-methylthiohexanoate can be found in a number of food items such as soursop, nance, turmeric, and strawberry guava, which makes 2-oxo-6-methylthiohexanoate a potential biomarker for the consumption of these food products.

   

9-(Methylthio)-2-oxononanoate

9-(Methylthio)-2-oxononanoate

C10H17O3S- (217.0898352)


   

10-(Methylthio)-2-oxodecanoate

10-(Methylthio)-2-oxodecanoate

C11H19O3S- (231.1054844)