NCBI Taxonomy: 1123467

Ayapana amygdalina (ncbi_taxid: 1123467)

found 40 associated metabolites at species taxonomy rank level.

Ancestor: Ayapana

Child Taxonomies: none taxonomy data.

alpha-Humulene

trans,trans,trans-2,6,6,9-Tetramethyl-1,4,8-cycloundecatriene

C15H24 (204.1878)


alpha-Humulene, also known as alpha-caryophyllene, belongs to the class of organic compounds known as sesquiterpenoids. These are terpenes with three consecutive isoprene units. Thus, alpha-humulene is considered to be an isoprenoid lipid molecule. alpha-Humulene is found in allspice. alpha-Humulene is a constituent of many essential oils including hops (Humulus lupulus) and cloves (Syzygium aromaticum). (1E,4E,8E)-alpha-humulene is the (1E,4E,8E)-isomer of alpha-humulene. Humulene is a natural product found in Nepeta nepetella, Teucrium montanum, and other organisms with data available. See also: Caryophyllene (related). α-Humulene is a main constituent of Tanacetum vulgare L. (Asteraceae) essential oil with anti-inflammation (IC50=15±2 μg/mL). α-Humulene inhibits COX-2 and iNOS expression[1]. α-Humulene is a main constituent of Tanacetum vulgare L. (Asteraceae) essential oil with anti-inflammation (IC50=15±2 μg/mL). α-Humulene inhibits COX-2 and iNOS expression[1].

   

beta-Caryophyllene

trans-(1R,9S)-4,11,11-Trimethyl-8-methylenebicyclo[7.2.0]undec-4-ene

C15H24 (204.1878)


beta-Caryophyllene, also known as caryophyllene or (−)-β-caryophyllene, is a natural bicyclic sesquiterpene that is a constituent of many essential oils including that of Syzygium aromaticum (cloves), Cannabis sativa, rosemary, and hops. It is usually found as a mixture with isocaryophyllene (the cis double bond isomer) and α-humulene (obsolete name: α-caryophyllene), a ring-opened isomer. beta-Caryophyllene is notable for having both a cyclobutane ring and a trans-double bond in a nine-membered ring, both rarities in nature (Wikipedia). beta-Caryophyllene is a sweet and dry tasting compound that can be found in a number of food items such as allspice, fig, pot marjoram, and roman camomile, which makes beta-caryophyllene a potential biomarker for the consumption of these food products. beta-Caryophyllene can be found in feces and saliva. (-)-Caryophyllene. CAS Common Chemistry. CAS, a division of the American Chemical Society, n.d. https://commonchemistry.cas.org/detail?cas_rn=87-44-5 (retrieved 2024-08-07) (CAS RN: 87-44-5). Licensed under the Attribution-Noncommercial 4.0 International License (CC BY-NC 4.0). β-Caryophyllene is a CB2 receptor agonist. β-Caryophyllene is a CB2 receptor agonist.

   

Germacrene D

(1E,6E,8S)-1-methyl-8-(1-methylethyl)-5-methylidenecyclodeca-1,6-diene

C15H24 (204.1878)


Germacrene d, also known as germacrene d, (s-(e,e))-isomer, is a member of the class of compounds known as germacrane sesquiterpenoids. Germacrane sesquiterpenoids are sesquiterpenoids having the germacrane skeleton, with a structure characterized by a cyclodecane ring substituted with an isopropyl and two methyl groups. Germacrene d can be found in a number of food items such as peppermint, roman camomile, hyssop, and common walnut, which makes germacrene d a potential biomarker for the consumption of these food products.

   

(Z)-2,6,10-Bisabolatriene

(1Z)-bisabola-1(10),4,7(11)-triene (4Z)-4-(1,5-dimethylhex-4-en-1-ylidene)-1-methylcyclohexene

C15H24 (204.1878)


   

(E)-gamma-Bisabolene

(1E)-bisabola-1(10),4,7(11)-triene (4E)-4-(1,5-dimethylhex-4-en-1-ylidene)-1-methylcyclohexene

C15H24 (204.1878)


   

alpha-Caryophyllene

2,6,6,9-tetramethylcycloundeca-1,4,8-triene

C15H24 (204.1878)


α-Humulene is a main constituent of Tanacetum vulgare L. (Asteraceae) essential oil with anti-inflammation (IC50=15±2 μg/mL). α-Humulene inhibits COX-2 and iNOS expression[1]. α-Humulene is a main constituent of Tanacetum vulgare L. (Asteraceae) essential oil with anti-inflammation (IC50=15±2 μg/mL). α-Humulene inhibits COX-2 and iNOS expression[1].

   

cis-beta-Bergamotene

(1R,5R,6R)-6-methyl-2-methylidene-6-(4-methylpent-3-en-1-yl)bicyclo[3.1.1]heptane

C15H24 (204.1878)


Cis-beta-bergamotene can be found in carrot and wild carrot, which makes cis-beta-bergamotene a potential biomarker for the consumption of these food products.

   

Germacrene D

1,6-Cyclodecadiene, 1-methyl-5-methylene-8-(1-methylethyl)-, [s-(E,E)]-

C15H24 (204.1878)


(-)-germacrene D is a germacrene D. It is an enantiomer of a (+)-germacrene D. (-)-Germacrene D is a natural product found in Teucrium montanum, Stachys obliqua, and other organisms with data available. See also: Clary Sage Oil (part of).

   

caryophyllene

(-)-beta-Caryophyllene

C15H24 (204.1878)


A beta-caryophyllene in which the stereocentre adjacent to the exocyclic double bond has S configuration while the remaining stereocentre has R configuration. It is the most commonly occurring form of beta-caryophyllene, occurring in many essential oils, particularly oil of cloves. D018373 - Peripheral Nervous System Agents > D018689 - Sensory System Agents D002491 - Central Nervous System Agents > D000700 - Analgesics D000893 - Anti-Inflammatory Agents D018501 - Antirheumatic Agents β-Caryophyllene is a CB2 receptor agonist. β-Caryophyllene is a CB2 receptor agonist.

   

(Z)-2,6,10-Bisabolatriene

(4E)-1-methyl-4-(6-methylhept-5-en-2-ylidene)cyclohex-1-ene

C15H24 (204.1878)


Flavouring ingredient used singly or as mixed isomers. Component of FEMA 3331. See also 2,7,10-Bisabolatriene JHG85-W. 2,6,10-Bisabolatriene is found in many foods, some of which are wild carrot, anise, peppermint, and ginger. 2,6,10-Bisabolatriene is found in anise. 2,6,10-Bisabolatriene is a flavouring ingredient used singly or as mixed isomers. 2,6,10-Bisabolatriene is a component of FEMA 3331. See also 2,7,10-Bisabolatriene JHG85-W

   

Humulene

trans,trans,trans-2,6,6,9-Tetramethyl-1,4,8-cycloundecatriene

C15H24 (204.1878)


α-Humulene is a main constituent of Tanacetum vulgare L. (Asteraceae) essential oil with anti-inflammation (IC50=15±2 μg/mL). α-Humulene inhibits COX-2 and iNOS expression[1]. α-Humulene is a main constituent of Tanacetum vulgare L. (Asteraceae) essential oil with anti-inflammation (IC50=15±2 μg/mL). α-Humulene inhibits COX-2 and iNOS expression[1].

   

gamma-BISABOLENE, (E)-

gamma-BISABOLENE, (E)-

C15H24 (204.1878)


   

5-{2,3-dimethyltricyclo[2.2.1.0²,⁶]heptan-3-yl}-2-methylpent-2-enal

5-{2,3-dimethyltricyclo[2.2.1.0²,⁶]heptan-3-yl}-2-methylpent-2-enal

C15H22O (218.1671)


   

methyl 5-(3,6-dihydroxy-5,5,8a-trimethyl-2-methylidene-hexahydro-1h-naphthalen-1-yl)-3-methylpent-2-enoate

methyl 5-(3,6-dihydroxy-5,5,8a-trimethyl-2-methylidene-hexahydro-1h-naphthalen-1-yl)-3-methylpent-2-enoate

C21H34O4 (350.2457)


   

methyl 5-{2,3-dimethyltricyclo[2.2.1.0²,⁶]heptan-3-yl}-2-methylpent-2-enoate

methyl 5-{2,3-dimethyltricyclo[2.2.1.0²,⁶]heptan-3-yl}-2-methylpent-2-enoate

C16H24O2 (248.1776)


   

methyl 5-(6-hydroxy-5,5,8a-trimethyl-2-oxo-hexahydro-1h-naphthalen-1-yl)-3-methylpent-2-enoate

methyl 5-(6-hydroxy-5,5,8a-trimethyl-2-oxo-hexahydro-1h-naphthalen-1-yl)-3-methylpent-2-enoate

C20H32O4 (336.23)


   

methyl (2z)-5-[(1s,2r,4as,6r,8ar)-2-formyl-2,6-dihydroxy-5,5,8a-trimethyl-hexahydro-1h-naphthalen-1-yl]-3-methylpent-2-enoate

methyl (2z)-5-[(1s,2r,4as,6r,8ar)-2-formyl-2,6-dihydroxy-5,5,8a-trimethyl-hexahydro-1h-naphthalen-1-yl]-3-methylpent-2-enoate

C21H34O5 (366.2406)


   

6-methyl-2-methylidene-6-(4-methylpent-3-en-1-yl)bicyclo[3.1.1]heptane

6-methyl-2-methylidene-6-(4-methylpent-3-en-1-yl)bicyclo[3.1.1]heptane

C15H24 (204.1878)


   

methyl (2e)-2-methyl-5-[(1r,2s,3r,4r,6s)-2,3-dimethyltricyclo[2.2.1.0²,⁶]heptan-3-yl]pent-2-enoate

methyl (2e)-2-methyl-5-[(1r,2s,3r,4r,6s)-2,3-dimethyltricyclo[2.2.1.0²,⁶]heptan-3-yl]pent-2-enoate

C16H24O2 (248.1776)


   

methyl 1-(5-methoxy-3-methyl-5-oxopent-3-en-1-yl)-5,5,8a-trimethyl-octahydronaphthalene-2-carboxylate

methyl 1-(5-methoxy-3-methyl-5-oxopent-3-en-1-yl)-5,5,8a-trimethyl-octahydronaphthalene-2-carboxylate

C22H36O4 (364.2613)


   

methyl 5-(2-formyl-2,6-dihydroxy-5,5,8a-trimethyl-hexahydro-1h-naphthalen-1-yl)-3-methylpent-2-enoate

methyl 5-(2-formyl-2,6-dihydroxy-5,5,8a-trimethyl-hexahydro-1h-naphthalen-1-yl)-3-methylpent-2-enoate

C21H34O5 (366.2406)


   

methyl 5-(2-formyl-6-hydroxy-5,5,8a-trimethyl-octahydronaphthalen-1-yl)-3-methylpent-2-enoate

methyl 5-(2-formyl-6-hydroxy-5,5,8a-trimethyl-octahydronaphthalen-1-yl)-3-methylpent-2-enoate

C21H34O4 (350.2457)


   

methyl (2z)-5-[(1s,4as,6r,8ar)-6-hydroxy-5,5,8a-trimethyl-2-oxo-hexahydro-1h-naphthalen-1-yl]-3-methylpent-2-enoate

methyl (2z)-5-[(1s,4as,6r,8ar)-6-hydroxy-5,5,8a-trimethyl-2-oxo-hexahydro-1h-naphthalen-1-yl]-3-methylpent-2-enoate

C20H32O4 (336.23)


   

methyl (2z)-5-[(1s,4as,8ar)-5,5,8a-trimethyl-2,6-dioxo-hexahydronaphthalen-1-yl]-3-methylpent-2-enoate

methyl (2z)-5-[(1s,4as,8ar)-5,5,8a-trimethyl-2,6-dioxo-hexahydronaphthalen-1-yl]-3-methylpent-2-enoate

C20H30O4 (334.2144)


   

methyl (2z)-5-[(1r,2s,4as,8as)-2-formyl-5,5,8a-trimethyl-6-oxo-hexahydro-1h-naphthalen-1-yl]-3-methylpent-2-enoate

methyl (2z)-5-[(1r,2s,4as,8as)-2-formyl-5,5,8a-trimethyl-6-oxo-hexahydro-1h-naphthalen-1-yl]-3-methylpent-2-enoate

C21H32O4 (348.23)


   

methyl 5-(5,5,8a-trimethyl-2,6-dioxo-hexahydronaphthalen-1-yl)-3-methylpent-2-enoate

methyl 5-(5,5,8a-trimethyl-2,6-dioxo-hexahydronaphthalen-1-yl)-3-methylpent-2-enoate

C20H30O4 (334.2144)


   

methyl (1r,2r,4ar,8as)-1-[(3z)-5-methoxy-3-methyl-5-oxopent-3-en-1-yl]-5,5,8a-trimethyl-octahydronaphthalene-2-carboxylate

methyl (1r,2r,4ar,8as)-1-[(3z)-5-methoxy-3-methyl-5-oxopent-3-en-1-yl]-5,5,8a-trimethyl-octahydronaphthalene-2-carboxylate

C22H36O4 (364.2613)


   

methyl 5-(2-formyl-5,5,8a-trimethyl-6-oxo-hexahydro-1h-naphthalen-1-yl)-3-methylpent-2-enoate

methyl 5-(2-formyl-5,5,8a-trimethyl-6-oxo-hexahydro-1h-naphthalen-1-yl)-3-methylpent-2-enoate

C21H32O4 (348.23)


   

(2z)-2-methyl-5-[(1r,2s,3r,4r,6s)-2,3-dimethyltricyclo[2.2.1.0²,⁶]heptan-3-yl]pent-2-enal

(2z)-2-methyl-5-[(1r,2s,3r,4r,6s)-2,3-dimethyltricyclo[2.2.1.0²,⁶]heptan-3-yl]pent-2-enal

C15H22O (218.1671)


   

methyl 5-(6-hydroxy-5,5,8a-trimethyl-2-methylidene-hexahydro-1h-naphthalen-1-yl)-3-methylpent-2-enoate

methyl 5-(6-hydroxy-5,5,8a-trimethyl-2-methylidene-hexahydro-1h-naphthalen-1-yl)-3-methylpent-2-enoate

C21H34O3 (334.2508)


   

(+)-α-santalene

(+)-α-santalene

C15H24 (204.1878)


   

5-{2,3-dimethyltricyclo[2.2.1.0²,⁶]heptan-3-yl}-2-methylpent-2-en-1-ol

5-{2,3-dimethyltricyclo[2.2.1.0²,⁶]heptan-3-yl}-2-methylpent-2-en-1-ol

C15H24O (220.1827)


   

methyl (2z)-5-[(1r,2r,4as,8as)-2-formyl-5,5,8a-trimethyl-6-oxo-hexahydro-1h-naphthalen-1-yl]-3-methylpent-2-enoate

methyl (2z)-5-[(1r,2r,4as,8as)-2-formyl-5,5,8a-trimethyl-6-oxo-hexahydro-1h-naphthalen-1-yl]-3-methylpent-2-enoate

C21H32O4 (348.23)


   

methyl (2z)-5-[(1r,4as,6r,8as)-6-hydroxy-5,5,8a-trimethyl-2-methylidene-hexahydro-1h-naphthalen-1-yl]-3-methylpent-2-enoate

methyl (2z)-5-[(1r,4as,6r,8as)-6-hydroxy-5,5,8a-trimethyl-2-methylidene-hexahydro-1h-naphthalen-1-yl]-3-methylpent-2-enoate

C21H34O3 (334.2508)


   

methyl (2z)-5-[(1r,2s,4as,6r,8as)-2-formyl-6-hydroxy-5,5,8a-trimethyl-octahydronaphthalen-1-yl]-3-methylpent-2-enoate

methyl (2z)-5-[(1r,2s,4as,6r,8as)-2-formyl-6-hydroxy-5,5,8a-trimethyl-octahydronaphthalen-1-yl]-3-methylpent-2-enoate

C21H34O4 (350.2457)


   

8-isopropyl-1-methyl-5-methylidenecyclodeca-1,6-diene

8-isopropyl-1-methyl-5-methylidenecyclodeca-1,6-diene

C15H24 (204.1878)


   

methyl (2z)-5-[(1r,2r,4as,6r,8as)-2-formyl-6-hydroxy-5,5,8a-trimethyl-octahydronaphthalen-1-yl]-3-methylpent-2-enoate

methyl (2z)-5-[(1r,2r,4as,6r,8as)-2-formyl-6-hydroxy-5,5,8a-trimethyl-octahydronaphthalen-1-yl]-3-methylpent-2-enoate

C21H34O4 (350.2457)


   

methyl (1r,2r,4ar,8as)-1-[(3e)-5-methoxy-3-methyl-5-oxopent-3-en-1-yl]-5,5,8a-trimethyl-octahydronaphthalene-2-carboxylate

methyl (1r,2r,4ar,8as)-1-[(3e)-5-methoxy-3-methyl-5-oxopent-3-en-1-yl]-5,5,8a-trimethyl-octahydronaphthalene-2-carboxylate

C22H36O4 (364.2613)


   

methyl (2z)-5-[(1s,3r,4as,6r,8ar)-3,6-dihydroxy-5,5,8a-trimethyl-2-methylidene-hexahydro-1h-naphthalen-1-yl]-3-methylpent-2-enoate

methyl (2z)-5-[(1s,3r,4as,6r,8ar)-3,6-dihydroxy-5,5,8a-trimethyl-2-methylidene-hexahydro-1h-naphthalen-1-yl]-3-methylpent-2-enoate

C21H34O4 (350.2457)


   

(2z)-2-methyl-5-[(1r,2s,3r,4r,6s)-2,3-dimethyltricyclo[2.2.1.0²,⁶]heptan-3-yl]pent-2-en-1-ol

(2z)-2-methyl-5-[(1r,2s,3r,4r,6s)-2,3-dimethyltricyclo[2.2.1.0²,⁶]heptan-3-yl]pent-2-en-1-ol

C15H24O (220.1827)