NCBI Taxonomy: 877974

Paleo South American clade (ncbi_taxid: 877974)

found 9 associated metabolites at clade taxonomy rank level.

Ancestor: Astereae

Child Taxonomies: Ocyroe, Novenia, Llerasia, Haroldia, Katinasia, Cabreraea, Oritrophium, Aylacophora, Nardophyllum, Chiliophyllum, Lepidophyllum, Chiliotrichum, Chiliotrichiopsis

Caryophyllene oxide

Caryophyllene alpha-oxide

C15H24O (220.18270539999997)


Constituent of oil of cloves (Eugenia caryophyllata)and is) also in oils of Betula alba, Mentha piperita (peppermint) and others. Caryophyllene alpha-oxide is found in many foods, some of which are spearmint, cloves, ceylon cinnamon, and herbs and spices. Caryophyllene beta-oxide is a member of the class of compounds known as sesquiterpenoids. Sesquiterpenoids are terpenes with three consecutive isoprene units. Caryophyllene beta-oxide is practically insoluble (in water) and an extremely weak basic (essentially neutral) compound (based on its pKa). Within the cell, caryophyllene beta-oxide is primarily located in the membrane (predicted from logP). It can also be found in the extracellular space. Caryophyllene oxide, isolated from from Hymenaea courbaril, possesses analgesic and anti-inflammatory activity[1]. Caryophyllene oxide, isolated from from Hymenaea courbaril, possesses analgesic and anti-inflammatory activity[1].

   

(1s,2s,4as,5s,5'r,6s,8as)-5'-(furan-3-yl)-5,6-dihydroxy-2,4a,5-trimethyl-hexahydrospiro[naphthalene-1,3'-oxolane]-2',3-dione

(1s,2s,4as,5s,5'r,6s,8as)-5'-(furan-3-yl)-5,6-dihydroxy-2,4a,5-trimethyl-hexahydrospiro[naphthalene-1,3'-oxolane]-2',3-dione

C20H26O6 (362.17292960000003)


   

6-[(acetyloxy)methyl]-2-(5-hydroxy-4-methylpent-3-en-1-yl)-9-(5-oxo-2h-furan-3-yl)nona-2,6-dienoic acid

6-[(acetyloxy)methyl]-2-(5-hydroxy-4-methylpent-3-en-1-yl)-9-(5-oxo-2h-furan-3-yl)nona-2,6-dienoic acid

C22H30O7 (406.199143)


   
   

(1s,3as,3br,7s,9ar,9br,11ar)-3a,3b,6,6,9a-pentamethyl-1-(6-methylhepta-1,5-dien-2-yl)-dodecahydro-1h-cyclopenta[a]phenanthren-7-yl acetate

(1s,3as,3br,7s,9ar,9br,11ar)-3a,3b,6,6,9a-pentamethyl-1-(6-methylhepta-1,5-dien-2-yl)-dodecahydro-1h-cyclopenta[a]phenanthren-7-yl acetate

C32H52O2 (468.3967092)


   

5'-(furan-3-yl)-5,6-dihydroxy-2,4a,5-trimethyl-hexahydrospiro[naphthalene-1,3'-oxolane]-2',3-dione

5'-(furan-3-yl)-5,6-dihydroxy-2,4a,5-trimethyl-hexahydrospiro[naphthalene-1,3'-oxolane]-2',3-dione

C20H26O6 (362.17292960000003)


   

(1ar,3as,4s,5s,5's,7as,7bs)-5'-(furan-3-yl)-5,7a,7b-trimethyl-hexahydrospiro[naphtho[1,2-b]oxirene-4,3'-oxolane]-2',6-dione

(1ar,3as,4s,5s,5's,7as,7bs)-5'-(furan-3-yl)-5,7a,7b-trimethyl-hexahydrospiro[naphtho[1,2-b]oxirene-4,3'-oxolane]-2',6-dione

C20H24O5 (344.1623654)


   

(2z,6z)-6-[(acetyloxy)methyl]-2-[(3z)-5-hydroxy-4-methylpent-3-en-1-yl]-9-(5-oxo-2h-furan-3-yl)nona-2,6-dienoic acid

(2z,6z)-6-[(acetyloxy)methyl]-2-[(3z)-5-hydroxy-4-methylpent-3-en-1-yl]-9-(5-oxo-2h-furan-3-yl)nona-2,6-dienoic acid

C22H30O7 (406.199143)


   

5'-(furan-3-yl)-5,7a,7b-trimethyl-hexahydrospiro[naphtho[1,2-b]oxirene-4,3'-oxolane]-2',6-dione

5'-(furan-3-yl)-5,7a,7b-trimethyl-hexahydrospiro[naphtho[1,2-b]oxirene-4,3'-oxolane]-2',6-dione

C20H24O5 (344.1623654)