Chrysobactin

Chrysobactin

C16H23N3O7 (369.1535928)


A catechol-type siderophore with a structure of D-lysyl-L-serine substituted on N(2) of the lysyl residue by a 2,3-dihydroxybenzoyl group. It is produced by the Gram-negative bacillus Dickeya dadantii (previously known as Erwinia chrysanthem). Only the catecholate hydroxyl groups participate in metal coordination, so chrysobactin cannot provide full 1:1 coordination of Fe(III); at neutral pH and concentrations of about 0.1 mM, ferric chrysobactin exists as a mixture of bis and tris complexes.

   

(2s)-2-{[(2r)-6-amino-2-{[(2,3-dihydroxyphenyl)(hydroxy)methylidene]amino}-1-hydroxyhexylidene]amino}-3-{[(2s)-2-{[(2r)-6-amino-2-{[(2,3-dihydroxyphenyl)(hydroxy)methylidene]amino}-1-hydroxyhexylidene]amino}-3-hydroxypropanoyl]oxy}propanoic acid

(2s)-2-{[(2r)-6-amino-2-{[(2,3-dihydroxyphenyl)(hydroxy)methylidene]amino}-1-hydroxyhexylidene]amino}-3-{[(2s)-2-{[(2r)-6-amino-2-{[(2,3-dihydroxyphenyl)(hydroxy)methylidene]amino}-1-hydroxyhexylidene]amino}-3-hydroxypropanoyl]oxy}propanoic acid

C32H44N6O13 (720.2966214)


   

1-{1-carboxy-3-[(3-carboxy-3-{2-[2-(2-carboxy-2-hydroxy-5-oxopyrrolidin-1-yl)ethoxy]-2-oxoethyl}-1,3-dihydroxypropylidene)amino]propyl}-2-hydroxy-5-oxopyrrolidine-2-carboxylic acid

1-{1-carboxy-3-[(3-carboxy-3-{2-[2-(2-carboxy-2-hydroxy-5-oxopyrrolidin-1-yl)ethoxy]-2-oxoethyl}-1,3-dihydroxypropylidene)amino]propyl}-2-hydroxy-5-oxopyrrolidine-2-carboxylic acid

C22H29N3O16 (591.1547754000001)


   

6-amino-3,5-dihydroxy-7-methyl-n-(11,19,27,35-tetraamino-3-hydroxytetracontyl)octanimidic acid

6-amino-3,5-dihydroxy-7-methyl-n-(11,19,27,35-tetraamino-3-hydroxytetracontyl)octanimidic acid

C49H104N6O4 (840.8118624)


   

(2r)-6-amino-n-[(3s,7s,11s)-7,11-bis({[(2r)-6-amino-2-{[(2,3-dihydroxyphenyl)(hydroxy)methylidene]amino}-1-hydroxyhexylidene]amino})-2,6,10-trioxo-1,5,9-trioxacyclododecan-3-yl]-2-{[(2,3-dihydroxyphenyl)(hydroxy)methylidene]amino}hexanimidic acid

(2r)-6-amino-n-[(3s,7s,11s)-7,11-bis({[(2r)-6-amino-2-{[(2,3-dihydroxyphenyl)(hydroxy)methylidene]amino}-1-hydroxyhexylidene]amino})-2,6,10-trioxo-1,5,9-trioxacyclododecan-3-yl]-2-{[(2,3-dihydroxyphenyl)(hydroxy)methylidene]amino}hexanimidic acid

C48H63N9O18 (1053.4290858)


   

2-[(6-amino-2-{[(2,3-dihydroxyphenyl)(hydroxy)methylidene]amino}-1-hydroxyhexylidene)amino]-3-hydroxypropanoic acid

2-[(6-amino-2-{[(2,3-dihydroxyphenyl)(hydroxy)methylidene]amino}-1-hydroxyhexylidene)amino]-3-hydroxypropanoic acid

C16H23N3O7 (369.1535928)


   

(2s)-2-{[(2r)-6-amino-2-{[(2,3-dihydroxyphenyl)(hydroxy)methylidene]amino}-1-hydroxyhexylidene]amino}-3-{[(2s)-2-{[(2r)-6-amino-2-{[(2,3-dihydroxyphenyl)(hydroxy)methylidene]amino}-1-hydroxyhexylidene]amino}-3-{[(2s)-2-{[(2r)-6-amino-2-{[(2,3-dihydroxyphenyl)(hydroxy)methylidene]amino}-1-hydroxyhexylidene]amino}-3-hydroxypropanoyl]oxy}propanoyl]oxy}propanoic acid

(2s)-2-{[(2r)-6-amino-2-{[(2,3-dihydroxyphenyl)(hydroxy)methylidene]amino}-1-hydroxyhexylidene]amino}-3-{[(2s)-2-{[(2r)-6-amino-2-{[(2,3-dihydroxyphenyl)(hydroxy)methylidene]amino}-1-hydroxyhexylidene]amino}-3-{[(2s)-2-{[(2r)-6-amino-2-{[(2,3-dihydroxyphenyl)(hydroxy)methylidene]amino}-1-hydroxyhexylidene]amino}-3-hydroxypropanoyl]oxy}propanoyl]oxy}propanoic acid

C48H65N9O19 (1071.43965)


   

(2s)-2-{[(2r)-6-amino-2-{[(2,3-dihydroxyphenyl)(hydroxy)methylidene]amino}-1-hydroxyhexylidene]amino}-3-hydroxypropanoic acid

(2s)-2-{[(2r)-6-amino-2-{[(2,3-dihydroxyphenyl)(hydroxy)methylidene]amino}-1-hydroxyhexylidene]amino}-3-hydroxypropanoic acid

C16H23N3O7 (369.1535928)


   

1,11,19,27,35-pentaaminotetracontan-3-ol

1,11,19,27,35-pentaaminotetracontan-3-ol

C40H87N5O (653.6910251999999)


   

2-[(6-amino-2-{[(2,3-dihydroxyphenyl)(hydroxy)methylidene]amino}-1-hydroxyhexylidene)amino]-3-({2-[(6-amino-2-{[(2,3-dihydroxyphenyl)(hydroxy)methylidene]amino}-1-hydroxyhexylidene)amino]-3-hydroxypropanoyl}oxy)propanoic acid

2-[(6-amino-2-{[(2,3-dihydroxyphenyl)(hydroxy)methylidene]amino}-1-hydroxyhexylidene)amino]-3-({2-[(6-amino-2-{[(2,3-dihydroxyphenyl)(hydroxy)methylidene]amino}-1-hydroxyhexylidene)amino]-3-hydroxypropanoyl}oxy)propanoic acid

C32H44N6O13 (720.2966214)


   

(3r,5s,6r)-6-amino-3,5-dihydroxy-7-methyl-n-[(3s,11s,19s,27s,35s)-11,19,27,35-tetraamino-3-hydroxytetracontyl]octanimidic acid

(3r,5s,6r)-6-amino-3,5-dihydroxy-7-methyl-n-[(3s,11s,19s,27s,35s)-11,19,27,35-tetraamino-3-hydroxytetracontyl]octanimidic acid

C49H104N6O4 (840.8118624)


   

6-amino-n-{7,11-bis[(6-amino-2-{[(2,3-dihydroxyphenyl)(hydroxy)methylidene]amino}-1-hydroxyhexylidene)amino]-2,6,10-trioxo-1,5,9-trioxacyclododecan-3-yl}-2-{[(2,3-dihydroxyphenyl)(hydroxy)methylidene]amino}hexanimidic acid

6-amino-n-{7,11-bis[(6-amino-2-{[(2,3-dihydroxyphenyl)(hydroxy)methylidene]amino}-1-hydroxyhexylidene)amino]-2,6,10-trioxo-1,5,9-trioxacyclododecan-3-yl}-2-{[(2,3-dihydroxyphenyl)(hydroxy)methylidene]amino}hexanimidic acid

C48H63N9O18 (1053.4290858)


   

2-[(6-amino-2-{[(2,3-dihydroxyphenyl)(hydroxy)methylidene]amino}-1-hydroxyhexylidene)amino]-3-({2-[(6-amino-2-{[(2,3-dihydroxyphenyl)(hydroxy)methylidene]amino}-1-hydroxyhexylidene)amino]-3-({2-[(6-amino-2-{[(2,3-dihydroxyphenyl)(hydroxy)methylidene]amino}-1-hydroxyhexylidene)amino]-3-hydroxypropanoyl}oxy)propanoyl}oxy)propanoic acid

2-[(6-amino-2-{[(2,3-dihydroxyphenyl)(hydroxy)methylidene]amino}-1-hydroxyhexylidene)amino]-3-({2-[(6-amino-2-{[(2,3-dihydroxyphenyl)(hydroxy)methylidene]amino}-1-hydroxyhexylidene)amino]-3-({2-[(6-amino-2-{[(2,3-dihydroxyphenyl)(hydroxy)methylidene]amino}-1-hydroxyhexylidene)amino]-3-hydroxypropanoyl}oxy)propanoyl}oxy)propanoic acid

C48H65N9O19 (1071.43965)