NCBI Taxonomy: 125668

Calocephalus (ncbi_taxid: 125668)

found 33 associated metabolites at genus taxonomy rank level.

Ancestor: Gnaphalieae

Child Taxonomies: Calocephalus sonderi, Calocephalus beardii, Calocephalus knappii, Calocephalus francisii, Calocephalus pilbarensis, Calocephalus multiflorus, Calocephalus platycephalus

Pseudoivalin

[3aR-(3aalpha,4aalpha,5alpha,9abeta)]-3a,4,4a,5,6,7,9,9a-Octahydro-5-hydroxy-5,8-dimethyl-3-methylene-azuleno[6,5-b]furan-2(3H)-one

C15H20O3 (248.14123700000002)


   

Candol B

[(1S,4S,5S,9S,10R,13R)-5,9-dimethyl-14-methylidenetetracyclo[11.2.1.0^{1,10}.0^{4,9}]hexadecan-5-yl]methanol

C20H32O (288.24530219999997)


Candol B, also known as 4beta-kaur-16-en-19-ol, belongs to the class of organic compounds known as kaurane diterpenoids. These are diterpene alkaloids with a structure that is based on the kaurane skeleton. Kaurane is a tetracyclic compound that arises by the cyclization of a pimarane precursor followed by rearrangement. It possesses a [3,2,1]-bicyclic ring system with C15-C16 bridge connected to C13, forming the five-membered ring D. Candol B is an extremely weak basic (essentially neutral) compound (based on its pKa). Candol B is found in cereals and cereal products. Candol B is a constituent of barley. Constituent of barley. Candol B is found in cereals and cereal products.

   

ent-Kaur-16-en-19-oic acid

ent-Kaur-16-en-19-oic acid

C20H30O2 (302.224568)


   

1,3-bis{[(1r,4s,5r,9s,10s,13s)-5,9,13-trimethyltetracyclo[11.2.1.0¹,¹⁰.0⁴,⁹]hexadec-14-en-5-yl]methyl} propanedioate

1,3-bis{[(1r,4s,5r,9s,10s,13s)-5,9,13-trimethyltetracyclo[11.2.1.0¹,¹⁰.0⁴,⁹]hexadec-14-en-5-yl]methyl} propanedioate

C43H64O4 (644.4804343999999)


   

[(1s,4s,5s,9s,10r,13r)-5,9-dimethyl-14-methylidenetetracyclo[11.2.1.0¹,¹⁰.0⁴,⁹]hexadecan-5-yl]methanol

[(1s,4s,5s,9s,10r,13r)-5,9-dimethyl-14-methylidenetetracyclo[11.2.1.0¹,¹⁰.0⁴,⁹]hexadecan-5-yl]methanol

C20H32O (288.24530219999997)


   

{5,9-dimethyl-14-methylidenetetracyclo[11.2.1.0¹,¹⁰.0⁴,⁹]hexadecan-5-yl}methanol

{5,9-dimethyl-14-methylidenetetracyclo[11.2.1.0¹,¹⁰.0⁴,⁹]hexadecan-5-yl}methanol

C20H32O (288.24530219999997)


   

(1s,3r,7s,9s,10r,12r,14s)-9,14-dimethyl-4-methylidene-5-oxo-6,13-dioxatetracyclo[8.4.0.0³,⁷.0¹²,¹⁴]tetradecan-10-yl acetate

(1s,3r,7s,9s,10r,12r,14s)-9,14-dimethyl-4-methylidene-5-oxo-6,13-dioxatetracyclo[8.4.0.0³,⁷.0¹²,¹⁴]tetradecan-10-yl acetate

C17H22O5 (306.1467162)


   

[(1s,4s,5r,9s,10r,13r)-5,9-dimethyl-14-methylidenetetracyclo[11.2.1.0¹,¹⁰.0⁴,⁹]hexadecan-5-yl]methanol

[(1s,4s,5r,9s,10r,13r)-5,9-dimethyl-14-methylidenetetracyclo[11.2.1.0¹,¹⁰.0⁴,⁹]hexadecan-5-yl]methanol

C20H32O (288.24530219999997)


   

5-hydroxy-5,8-dimethyl-3-methylidene-3ah,4h,4ah,6h,7h,9h,9ah-azuleno[6,5-b]furan-2-one

5-hydroxy-5,8-dimethyl-3-methylidene-3ah,4h,4ah,6h,7h,9h,9ah-azuleno[6,5-b]furan-2-one

C15H20O3 (248.14123700000002)


   

3-{[(1s,4s,5r,9s,10r,13r)-5,9-dimethyl-14-methylidenetetracyclo[11.2.1.0¹,¹⁰.0⁴,⁹]hexadecan-5-yl]methoxy}-3-oxopropanoic acid

3-{[(1s,4s,5r,9s,10r,13r)-5,9-dimethyl-14-methylidenetetracyclo[11.2.1.0¹,¹⁰.0⁴,⁹]hexadecan-5-yl]methoxy}-3-oxopropanoic acid

C23H34O4 (374.24569640000004)


   

5,8-dimethyl-3-methylidene-2-oxo-3ah,4h,4ah,6h,7h,9h,9ah-azuleno[6,5-b]furan-5-yl acetate

5,8-dimethyl-3-methylidene-2-oxo-3ah,4h,4ah,6h,7h,9h,9ah-azuleno[6,5-b]furan-5-yl acetate

C17H22O4 (290.1518012)


   

(1r,3s,7s,9r,10r,12s,14r)-9,14-dimethyl-4-methylidene-5-oxo-6,13-dioxatetracyclo[8.4.0.0³,⁷.0¹²,¹⁴]tetradecan-10-yl acetate

(1r,3s,7s,9r,10r,12s,14r)-9,14-dimethyl-4-methylidene-5-oxo-6,13-dioxatetracyclo[8.4.0.0³,⁷.0¹²,¹⁴]tetradecan-10-yl acetate

C17H22O5 (306.1467162)


   

(5r,9s,13s)-5,9-dimethyl-14-methylidenetetracyclo[11.2.1.0¹,¹⁰.0⁴,⁹]hexadecane-5-carboxylic acid

(5r,9s,13s)-5,9-dimethyl-14-methylidenetetracyclo[11.2.1.0¹,¹⁰.0⁴,⁹]hexadecane-5-carboxylic acid

C20H30O2 (302.224568)


   

(3ar,4ar,5r,9ar)-5,8-dimethyl-3-methylidene-2-oxo-3ah,4h,4ah,6h,7h,9h,9ah-azuleno[6,5-b]furan-5-yl acetate

(3ar,4ar,5r,9ar)-5,8-dimethyl-3-methylidene-2-oxo-3ah,4h,4ah,6h,7h,9h,9ah-azuleno[6,5-b]furan-5-yl acetate

C17H22O4 (290.1518012)


   

9,14-dimethyl-4-methylidene-5-oxo-6,13-dioxatetracyclo[8.4.0.0³,⁷.0¹²,¹⁴]tetradecan-10-yl acetate

9,14-dimethyl-4-methylidene-5-oxo-6,13-dioxatetracyclo[8.4.0.0³,⁷.0¹²,¹⁴]tetradecan-10-yl acetate

C17H22O5 (306.1467162)


   

3-({5,9-dimethyl-14-methylidenetetracyclo[11.2.1.0¹,¹⁰.0⁴,⁹]hexadecan-5-yl}methoxy)-3-oxopropanoic acid

3-({5,9-dimethyl-14-methylidenetetracyclo[11.2.1.0¹,¹⁰.0⁴,⁹]hexadecan-5-yl}methoxy)-3-oxopropanoic acid

C23H34O4 (374.24569640000004)