Chemical Formula: C53H85ClN14O17
Chemical Formula C53H85ClN14O17
Found 12 metabolite its formula value is C53H85ClN14O17
Syringomycin
(2S)-2-[(3S,6S,12S,15S,18S,21R,24R,27S)-18,21-bis(2-aminoethyl)-12-benzyl-15-(3-carbamimidamidopropyl)-3-[(1S)-2-chloro-1-hydroxyethyl]-27-{[(3S)-1,3-dihydroxydodecylidene]amino}-9-ethylidene-5,8,11,14,17,20,23,26-octahydroxy-24-(hydroxymethyl)-2-oxo-1-oxa-4,7,10,13,16,19,22,25-octaazacyclooctacosa-4,7,10,13,16,19,22,25-octaen-6-yl]-2-hydroxyacetic acid
Production by a sugar cane isolate of Pseudomonas syringae pv. syringae. Syringomycin is a general name given to a class of lipodepsinonapeptide molecules which are secreted by the plant pathogen Pseudomonas syringae. Lipodepsinonapeptides comprise a closed ring of nine nonribosomally-synthesized amino acids bonded to a fatty acid hydrocarbon tail. A commonly-encountered pathovar (pv) of P. syringae is P. syringae pv syringae which secretes a number of closely-related forms of the molecule. Syringomycins are virulence determinants which means that their secretion is required for the manifestation of disease symptoms on a number of stone fruit crop plants.
Syringomycin E
Syringomycin E
A member of the class of syringomycins that has 3-hydroxydodecanoyl as the fatty acyl tail group. It is isolated from Pseudomonas syringae pv. syringae and exhibits phytotoxic and antifungal properties.
(2S)-[(3S,6S,9Z,12S,15S,18R,21S,24R,27S)-18,21-bis(2-aminoethyl)-12-benzyl-15-(3-carbamimidamidopropyl)-3-[(1S)-2-chloro-1-hydroxyethyl]-9-ethylidene-27-{[(3R)-3-hydroxydodecanoyl]amino}-24-(hydroxymethyl)-2,5,8,11,14,17,20,23,26-nonaoxo-1-oxa-4,7,10,13,16,19,22,25-octaazacyclooctacosan-6-yl](hydroxy)acetic acid
(2S)-[(3S,6S,9Z,12S,15S,18R,21S,24R,27S)-18,21-bis(2-aminoethyl)-12-benzyl-15-(3-carbamimidamidopropyl)-3-[(1S)-2-chloro-1-hydroxyethyl]-9-ethylidene-27-{[(3R)-3-hydroxydodecanoyl]amino}-24-(hydroxymethyl)-2,5,8,11,14,17,20,23,26-nonaoxo-1-oxa-4,7,10,13,16,19,22,25-octaazacyclooctacosan-6-yl](hydroxy)acetic acid
Unk-Ser(1)-Ser-Dab-Dab-Arg-Phe-Nva(2,3-dehydro)-D-Asp(3S-OH)-Thr(4-Cl)-(1)
Unk-Ser(1)-Ser-Dab-Dab-Arg-Phe-Nva(2,3-dehydro)-D-Asp(3S-OH)-Thr(4-Cl)-(1)
(r)-[(3r,6r,9z,12r,15r,18s,21r,24s,27r)-18,21-bis(2-aminoethyl)-12-benzyl-15-(3-carbamimidamidopropyl)-3-[(1s)-2-chloro-1-hydroxyethyl]-27-{[(3s)-1,3-dihydroxydodecylidene]amino}-9-ethylidene-5,8,11,14,17,20,23,26-octahydroxy-24-(hydroxymethyl)-2-oxo-1-oxa-4,7,10,13,16,19,22,25-octaazacyclooctacosa-4,7,10,13,16,19,22,25-octaen-6-yl](hydroxy)acetic acid
(r)-[(3r,6r,9z,12r,15r,18s,21r,24s,27r)-18,21-bis(2-aminoethyl)-12-benzyl-15-(3-carbamimidamidopropyl)-3-[(1s)-2-chloro-1-hydroxyethyl]-27-{[(3s)-1,3-dihydroxydodecylidene]amino}-9-ethylidene-5,8,11,14,17,20,23,26-octahydroxy-24-(hydroxymethyl)-2-oxo-1-oxa-4,7,10,13,16,19,22,25-octaazacyclooctacosa-4,7,10,13,16,19,22,25-octaen-6-yl](hydroxy)acetic acid
(s)-[(3s,6r,9z,12s,15s,18s,21s,24s,27s)-18,21-bis(2-aminoethyl)-12-benzyl-15-(3-carbamimidamidopropyl)-3-[(1s)-2-chloro-1-hydroxyethyl]-27-[(1,3-dihydroxyundecylidene)amino]-5,8,11,14,17,20,23,26-octahydroxy-24-(hydroxymethyl)-2-oxo-9-propylidene-1-oxa-4,7,10,13,16,19,22,25-octaazacyclooctacosa-4,7,10,13,16,19,22,25-octaen-6-yl](hydroxy)acetic acid
(s)-[(3s,6r,9z,12s,15s,18s,21s,24s,27s)-18,21-bis(2-aminoethyl)-12-benzyl-15-(3-carbamimidamidopropyl)-3-[(1s)-2-chloro-1-hydroxyethyl]-27-[(1,3-dihydroxyundecylidene)amino]-5,8,11,14,17,20,23,26-octahydroxy-24-(hydroxymethyl)-2-oxo-9-propylidene-1-oxa-4,7,10,13,16,19,22,25-octaazacyclooctacosa-4,7,10,13,16,19,22,25-octaen-6-yl](hydroxy)acetic acid
[(9z)-18,21-bis(2-aminoethyl)-12-benzyl-15-(3-carbamimidamidopropyl)-3-(2-chloro-1-hydroxyethyl)-27-[(1,3-dihydroxyundecylidene)amino]-5,8,11,14,17,20,23,26-octahydroxy-24-(hydroxymethyl)-2-oxo-9-propylidene-1-oxa-4,7,10,13,16,19,22,25-octaazacyclooctacosa-4,7,10,13,16,19,22,25-octaen-6-yl](hydroxy)acetic acid
[(9z)-18,21-bis(2-aminoethyl)-12-benzyl-15-(3-carbamimidamidopropyl)-3-(2-chloro-1-hydroxyethyl)-27-[(1,3-dihydroxyundecylidene)amino]-5,8,11,14,17,20,23,26-octahydroxy-24-(hydroxymethyl)-2-oxo-9-propylidene-1-oxa-4,7,10,13,16,19,22,25-octaazacyclooctacosa-4,7,10,13,16,19,22,25-octaen-6-yl](hydroxy)acetic acid
[18,21-bis(2-aminoethyl)-12-benzyl-15-(3-carbamimidamidopropyl)-3-(2-chloro-1-hydroxyethyl)-27-[(1,3-dihydroxydodecylidene)amino]-9-ethylidene-5,8,11,14,17,20,23,26-octahydroxy-24-(hydroxymethyl)-2-oxo-1-oxa-4,7,10,13,16,19,22,25-octaazacyclooctacosa-4,7,10,13,16,19,22,25-octaen-6-yl](hydroxy)acetic acid
[18,21-bis(2-aminoethyl)-12-benzyl-15-(3-carbamimidamidopropyl)-3-(2-chloro-1-hydroxyethyl)-27-[(1,3-dihydroxydodecylidene)amino]-9-ethylidene-5,8,11,14,17,20,23,26-octahydroxy-24-(hydroxymethyl)-2-oxo-1-oxa-4,7,10,13,16,19,22,25-octaazacyclooctacosa-4,7,10,13,16,19,22,25-octaen-6-yl](hydroxy)acetic acid
(s)-[(3s,6s,9z,12s,15s,18r,21s,24r,27s)-18,21-bis(2-aminoethyl)-12-benzyl-15-(3-carbamimidamidopropyl)-3-[(1s)-2-chloro-1-hydroxyethyl]-27-{[(3r)-1,3-dihydroxydodecylidene]amino}-9-ethylidene-5,8,11,14,17,20,23,26-octahydroxy-24-(hydroxymethyl)-2-oxo-1-oxa-4,7,10,13,16,19,22,25-octaazacyclooctacosa-4,7,10,13,16,19,22,25-octaen-6-yl](hydroxy)acetic acid
(s)-[(3s,6s,9z,12s,15s,18r,21s,24r,27s)-18,21-bis(2-aminoethyl)-12-benzyl-15-(3-carbamimidamidopropyl)-3-[(1s)-2-chloro-1-hydroxyethyl]-27-{[(3r)-1,3-dihydroxydodecylidene]amino}-9-ethylidene-5,8,11,14,17,20,23,26-octahydroxy-24-(hydroxymethyl)-2-oxo-1-oxa-4,7,10,13,16,19,22,25-octaazacyclooctacosa-4,7,10,13,16,19,22,25-octaen-6-yl](hydroxy)acetic acid
(s)-[(3s,6s,9z,12s,15s,18s,21r,24r,27s)-18,21-bis(2-aminoethyl)-12-benzyl-15-(3-carbamimidamidopropyl)-3-[(1s)-2-chloro-1-hydroxyethyl]-27-{[(3s)-1,3-dihydroxydodecylidene]amino}-9-ethylidene-5,8,11,14,17,20,23,26-octahydroxy-24-(hydroxymethyl)-2-oxo-1-oxa-4,7,10,13,16,19,22,25-octaazacyclooctacosa-4,7,10,13,16,19,22,25-octaen-6-yl](hydroxy)acetic acid
(s)-[(3s,6s,9z,12s,15s,18s,21r,24r,27s)-18,21-bis(2-aminoethyl)-12-benzyl-15-(3-carbamimidamidopropyl)-3-[(1s)-2-chloro-1-hydroxyethyl]-27-{[(3s)-1,3-dihydroxydodecylidene]amino}-9-ethylidene-5,8,11,14,17,20,23,26-octahydroxy-24-(hydroxymethyl)-2-oxo-1-oxa-4,7,10,13,16,19,22,25-octaazacyclooctacosa-4,7,10,13,16,19,22,25-octaen-6-yl](hydroxy)acetic acid