Exact Mass: 1224.590535
Exact Mass Matches: 1224.590535
Found 12 metabolites which its exact mass value is equals to given mass value 1224.590535,
within given mass tolerance error 0.0002 dalton. Try search metabolite list with more accurate mass tolerance error
4.0E-5 dalton.
Syringomycin
(2S)-2-[(3S,6S,12S,15S,18S,21R,24R,27S)-18,21-bis(2-aminoethyl)-12-benzyl-15-(3-carbamimidamidopropyl)-3-[(1S)-2-chloro-1-hydroxyethyl]-27-{[(3S)-1,3-dihydroxydodecylidene]amino}-9-ethylidene-5,8,11,14,17,20,23,26-octahydroxy-24-(hydroxymethyl)-2-oxo-1-oxa-4,7,10,13,16,19,22,25-octaazacyclooctacosa-4,7,10,13,16,19,22,25-octaen-6-yl]-2-hydroxyacetic acid
Production by a sugar cane isolate of Pseudomonas syringae pv. syringae. Syringomycin is a general name given to a class of lipodepsinonapeptide molecules which are secreted by the plant pathogen Pseudomonas syringae. Lipodepsinonapeptides comprise a closed ring of nine nonribosomally-synthesized amino acids bonded to a fatty acid hydrocarbon tail. A commonly-encountered pathovar (pv) of P. syringae is P. syringae pv syringae which secretes a number of closely-related forms of the molecule. Syringomycins are virulence determinants which means that their secretion is required for the manifestation of disease symptoms on a number of stone fruit crop plants.
Syringomycin E
Syringomycin E
A member of the class of syringomycins that has 3-hydroxydodecanoyl as the fatty acyl tail group. It is isolated from Pseudomonas syringae pv. syringae and exhibits phytotoxic and antifungal properties.
(2S)-[(3S,6S,9Z,12S,15S,18R,21S,24R,27S)-18,21-bis(2-aminoethyl)-12-benzyl-15-(3-carbamimidamidopropyl)-3-[(1S)-2-chloro-1-hydroxyethyl]-9-ethylidene-27-{[(3R)-3-hydroxydodecanoyl]amino}-24-(hydroxymethyl)-2,5,8,11,14,17,20,23,26-nonaoxo-1-oxa-4,7,10,13,16,19,22,25-octaazacyclooctacosan-6-yl](hydroxy)acetic acid
(2S)-[(3S,6S,9Z,12S,15S,18R,21S,24R,27S)-18,21-bis(2-aminoethyl)-12-benzyl-15-(3-carbamimidamidopropyl)-3-[(1S)-2-chloro-1-hydroxyethyl]-9-ethylidene-27-{[(3R)-3-hydroxydodecanoyl]amino}-24-(hydroxymethyl)-2,5,8,11,14,17,20,23,26-nonaoxo-1-oxa-4,7,10,13,16,19,22,25-octaazacyclooctacosan-6-yl](hydroxy)acetic acid
Unk-Ser(1)-Ser-Dab-Dab-Arg-Phe-Nva(2,3-dehydro)-D-Asp(3S-OH)-Thr(4-Cl)-(1)
Unk-Ser(1)-Ser-Dab-Dab-Arg-Phe-Nva(2,3-dehydro)-D-Asp(3S-OH)-Thr(4-Cl)-(1)
(r)-[(3r,6r,9z,12r,15r,18s,21r,24s,27r)-18,21-bis(2-aminoethyl)-12-benzyl-15-(3-carbamimidamidopropyl)-3-[(1s)-2-chloro-1-hydroxyethyl]-27-{[(3s)-1,3-dihydroxydodecylidene]amino}-9-ethylidene-5,8,11,14,17,20,23,26-octahydroxy-24-(hydroxymethyl)-2-oxo-1-oxa-4,7,10,13,16,19,22,25-octaazacyclooctacosa-4,7,10,13,16,19,22,25-octaen-6-yl](hydroxy)acetic acid
(r)-[(3r,6r,9z,12r,15r,18s,21r,24s,27r)-18,21-bis(2-aminoethyl)-12-benzyl-15-(3-carbamimidamidopropyl)-3-[(1s)-2-chloro-1-hydroxyethyl]-27-{[(3s)-1,3-dihydroxydodecylidene]amino}-9-ethylidene-5,8,11,14,17,20,23,26-octahydroxy-24-(hydroxymethyl)-2-oxo-1-oxa-4,7,10,13,16,19,22,25-octaazacyclooctacosa-4,7,10,13,16,19,22,25-octaen-6-yl](hydroxy)acetic acid
(s)-[(3s,6r,9z,12s,15s,18s,21s,24s,27s)-18,21-bis(2-aminoethyl)-12-benzyl-15-(3-carbamimidamidopropyl)-3-[(1s)-2-chloro-1-hydroxyethyl]-27-[(1,3-dihydroxyundecylidene)amino]-5,8,11,14,17,20,23,26-octahydroxy-24-(hydroxymethyl)-2-oxo-9-propylidene-1-oxa-4,7,10,13,16,19,22,25-octaazacyclooctacosa-4,7,10,13,16,19,22,25-octaen-6-yl](hydroxy)acetic acid
(s)-[(3s,6r,9z,12s,15s,18s,21s,24s,27s)-18,21-bis(2-aminoethyl)-12-benzyl-15-(3-carbamimidamidopropyl)-3-[(1s)-2-chloro-1-hydroxyethyl]-27-[(1,3-dihydroxyundecylidene)amino]-5,8,11,14,17,20,23,26-octahydroxy-24-(hydroxymethyl)-2-oxo-9-propylidene-1-oxa-4,7,10,13,16,19,22,25-octaazacyclooctacosa-4,7,10,13,16,19,22,25-octaen-6-yl](hydroxy)acetic acid
[(9z)-18,21-bis(2-aminoethyl)-12-benzyl-15-(3-carbamimidamidopropyl)-3-(2-chloro-1-hydroxyethyl)-27-[(1,3-dihydroxyundecylidene)amino]-5,8,11,14,17,20,23,26-octahydroxy-24-(hydroxymethyl)-2-oxo-9-propylidene-1-oxa-4,7,10,13,16,19,22,25-octaazacyclooctacosa-4,7,10,13,16,19,22,25-octaen-6-yl](hydroxy)acetic acid
[(9z)-18,21-bis(2-aminoethyl)-12-benzyl-15-(3-carbamimidamidopropyl)-3-(2-chloro-1-hydroxyethyl)-27-[(1,3-dihydroxyundecylidene)amino]-5,8,11,14,17,20,23,26-octahydroxy-24-(hydroxymethyl)-2-oxo-9-propylidene-1-oxa-4,7,10,13,16,19,22,25-octaazacyclooctacosa-4,7,10,13,16,19,22,25-octaen-6-yl](hydroxy)acetic acid
[18,21-bis(2-aminoethyl)-12-benzyl-15-(3-carbamimidamidopropyl)-3-(2-chloro-1-hydroxyethyl)-27-[(1,3-dihydroxydodecylidene)amino]-9-ethylidene-5,8,11,14,17,20,23,26-octahydroxy-24-(hydroxymethyl)-2-oxo-1-oxa-4,7,10,13,16,19,22,25-octaazacyclooctacosa-4,7,10,13,16,19,22,25-octaen-6-yl](hydroxy)acetic acid
[18,21-bis(2-aminoethyl)-12-benzyl-15-(3-carbamimidamidopropyl)-3-(2-chloro-1-hydroxyethyl)-27-[(1,3-dihydroxydodecylidene)amino]-9-ethylidene-5,8,11,14,17,20,23,26-octahydroxy-24-(hydroxymethyl)-2-oxo-1-oxa-4,7,10,13,16,19,22,25-octaazacyclooctacosa-4,7,10,13,16,19,22,25-octaen-6-yl](hydroxy)acetic acid
(s)-[(3s,6s,9z,12s,15s,18r,21s,24r,27s)-18,21-bis(2-aminoethyl)-12-benzyl-15-(3-carbamimidamidopropyl)-3-[(1s)-2-chloro-1-hydroxyethyl]-27-{[(3r)-1,3-dihydroxydodecylidene]amino}-9-ethylidene-5,8,11,14,17,20,23,26-octahydroxy-24-(hydroxymethyl)-2-oxo-1-oxa-4,7,10,13,16,19,22,25-octaazacyclooctacosa-4,7,10,13,16,19,22,25-octaen-6-yl](hydroxy)acetic acid
(s)-[(3s,6s,9z,12s,15s,18r,21s,24r,27s)-18,21-bis(2-aminoethyl)-12-benzyl-15-(3-carbamimidamidopropyl)-3-[(1s)-2-chloro-1-hydroxyethyl]-27-{[(3r)-1,3-dihydroxydodecylidene]amino}-9-ethylidene-5,8,11,14,17,20,23,26-octahydroxy-24-(hydroxymethyl)-2-oxo-1-oxa-4,7,10,13,16,19,22,25-octaazacyclooctacosa-4,7,10,13,16,19,22,25-octaen-6-yl](hydroxy)acetic acid
(s)-[(3s,6s,9z,12s,15s,18s,21r,24r,27s)-18,21-bis(2-aminoethyl)-12-benzyl-15-(3-carbamimidamidopropyl)-3-[(1s)-2-chloro-1-hydroxyethyl]-27-{[(3s)-1,3-dihydroxydodecylidene]amino}-9-ethylidene-5,8,11,14,17,20,23,26-octahydroxy-24-(hydroxymethyl)-2-oxo-1-oxa-4,7,10,13,16,19,22,25-octaazacyclooctacosa-4,7,10,13,16,19,22,25-octaen-6-yl](hydroxy)acetic acid
(s)-[(3s,6s,9z,12s,15s,18s,21r,24r,27s)-18,21-bis(2-aminoethyl)-12-benzyl-15-(3-carbamimidamidopropyl)-3-[(1s)-2-chloro-1-hydroxyethyl]-27-{[(3s)-1,3-dihydroxydodecylidene]amino}-9-ethylidene-5,8,11,14,17,20,23,26-octahydroxy-24-(hydroxymethyl)-2-oxo-1-oxa-4,7,10,13,16,19,22,25-octaazacyclooctacosa-4,7,10,13,16,19,22,25-octaen-6-yl](hydroxy)acetic acid