Classification Term: 170951

Shionane triterpenoids (ontology term: ba3ebcb7e173160d08d90f3410d43f36)

found 13 associated metabolites at sub_class metabolite taxonomy ontology rank level.

Ancestor: Triterpenoids

Child Taxonomies: There is no child term of current ontology term.

Shionone

2(1H)-CHRYSENONE, HEXADECAHYDRO-1,4B,6A,8,10A,12A-HEXAMETHYL-8-(4-METHYL-3-PENTENYL)-, (1R-(1.ALPHA.,4A.BETA.,4B.ALPHA.,6A.BETA.,8.BETA.,10A.ALPHA.,10B.BETA.,12A.ALPHA.))-

C30H50O (426.386145)


Shionone is a tetracyclic triterpenoid that is perhydrochrysene which is substituted by methyl groups at positions 1, 4bbeta, 6aalpha, 8beta, 10abeta and 12a positions, by a 4-methylpent-3-enyl group at the 8alpha position, and with an oxo group at position 2. It is a tetracyclic triterpenoid and a cyclic terpene ketone. Shionone is a natural product found in Aster baccharoides, Aster poliothamnus, and other organisms with data available. Shionone is the major triterpenoid isolated from Aster tataricus, has anti-tussive, anti-inflammatory activities[1][2]. Shionone possesses a unique six-membered tetracyclic skeleton and 3-oxo-4-monomethyl structure[1]. Shionone is the major triterpenoid isolated from Aster tataricus, has anti-tussive, anti-inflammatory activities[1][2]. Shionone possesses a unique six-membered tetracyclic skeleton and 3-oxo-4-monomethyl structure[1].

   

1,4b,6a,8,10a,12a-hexamethyl-8-(4-methylpent-3-en-1-yl)-dodecahydro-1h-chrysen-2-ol

1,4b,6a,8,10a,12a-hexamethyl-8-(4-methylpent-3-en-1-yl)-dodecahydro-1h-chrysen-2-ol

C30H52O (428.4017942)


   

4,4a,6b,11,11,12b,14a-heptamethyl-1,2,4,5,6,6a,7,8,9,10,12,13,14,14b-tetradecahydropicen-3-one

4,4a,6b,11,11,12b,14a-heptamethyl-1,2,4,5,6,6a,7,8,9,10,12,13,14,14b-tetradecahydropicen-3-one

C29H46O (410.3548466)


   

(1r,4as,4br,6as,8r,10ar,10bs,12as)-1-hydroxy-1,4b,6a,8,10a,12a-hexamethyl-8-(4-methylpent-3-en-1-yl)-decahydro-3h-chrysen-2-one

(1r,4as,4br,6as,8r,10ar,10bs,12as)-1-hydroxy-1,4b,6a,8,10a,12a-hexamethyl-8-(4-methylpent-3-en-1-yl)-decahydro-3h-chrysen-2-one

C30H50O2 (442.38106)


   

(2r,3s,4s,5r,6r)-2-({[(2r,3r,4r)-3,4-dihydroxy-4-(hydroxymethyl)oxolan-2-yl]oxy}methyl)-6-{[(1r,2r,4s)-3,3-dimethylbicyclo[2.2.1]heptan-2-yl]methoxy}oxane-3,4,5-triol

(2r,3s,4s,5r,6r)-2-({[(2r,3r,4r)-3,4-dihydroxy-4-(hydroxymethyl)oxolan-2-yl]oxy}methyl)-6-{[(1r,2r,4s)-3,3-dimethylbicyclo[2.2.1]heptan-2-yl]methoxy}oxane-3,4,5-triol

C21H36O10 (448.2308356)


   

(4r,4as,6as,6br,12br,14as,14bs)-4,4a,6b,11,11,12b,14a-heptamethyl-1,2,4,5,6,6a,7,8,9,10,12,13,14,14b-tetradecahydropicen-3-one

(4r,4as,6as,6br,12br,14as,14bs)-4,4a,6b,11,11,12b,14a-heptamethyl-1,2,4,5,6,6a,7,8,9,10,12,13,14,14b-tetradecahydropicen-3-one

C29H46O (410.3548466)


   

(1r,2s,4as,4bs,6as,8r,10ar,10bs,12as)-1,4b,6a,8,10a,12a-hexamethyl-8-(4-methylpent-3-en-1-yl)-dodecahydro-1h-chrysen-2-ol

(1r,2s,4as,4bs,6as,8r,10ar,10bs,12as)-1,4b,6a,8,10a,12a-hexamethyl-8-(4-methylpent-3-en-1-yl)-dodecahydro-1h-chrysen-2-ol

C30H52O (428.4017942)


   

2-({[3,4-dihydroxy-4-(hydroxymethyl)oxolan-2-yl]oxy}methyl)-6-({3,3-dimethylbicyclo[2.2.1]heptan-2-yl}methoxy)oxane-3,4,5-triol

2-({[3,4-dihydroxy-4-(hydroxymethyl)oxolan-2-yl]oxy}methyl)-6-({3,3-dimethylbicyclo[2.2.1]heptan-2-yl}methoxy)oxane-3,4,5-triol

C21H36O10 (448.2308356)


   

1-hydroxy-1,4b,6a,8,10a,12a-hexamethyl-8-(4-methylpent-3-en-1-yl)-decahydro-3h-chrysen-2-one

1-hydroxy-1,4b,6a,8,10a,12a-hexamethyl-8-(4-methylpent-3-en-1-yl)-decahydro-3h-chrysen-2-one

C30H50O2 (442.38106)


   

(1s,4as,4bs,6ar,8s,10ar,10br,12ar)-1,4b,6a,8,10a,12a-hexamethyl-8-(4-methylpent-3-en-1-yl)-dodecahydrochrysen-2-one

(1s,4as,4bs,6ar,8s,10ar,10br,12ar)-1,4b,6a,8,10a,12a-hexamethyl-8-(4-methylpent-3-en-1-yl)-dodecahydrochrysen-2-one

C30H50O (426.386145)


   

(1r,2s,4as,4bs,6as,8s,10ar,10bs,12as)-8-[(3r)-3-hydroxy-4-methylpent-4-en-1-yl]-1,4b,6a,8,10a,12a-hexamethyl-dodecahydro-1h-chrysen-2-ol

(1r,2s,4as,4bs,6as,8s,10ar,10bs,12as)-8-[(3r)-3-hydroxy-4-methylpent-4-en-1-yl]-1,4b,6a,8,10a,12a-hexamethyl-dodecahydro-1h-chrysen-2-ol

C30H52O2 (444.3967092)


   

(1r,4as,4bs,6as,8s,10ar,10bs,12as)-1,4b,6a,8,10a,12a-hexamethyl-8-(4-methyl-3-oxopent-4-en-1-yl)-dodecahydrochrysen-2-one

(1r,4as,4bs,6as,8s,10ar,10bs,12as)-1,4b,6a,8,10a,12a-hexamethyl-8-(4-methyl-3-oxopent-4-en-1-yl)-dodecahydrochrysen-2-one

C30H48O2 (440.36541079999995)


   

1,4b,6a,8,10a,12a-hexamethyl-8-(4-methylpent-3-en-1-yl)-dodecahydrochrysen-2-one

1,4b,6a,8,10a,12a-hexamethyl-8-(4-methylpent-3-en-1-yl)-dodecahydrochrysen-2-one

C30H50O (426.386145)