Classification Term: 1573

Polyprenyl diphosphates (ontology term: CHEMONTID:0004277)

Prenol lipids in which the diphosphate group is linked to one end of the polyprenol moiety." []

found 3 associated metabolites at family metabolite taxonomy ontology rank level.

Ancestor: Polyprenyl phosphates

Child Taxonomies: There is no child term of current ontology term.

Geranylfarnesyl diphosphate

{[hydroxy({[(2E,6E,10E,14E)-3,7,11,15,19-pentamethylicosa-2,6,10,14,18-pentaen-1-yl]oxy})phosphoryl]oxy}phosphonic acid

C25H44O7P2 (518.2562134)


Geranylfarnesyl diphosphate reacts with isopentenyl diphosphate to produce all-trans-hexaprenyl diphosphate and diphosphate. The reaction is catalyzed by a all-trans-hexaprenyl-diphosphate synthase enzyme. [HMDB] Geranylfarnesyl diphosphate reacts with isopentenyl diphosphate to produce all-trans-hexaprenyl diphosphate and diphosphate. The reaction is catalyzed by a all-trans-hexaprenyl-diphosphate synthase enzyme.

   

Dehydrodolichol diphosphate

{[hydroxy({[(2Z,6Z,10E,14E)-3,7,11,15,19-pentamethylicosa-2,6,10,14,18-pentaen-1-yl]oxy})phosphoryl]oxy}phosphonic acid

C25H44O7P2 (518.2562134)


This compound belongs to the family of Sesterterpenes. These are terpenes compsed of five consecutive isoprene units

   

Dolichyl diphosphate

Dolichol diphosphoric acid

(C5H8)nC20H38O7P2 (681010.1146689999)


The glycosylation of asparagine residues in proteins is known to occur by transfer from a dolichyl diphosphate oligosaccharide containing glucose. The addition of all three glucoses to the dolichyl diphosphate oligosaccharide occur with dolichyl phosphate glucose as donor.(http://www.blackwell-synergy.com/links/doi/10.1111/j.1432-1033.1980.tb04498.x/abs/) [HMDB]. Dolichyl diphosphate is found in many foods, some of which are taro, winter squash, sweet rowanberry, and oregon yampah. The term dolichol refers to a group of long-chain mostly unsaturated organic compounds consisting of a variable number of isoprene units that terminate with an alpha-saturated isoprenoid group containing an alcohol functional group. In the form of dolichol phosphate, dolichols help facilitate protein N-glycosylation (Wikipedia). Glycosylation of asparagine residues in proteins is carried out by transferring glucose from a dolichyl diphosphate oligosaccharide (PMID: 7379786).