Cyhalofop-butyl (BioDeep_00000012335)

Volatile Flavor Compounds

代谢物信息卡片

Cyhalofop-butyl

化学式: C20H20FNO4 (357.13762920000005)
中文名称: 氰氟草酯
谱图信息: 最多检出来源 Viridiplantae(plant) 50%

分子结构信息

SMILES: CCCCOC(=O)C(C)OC1=CC=C(C=C1)OC2=C(C=C(C=C2)C#N)F
InChI: InChI=1S/C20H20FNO4/c1-3-4-11-24-20(23)14(2)25-16-6-8-17(9-7-16)26-19-10-5-15(13-22)12-18(19)21/h5-10,12,14H,3-4,11H2,1-2H3/t14-/m1/s1

描述信息

CONFIDENCE standard compound; INTERNAL_ID 747; DATASET 20200303_ENTACT_RP_MIX507; DATA_PROCESSING MERGING RMBmix ver. 0.2.7; DATA_PROCESSING PRESCREENING Shinyscreen ver. 0.8.0; ORIGINAL_ACQUISITION_NO 8186; ORIGINAL_PRECURSOR_SCAN_NO 8182
CONFIDENCE standard compound; INTERNAL_ID 747; DATASET 20200303_ENTACT_RP_MIX507; DATA_PROCESSING MERGING RMBmix ver. 0.2.7; DATA_PROCESSING PRESCREENING Shinyscreen ver. 0.8.0; ORIGINAL_ACQUISITION_NO 8182; ORIGINAL_PRECURSOR_SCAN_NO 8179
CONFIDENCE standard compound; INTERNAL_ID 747; DATASET 20200303_ENTACT_RP_MIX507; DATA_PROCESSING MERGING RMBmix ver. 0.2.7; DATA_PROCESSING PRESCREENING Shinyscreen ver. 0.8.0; ORIGINAL_ACQUISITION_NO 3854; ORIGINAL_PRECURSOR_SCAN_NO 3852
CONFIDENCE standard compound; INTERNAL_ID 747; DATASET 20200303_ENTACT_RP_MIX507; DATA_PROCESSING MERGING RMBmix ver. 0.2.7; DATA_PROCESSING PRESCREENING Shinyscreen ver. 0.8.0; ORIGINAL_ACQUISITION_NO 3854; ORIGINAL_PRECURSOR_SCAN_NO 3851
CONFIDENCE standard compound; INTERNAL_ID 747; DATASET 20200303_ENTACT_RP_MIX507; DATA_PROCESSING MERGING RMBmix ver. 0.2.7; DATA_PROCESSING PRESCREENING Shinyscreen ver. 0.8.0; ORIGINAL_ACQUISITION_NO 3828; ORIGINAL_PRECURSOR_SCAN_NO 3825
CONFIDENCE standard compound; INTERNAL_ID 747; DATASET 20200303_ENTACT_RP_MIX507; DATA_PROCESSING MERGING RMBmix ver. 0.2.7; DATA_PROCESSING PRESCREENING Shinyscreen ver. 0.8.0; ORIGINAL_ACQUISITION_NO 8179; ORIGINAL_PRECURSOR_SCAN_NO 8176
CONFIDENCE standard compound; INTERNAL_ID 747; DATASET 20200303_ENTACT_RP_MIX507; DATA_PROCESSING MERGING RMBmix ver. 0.2.7; DATA_PROCESSING PRESCREENING Shinyscreen ver. 0.8.0; ORIGINAL_ACQUISITION_NO 3830; ORIGINAL_PRECURSOR_SCAN_NO 3828
CONFIDENCE standard compound; INTERNAL_ID 747; DATASET 20200303_ENTACT_RP_MIX507; DATA_PROCESSING MERGING RMBmix ver. 0.2.7; DATA_PROCESSING PRESCREENING Shinyscreen ver. 0.8.0; ORIGINAL_ACQUISITION_NO 8167; ORIGINAL_PRECURSOR_SCAN_NO 8165
CONFIDENCE standard compound; INTERNAL_ID 747; DATASET 20200303_ENTACT_RP_MIX507; DATA_PROCESSING MERGING RMBmix ver. 0.2.7; DATA_PROCESSING PRESCREENING Shinyscreen ver. 0.8.0; ORIGINAL_ACQUISITION_NO 8182; ORIGINAL_PRECURSOR_SCAN_NO 8180
CONFIDENCE standard compound; INTERNAL_ID 747; DATASET 20200303_ENTACT_RP_MIX507; DATA_PROCESSING MERGING RMBmix ver. 0.2.7; DATA_PROCESSING PRESCREENING Shinyscreen ver. 0.8.0; ORIGINAL_ACQUISITION_NO 8172; ORIGINAL_PRECURSOR_SCAN_NO 8170
CONFIDENCE standard compound; INTERNAL_ID 747; DATASET 20200303_ENTACT_RP_MIX507; DATA_PROCESSING MERGING RMBmix ver. 0.2.7; DATA_PROCESSING PRESCREENING Shinyscreen ver. 0.8.0; ORIGINAL_ACQUISITION_NO 3829; ORIGINAL_PRECURSOR_SCAN_NO 3826

同义名列表

2 个代谢物同义名

Cyhalofop-butyl; Cyhalofop-butyl

数据库引用编号

21 个数据库交叉引用编号

ChEBI: CHEBI:81863
KEGG: C18607
PubChem: 180089
Metlin: METLIN72406
ChEMBL: CHEMBL1900438
CAS: 122008-85-9
MoNA: LU074752
MoNA: LU074702
MoNA: LU074753
MoNA: LU074704
MoNA: LU074701
MoNA: LU074754
MoNA: LU074751
MoNA: LU074755
MoNA: LU074705
MoNA: LU074706
MoNA: LU074703
MoNA: LU074756
PMhub: MS000026638
PubChem: 124489281
KNApSAcK: 81863

分类词条

代谢反应

0 个相关的代谢反应过程信息。

Reactome(0)

BioCyc(0)

WikiPathways(0)

Plant Reactome(0)

INOH(0)

PlantCyc(0)

COVID-19 Disease Map(0)

PathBank(0)

PharmGKB(0)

0 个相关的物种来源信息

在这里通过桑基图来展示出与当前的这个代谢物在我们的BioDeep知识库中具有相关联信息的其他代谢物。在这里进行关联的信息来源主要有：

PubMed: 来源于PubMed文献库中的文献信息，我们通过自然语言数据挖掘得到的在同一篇文献中被同时提及的相关代谢物列表，这个列表按照代谢物同时出现的文献数量降序排序，取前10个代谢物作为相关研究中关联性很高的代谢物集合展示在桑基图中。
NCBI Taxonomy: 通过文献数据挖掘，得到的代谢物物种来源信息关联。这个关联信息同样按照出现的次数降序排序，取前10个代谢物作为高关联度的代谢物集合展示在桑吉图上。
Chemical Taxonomy: 在物质分类上处于同一个分类集合中的其他代谢物
Chemical Reaction: 在化学反应过程中，存在为当前代谢物相关联的生化反应过程中的反应底物或者反应产物的关联代谢物信息。

点击图上的相关代谢物的名称，可以跳转到相关代谢物的信息页面。

文献列表

Xiaoyue Yu, Jinqiu Sun, Yongjie Yang, Jianping Zhang, Yongliang Lu, Wei Tang. Enhanced Herbicide Metabolism and Target Site Mutation Enabled the Multiple Resistance to Cyhalofop-butyl, Florpyrauxifen-benzyl, and Penoxsulam in Echinochloa crus-galli. Journal of agricultural and food chemistry. 2024 May; 72(20):11405-11414. doi: 10.1021/acs.jafc.4c02450. [PMID: 38717990]
Min Liao, Minghao Jiang, Xumiao Wang, Wei Hu, Ning Zhao, Haiqun Cao. The Cys-2088-Arg mutation in the ACCase gene and enhanced metabolism confer cyhalofop-butyl resistance in Chinese sprangletop (Leptochloa chinensis). Pesticide biochemistry and physiology. 2024 Mar; 200(?):105826. doi: 10.1016/j.pestbp.2024.105826. [PMID: 38582590]
Fidel González-Torralva, Jason K Norsworthy. Overexpression of Acetyl CoA Carboxylase 1 and 3 (ACCase1 and ACCase3), and CYP81A21 were related to cyhalofop resistance in a barnyardgrass accession from Arkansas. Plant signaling & behavior. 2023 12; 18(1):2172517. doi: 10.1080/15592324.2023.2172517. [PMID: 36722712]
Wei Deng, Yang Li, Sai Yao, Jiawen Wu, Axiu Zhu, Qian Yang, Shuzhong Yuan. Current status of cyhalofop-butyl and metamifop resistance and diversity of the ACCase gene mutations in Chinese sprangletop (Leptochloa chinensis) from China. Pesticide biochemistry and physiology. 2023 Dec; 197(?):105648. doi: 10.1016/j.pestbp.2023.105648. [PMID: 38072523]
Ziheng Cao, Min Liu, Wanfen Cao, You Zhan, Lianyang Bai, Lang Pan. A glutathione S-transferase and a cytochrome P450 may confer cyhalofop-butyl resistance in Leptochloa chinensis (L.) Nees. Pesticide biochemistry and physiology. 2023 Dec; 197(?):105691. doi: 10.1016/j.pestbp.2023.105691. [PMID: 38072546]
Wei Deng, Yang Li, Sai Yao, Zhiwen Duan, Qian Yang, Shuzhong Yuan. ACCase gene mutations and P450-mediated metabolism contribute to cyhalofop-butyl resistance in Eleusine indica biotypes from direct-seeding paddy fields. Pesticide biochemistry and physiology. 2023 Aug; 194(?):105530. doi: 10.1016/j.pestbp.2023.105530. [PMID: 37532339]
Kang Ou-Yang, Tangqi Feng, Yifang Han, Jianhong Li, Hongju Ma. Cyhalofop-butyl and pyribenzoxim-induced oxidative stress and transcriptome changes in the muscle of crayfish (Procambarus clarkii). The Science of the total environment. 2023 Mar; 864(?):161170. doi: 10.1016/j.scitotenv.2022.161170. [PMID: 36572293]
Guanghua Xiong, Hongmei Hu, Haiyan Zhang, Jun'e Zhang, Zigang Cao, Huiqiang Lu, Xinjun Liao. Cyhalofop-butyl exposure induces the severe hepatotoxicity and immunotoxicity in zebrafish embryos. Fish & shellfish immunology. 2023 Mar; 134(?):108644. doi: 10.1016/j.fsi.2023.108644. [PMID: 36842639]
Xile Deng, Pengyue Zhao, Yong Xie, Lianyang Bai. Self-Assembled Sphere Covalent Organic Framework with Enhanced Herbicidal Activity by Loading Cyhalofop-butyl. Journal of agricultural and food chemistry. 2023 Jan; 71(3):1417-1425. doi: 10.1021/acs.jafc.2c07616. [PMID: 36629331]
Ying Liu, Hao Wang, Haitao Gao, Guangtao Zhu, Zhen Peng, Jun Li, Liyao Dong. Two mechanisms provide tolerance to cyhalofop-butyl in pond lovegrass [Eragrostis japonica (Thunb.) Trin.]. Pesticide biochemistry and physiology. 2022 Nov; 188(?):105247. doi: 10.1016/j.pestbp.2022.105247. [PMID: 36464357]
Manman Duan, Xuanjun Guo, Xiangguang Chen, Mengyu Guo, Mengna Zhang, Hao Xu, Chengju Wang, Yang Yang. Transcriptome analysis reveals hepatotoxicity in zebrafish induced by cyhalofop‑butyl. Aquatic toxicology (Amsterdam, Netherlands). 2022 Nov; 252(?):106322. doi: 10.1016/j.aquatox.2022.106322. [PMID: 36240591]
Minghao Jiang, Yafei Wang, Wei Li, Qi Li, Jingxu Zhang, Min Liao, Ning Zhao, Haiqun Cao. Investigating resistance levels to cyhalofop-butyl and mechanisms involved in Chinese sprangletop (Leptochloa chinensis L.) from Anhui Province, China. Pesticide biochemistry and physiology. 2022 Aug; 186(?):105165. doi: 10.1016/j.pestbp.2022.105165. [PMID: 35973761]
Ning Zhao, Minghao Jiang, Qi Li, Quan Gao, Jingxu Zhang, Min Liao, Haiqun Cao. Cyhalofop-butyl resistance conferred by a novel Trp-2027-Leu mutation of acetyl-CoA carboxylase and enhanced metabolism in Leptochloa chinensis. Pest management science. 2022 Mar; 78(3):1176-1186. doi: 10.1002/ps.6734. [PMID: 34822218]
Ke Chen, Yajun Peng, Liang Zhang, Long Wang, Donghai Mao, Zhenghong Zhao, Lianyang Bai, Lifeng Wang. Whole transcriptome analysis resulted in the identification of Chinese sprangletop (Leptochloa chinensis) genes involved in cyhalofop-butyl tolerance. BMC genomics. 2021 Jul; 22(1):521. doi: 10.1186/s12864-021-07856-z. [PMID: 34238252]
Wei Deng, Mengting Yang, Yang Li, Zhiming Xia, Yongrui Chen, Shuzhong Yuan, Qian Yang. Enhanced metabolism confers a high level of cyhalofop-butyl resistance in a Chinese sprangletop (Leptochloa chinensis (L.) Nees) population. Pest management science. 2021 May; 77(5):2576-2583. doi: 10.1002/ps.6297. [PMID: 33497007]
Yi Zhang, Liping Chen, Wen Song, Tao Cang, Mingfei Xu, Guojun Zhou, Changxing Wu. Reference genes for the study of herbicide stress responses in Leptochloa chinensis (L.) Nees and estimation of ACCase expression in cyhalofop-butyl resistant populations. Pesticide biochemistry and physiology. 2021 Jan; 171(?):104739. doi: 10.1016/j.pestbp.2020.104739. [PMID: 33357561]
Wei Deng, Qian Yang, Yongrui Chen, Mengting Yang, Zhiming Xia, Jin Zhu, Yueyang Chen, Jingxuan Cai, Shuzhong Yuan. Cyhalofop-butyl and Glyphosate Multiple-Herbicide Resistance Evolved in an Eleusine indica Population Collected in Chinese Direct-Seeding Rice. Journal of agricultural and food chemistry. 2020 Mar; 68(9):2623-2630. doi: 10.1021/acs.jafc.9b07342. [PMID: 32058714]
Wei Deng, Jingxuan Cai, Jingyun Zhang, Yueyang Chen, Yongrui Chen, Yingjie Di, Shuzhong Yuan. Molecular basis of resistance to ACCase-inhibiting herbicide cyhalofop-butyl in Chinese sprangletop (Leptochloa chinensis (L.) Nees) from China. Pesticide biochemistry and physiology. 2019 Jul; 158(?):143-148. doi: 10.1016/j.pestbp.2019.05.004. [PMID: 31378350]
Jiaxing Yu, Haitao Gao, Lang Pan, Zhenwei Yao, Liyao Dong. Mechanism of resistance to cyhalofop-butyl in Chinese sprangletop (Leptochloa chinensis (L.) Nees). Pesticide biochemistry and physiology. 2017 Nov; 143(?):306-311. doi: 10.1016/j.pestbp.2016.11.001. [PMID: 29183606]
Parsa Tehranchian, Jason K Norsworthy, Nicholas E Korres, Scott McElroy, Shu Chen, Robert C Scott. Resistance to aryloxyphenoxypropionate herbicides in Amazon sprangletop: Confirmation, control, and molecular basis of resistance. Pesticide biochemistry and physiology. 2016 Oct; 133(?):79-84. doi: 10.1016/j.pestbp.2016.02.010. [PMID: 27742365]
Satoshi Iwakami, Masato Hashimoto, Ken-ichi Matsushima, Hiroaki Watanabe, Kenshiro Hamamura, Akira Uchino. Multiple-herbicide resistance in Echinochloa crus-galli var. formosensis, an allohexaploid weed species, in dry-seeded rice. Pesticide biochemistry and physiology. 2015 Mar; 119(?):1-8. doi: 10.1016/j.pestbp.2015.02.007. [PMID: 25868810]
Junxue Wu, Kai Wang, Yun Zhang, Hongyan Zhang. Determination and study on dissipation and residue determination of cyhalofop-butyl and its metabolite using HPLC-MS/MS in a rice ecosystem. Environmental monitoring and assessment. 2014 Oct; 186(10):6959-67. doi: 10.1007/s10661-014-3902-7. [PMID: 25007772]
J P Ruiz-Santaella, A Heredia, R De Prado. Basis of selectivity of cyhalofop-butyl in Oryza sativa L. Planta. 2006 Jan; 223(2):191-9. doi: 10.1007/s00425-005-0075-1. [PMID: 16160841]
Brian V Ottis, John D Mattice, Ronald E Talbert. Determination of antagonism between cyhalofop-butyl and other rice (Oryza sativa) herbicides in barnyardgrass (Echinochloa crus-galli). Journal of agricultural and food chemistry. 2005 May; 53(10):4064-8. doi: 10.1021/jf050006d. [PMID: 15884840]